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41.
42.
Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar have been numerically simulated with detailed chemistry. The combination of H2, CO2 and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO2. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO2, N2O and Fenimore are taken into account to separately evaluate the effects of CO2 addition on NO emission characteristics. The increase of added CO2 quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO2 produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N2O and NO2 mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO2 quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
43.
Gibbs energies of formation of CoF2 and MnF2 have been measured in the temperature range from 700 to 1100 K using Al2O3-dispersed CaF2 solid electrolyte and Ni+NiF2 as the reference electrode. The dispersed solid electrolyte has higher conductivity than pure CaF2 thus permitting accurate measurements at lower temperatures. However, to prevent reaction between Al2O3 in the solid electrolyte and NiF2 (or CoF2) at the electrode, the dispersed solid electrolyte was coated with pure CaF2, thus creating a composite structure. The free energies of formation of CoF2 and MnF2 are (± 1700) J mol−1; {fx37-1} The third law analysis gives the enthalpy of formation of solid CoF2 as ΔH° (298·15 K) = −672·69 (± 0·1) kJ mol−1, which compares with a value of −671·5 (± 4) kJ mol−1 given in Janaf tables. For solid MnF2, ΔH°(298·15 K) = − 854·97 (± 0·13) kJ mol−1, which is significantly different from a value of −803·3 kJ mol−1 given in the compilation by Barinet al. 相似文献
44.
对未知组成的样品进行紫外光谱扫描 ,根据扫描结果以及各种溴指数测定方法的适用范围 ,选择测定未知物溴指数的适宜方法 ,以提高测定准确度。 相似文献
45.
目前采用的视频流调度算法,没有充分利用补丁流满足服务率高而占用系统资源少的优势,系统效率较低.为了提高效率,提出了一种基于MFQ的补丁优先算法,并给出了该算法的系统流程。通过对实验结果的比较,该算法在用户请求撤销率、节目调度不公平性和用户等待时间方面有明显的优越性. 相似文献
46.
提出了用三角函数表示的一类用于油田开发指标预测的增长曲线共6条,从而进一步完善和丰富了现有的增长曲线法。提出和推导了它们的Np-t、Qt-t、Qt-Np关系式、(Np/NRmax)Qtmax准数计算式以及参数求解式。其特片研究表明,它们特征相近;(Np/NRamx)Qtmax变化范围为0-0.36785,属于峰值产量出现在油田开发初期的情况,其Qt-Np关系为一不对称的拱形曲线。提出了求取曲线参数的过原点重复线性回归法。双河油田的实例表明该方法有一定实用价值。 相似文献
47.
Pulkki-R?back Laura; Elovainio Marko; Kivim?ki Mika; Raitakari Olli T.; Keltikangas-J?rvinen Liisa 《Canadian Metallurgical Quarterly》2005,24(3):307
This study examined associations of temperament at ages 6 to 12 with body-mass index (BMI) and waist circumference (WC) at ages 24 to 30 years. The participants were 619 men and women derived from the population-based Cardiovascular Risk in Young Finns Study. Temperament was operationalized as (negative) emotionality, sociability, and activity. High emotionality predicted increased BMI, independently of WC, and independently of childhood and adulthood risk factors for adult obesity. None of the temperament dimensions had any associations with WC after controlling for BMI. The findings suggest that temperamental difficulty in childhood may be a useful risk indicator for general body mass in adulthood, and the mechanisms relating temperament with body mass should be further explored. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
49.
Boiling: Size Distribution of Bubbles as Demanded by the Principle of Maximum Information 总被引:1,自引:0,他引:1
The principle of maximum informational entropy is used to find the probability density function for the departure radius of a bubble in boiling on a solid surface. A general relation is derived, which leads to particular expressions. 相似文献
50.
Differential pressure fluctuation time series were obtained at different locations in a two-dimensional spout-fluid bed with a cross section of 300 × 30 mm and height 2000 mm. Shannon entropy analysis of differential pressure fluctuations was developed to characterize the dynamic behavior. Effects of two important operating parameters (spouting gas velocity and fluidizing gas flow rate) on the Shannon entropy were examined. It was demonstrated that a spout-fluid bed at a high spouting gas velocity or fluidizing gas flow rate was a deterministic chaos system since the Shannon entropies at all bed locations increased sharply and asymmetric unstable flows occurred. Shannon entropies were found to be significantly different at various bed locations. Shannon entropies of different flow regimes were distinct, so they were used to identify the flow regimes. The results show that the Shannon entropy helps to grasp the complex characteristics of dynamic behavior in spout-fluid beds. 相似文献