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The recently established spin-coating electrostatic self-assembly (SCESA) technique has been shown to facilitate not only the rapid fabrication of polyelectrolyte multilayer assemblies, but also allow each layer to be easily controlled on a monomolecular scale by minimizing the film thickness across a substrate surface. In this paper, the influence of polyelectrolyte concentration on the amount and thickness of spin-deposited polymer films has been examined for a multilayer system of poly(allyamine hydrochloride) (PAH) and poly(sodium 4-styrenesulfonate) (PSS), when the washing steps employed for removing weakly bound polyelectrolytes on a resultant film on a substrate are excluded from the standard fabrication procedure of the SCESA method. The thickness of the spin-deposited PAH/PSS bilayer increased linearly for the PSS concentrations in the range from 1 to 10 mM with PAH constant at 1 mM, which demonstrates the uniform deposition of each layer material onto the thin film. The thickness of PAH/PSS bilayers increased from 1.43 ± 0.06 to 3.37 ± 0.08 nm as the PSS concentration increased from 1 to 10 mM, while the PAH concentration was kept constant at 1 mM. The multilayer films were found to be stable in a good solvent (H2O) for at least 30 h, without any noticeable loss of the adsorbed layer component of the polyelectrolyte. This improvement to the SCESA method (exclusion of washing steps) provides a convenient way to create multilayer heterostructures with the thickness of each layer being easily adjusted. 相似文献
63.
Metal matrix composites reinforced by three-dimensional (3-D) continuous network structure reinforcement (3DCNRMMC) are difficult to machine due to serious tool wear and poor surface roughness caused by the brittle and hard reinforcement which interpenetrate into ductile matrix. In order to achieve the approach of low cost of 3DCNRMMC, the machinability of it needs to be understood. The influences of three cutting parameters and volume fraction of reinforcement on cutting force were analyzed in detail. The results indicate that: (1) Due to the brittle phase(s) introduced into ductile matrix of composites, there is a large fluctuation of cutting force causing deterioration of machinability. The fluctuation ranges of cutting forces, initially increase rapidly with the increase of volume fraction of reinforcement and then decrease finally, are largest at the range of the volume fraction of 55–65%; (2) The influence of cutting parameters on cutting force is obvious. With the increases of cutting speed, cutting force decreases gradually unless cutting speed exceeds the value of 209 m/min. Cutting forces increase with increasing feed rate and depth of cut; (3) Owing to the large fluctuation of cutting force, there were some cratered surfaces caused by Si3N4 reinforcement pulling-out and flaking-off. Some brittle phase protruding from the machined surface caused the deterioration of machined surface. 相似文献
64.
WEI Shuangying 《武汉理工大学学报》2006,28(Z2)
The modern industrial control objects become more and more complicated, and higher control quality is required, so a series of new control strategies appear, applied, modified and develop quickly. This paper researches a new control strategy-prediction control-and its application in Multi-Variable Control Process. The research result is worthy for automatic control in process industry. 相似文献
65.
刘红 《广东输电与变电技术》2005,(1):20-21
变压器对抗短路强度的要求是很高的。文中介绍了变压器短路时的电动力的作用情况,结合单位实际情况介绍了提高变压器抗短路能力的措施。 相似文献
66.
用常规方法处理乳化油污水比较困难,存在不同的问题,膜分离技术处理乳化油污水具有分离精度高,无二次污染,过程无相变等优点。 相似文献
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