Dynamic properties of carbon black filled chlorinated polyethylene/hindered phenol blends

Aggregates of carbon black (CB) in a polymer matrix have a tendency to form a CB network. The dynamic mechanical properties of binary systems of chlorinated polyethylene (CPE) and CB or 3,9‐bis{1,1‐dimethyl‐2[β‐(3‐tert‐butyl‐4‐hydroxy‐5‐methylphenyl)propionyloxy]ethyl}‐2,4,8,10‐tetraoxaspiro[5,5]‐undecane (AO‐80) and their ternary systems were investigated. It was found that the dynamic mechanical properties of those systems depend on the colloidal properties, surface oxides, and surface modification of CB. For binary systems of CPE and CB, oxidized CB gives a high modulus at low strain amplitude and a large Payne effect compared with untreated CB. In contrast, the reverse effect was observed for their ternary systems. Consequently, a good micro‐dispersion is obtainable by surface modification due to physical adsorption of AO‐80 on oxidized CB particles via hydrogen bonds. © 2003 Society of Chemical Industry     

精馏塔静态仿真：Ⅰ.静动态混合数学模型的应用

本文为了克服精馏塔静态仿真不易收敛和初值难以给定等难题，巧妙地利用隐含数值积分方法的特点，将稳态与动态数学模型耦合起来，用以求解高难度的非理想精馏塔静态仿真问题。所得静动态混俣模型大大提高了精馏塔静态仿真的鲁棒性，对于高度非理想精馏塔的仿真尤为有效。通过对某丙烯腈萃取精馏塔的静态仿真，充分证明了这种混合模型化方法的可行性。     

预测控制算法的统一格式及其在电加热炉的应用

本文根据常用的两类预测控制算法推出一种新型预测控制算法。并将其应用于一双输入/双输出的力学持久机电加热炉的温度控制系统上,获得了满意的结果:控温精度为±1.5℃/300℃,且适用于非最小相位系统。     

Procedures for analysis of strain transfer in the acetabular region in vitro

The failure of acetabular cups via loosening, migration or fracture is partially related to the stress distribution existing in the acetabular region. The complexity of the investigation of these stresses demands the application of a variety of model testing techniques involving combined embedded strain gauging, finite element analysis, transmission and reflective photoelasticity and crack propagation studies. The application of these procedures are described and the difficulties of obtaining representative loadings and restraints are commented upon.     

Dynamic Survivability in WDM Mesh Networks Under Dynamic Traffic

Network survivability is a crucial requirement in WDM mesh networks. In this paper, we systematically consider the problem of dynamic survivability with dynamic single link failure in WDM networks under dynamic traffic demands. Specifically, we investigate various protection schemes, such as dedicated path protection (DPP), shared path protection (SPP), dedicated link protection (DLP), shared link protection (SLP), and two restoration schemes, path restoration (PR) and link restoration (LR). Moreover, two new shared protection methods are proposed, i.e., SRLG-based shared link protection (SRLG-SLP) and SRLG-based shared path protection (SRLG-SPP). The SRLG (shared risk link group) constraint defines the availability of protection resources to a working path, which requires that any two working paths sharing the same risk of failure (or in the same SRLG) cannot share the same protection resources. Furthermore, in our study, we consider a more practical dynamic single-link failure model, in which the link-failure-interarrival time and link-failure-holding time are considered as two independent parameters. Based on this link-failure model, extensive simulations are done to analyze and compare the dynamic survivable performance of various protection and restoration schemes. Resource utilization, protection efficiency, restoration efficiency, and service disruption ratio are employed as survivable performance metrics versus traffic load, link-failure frequency, and link-failure reparation time to evaluate the survivable performance. Many meaningful results are given. In addition, we show that the developed SRLG-SLP and SRLG-SPP protection schemes perform very well in terms of protection efficiency and service disruption ratio, while sacrificing some performance in terms of resource utilization.     

Electrocatalytic hydrogenation of cyclohexanone: Simple dynamic cell design

The electrocatalytic hydrogenation of cyclohexanone has been investigated with catalytic powder particles made of metal nanoaggregates deposited on a nonconductive material such as activated carbon and alumina. The catalytic powder particles were suspended in the solution under vigorous stirring conditions. The brief contact of the powder particles with a porous carbon cathode was sufficient to form adsorbed hydrogen on the metallic nanoaggregates through water electrolysis and initiate the electrohydrogenation process. It is demonstrated that the key parameters of the electrohydrogenation process are both the nature of the metallic nanoaggregates and the nature of the non-conductive material. The hydrodynamics of the solution under vigorous stirring conditions have also been studied for the particular cell used in the present study.     

一种新的图像水印方案

目标区域是图像中视觉上最重要的部分。针对现有的水印算法很少考虑图像中确定的目标区域这一问题，提出了一种基于目标区域的水印方案(WIOR)。方案首先利用小波变换分析图像的目标特征，并依据图像的小波高频系数特征对其进行聚类，获得水印的嵌入域，在此嵌入域中，选择小波系数并对其进行量化调制来嵌入二值扩谱水印；同时，通过只在图像的局部区域内嵌入较少的水印信息来改善水印的隐蔽性。实验结果表明，该方案对于一类具有突出目标特征的图像具有较好的效果。嵌入的水印主要优势在于真正把水印嵌入图像的视觉重要部分，从而能有效地抵御剪切攻击，而且可以实现盲检测。     

Characterization of resol resins modified by the addition of PVC plastisols

Plastisols, which are a blend of poly(vinyl chloride) resin and a plasticizer (DEHP), were used as a toughening agent of a resol resin in order to improve the mechanical properties. It was not possible to formulate resol blends by adding more than 10 % of plastisol owing to a lack of apparent homogeneity in the systems, which also showed many air bubbles. The relationship between dynamic mechanical, mechanical and thermal properties and the amount of plastisol added was studied. It was determined from the infrared spectroscopy and dynamic mechanical results that the resol–plastisol blends seem to be formed by a reaction between the phenol and PVC giving a higher crosslinked structure. An improvement in the thermal resistance of the blends at lower temperatures was observed with an increase in the percentage of plastisol. Flexural analysis showed the elastic behaviour of the systems. However, it was not possible to observe the effect of the plasticizer (DEHP) owing to the low quantity of plastisol that was added to the resol. Copyright © 2004 Society of Chemical Industry     

Decomposition of Time Series Dynamic Linear Models

This paper derives the admissible decompositions for a time series dynamic linear model, assuming only that the model is observable. The decompositions depend on factorizations of the characteristic polynomial of the state evolution matrix G into relatively prime factors. This generalizes the method of West (1997 ) which considers one decomposition in the particular case where G is diagonalizable. Conditions are derived for a decomposition to be independent. These results show that no autoregressive process of order d has an independent decomposition for any integer d . Two illustrations of this procedure are discussed in detail.