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41.
Gradient-corrected density functional theory was used to investigate the adsorption of H2S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H2S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H2S decomposition giving rise to adsorbed S and H were determined. Both H2S(ad) → SH(ad) + H(ad) and SH(ad) → S(ad) + H(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H2S on Pd(1 1 1) surface is a facile process. 相似文献
42.
William Kent 《Computer Standards & Interfaces》1991,13(1-3):201-206
OSQL is the object-oriented database language developed for the Iris object-oriented database management system at Hewlett-Packard Laboratories. Its three fundamental constructs are objects, types, and functions. This paper provides an overview of the underlying concepts and some important features of OSQL. 相似文献
43.
基于蚁群算法的区域覆盖卫星星座优化设计 总被引:1,自引:0,他引:1
首先建立了以区域覆盖性能为目标的卫星星座参数优化模型,通过在连续域定义新的蚂蚁分类与转移策略改进了蚁群算法,使算法能够兼顾多目标优化时目标不兼容的情况,给出了基于该算法实现星座参数优化的框架。优化仿真实验验证了该算法的有效性,可为星座方案决策提供有力的支持。 相似文献
44.
WANG Jiqing 《声学技术》2004,23(Z3)
This paper gives an overview of the research at Institute of Acoustics, Tongji University, on functional absorbers and experience acquired in practical applications over the past three decades. Experiments and analysis of the absorption characteristics of three different geometrical forms of functional absorbers, i.e., panels, cubes and tubes, were conducted with different arrangements. The resulting esthetical effects are illustrated with pictures. Several non-fiber materials are used to compose functional absorbers with advantages both in acoustic properties and in architectural features. Cost effectiveness analysis is also given in order to provide design guidelines. 相似文献
45.
Woo-Seok Cheong 《Journal of Electronic Materials》2003,32(4):249-253
For the lowest resistance, it is required to have the epitaxial silicon contact between the silicon plug and the substrate
and good step coverage at the high aspect-ratio contact holes, simultaneously. In this work, a double polysilicon (DPS) deposition
technique was proposed for the requirements. The first, thin silicon layer is deposited in a single-wafer process chamber
with an in-situ H2-RTP (rapid thermal process) treatment for the epitaxial contact, and the second silicon layer is formed in a batch-type furnace
for good step coverage. From chain resistance, Kelvin Rc, and current-voltage (I–V) measurement, the DPS process meets both low resistance and good uniformity, so that it suggests
a breakthrough in the small-sized, semiconductor device application. 相似文献
46.
石英砂在菱苦土磨具中的作用机理 总被引:1,自引:0,他引:1
本文利用物质结构与化学键的有关理论对石英砂的菱苦土磨具中的作用机理进行分析,并以实验对分析结果进行验证。结果表明:金刚砂晶体中Si-C共价键的离子性百分数仅为9%,石英晶体中Si-O共价键的离子性百分数为47%,因此,石英与主要以离子键结合的菱苦土结合剂之间有较强的静电作用力,石英与菱苦土的结合力强于金刚砂,可提高菱苦土磨具的耐磨性。 相似文献
47.
The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is Rp ∝ [BPO]0.5 [AN]1.0 [GER]1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm?1 due to ? OH group of GER and ? CN group of AN, respectively. The 13C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (Tg) 56°C. The reactivity ratios r1 (AN) and r2 (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
48.
O. L. Perevozchikova V. G. Tul'chinskii A. V. Kharchenko 《Cybernetics and Systems Analysis》2003,39(4):501-508
A statistical learning model is considered within the framework of the theory of uniform convergence of frequencies of errors in the case where the convergence is violated as a result of increasing the informativeness of training examples. Drawbacks of nonconstructive refinements of Vapnik-Chervonenkis estimates based on an assumption on the distribution law of violations are shown. A new approach to obtaining constructive estimates for mass data sets is proposed. 相似文献
49.
Summary Recent progress in the modelling of exchanged Cu sites and their interactions with small molecules, based on DFT cluster calculations, is briefly reviewed. 相似文献
50.
复合功能陶瓷中的晶界渗流模型 总被引:1,自引:0,他引:1
在复合陶瓷材料中提出了晶界控制的渗液模,考虑晶界效应对渗流阀值的影响,采用MonteCarlo模拟,计算得到三维FCC晶格点阵的渗流阀值约为4.5%。该结果与实验数据符合得很好。 相似文献