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941.
942.
A novel process was developed for the bitumen emulsion upgrading, wherein emulsion breaking and upgrading occurred in the same reactor using H2 generated in situ from the water in the emulsion via the water gas shift reaction (WGSR). In this study, dibenzothiophene (DBT) was chosen as a model compound to investigate the effect of water and in situ H2 on hydrodesulfurization (HDS). All the experiments were performed in a 1-L autoclave reactor at temperatures between 300 and 380 °C using in situ H2 and ex situ H2 (externally supplied H2) over a dispersed Mo catalyst formed from phosphomolybdic acid (PMA). At very low water content, water was found to promote the HDS reaction in the ex situ H2 run probably because it facilitates the formation of more active dispersed MoSx species. At higher water content, however, water inhibits every individual reaction in the reaction network in the HDS of DBT, blocking the hydrogenation pathway more than the hydrogenolysis pathway. The relative reactivity of the in situ and ex situ H2 depends on the water content present in the reaction system. At an optimized mole ratio of H2O:CO (1.35), higher HDS activity was observed in the in situ H2 run compared to ex situ H2 run, and particularly, the hydrogenation pathway was promoted in the in situ H2 run. 相似文献
943.
Passing of a triangular moderate-intensity pulse through a constant discontinuity is considered. Decay of the shock wave that
passed into the second gas is analyzed. Damping of the detonation wave after burnout of the combustible mixture is discussed.
__________
Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 4, pp. 102–107, July–August, 2007. 相似文献
944.
Ion beam irradiation can be used to modify the structure and gas transport properties of glassy polymers. This is the first of two studies that focus on the impact of H+ ion irradiation on the structure and permeation properties of the polyimide Matrimid®. Specifically, the evolution in chemical structure after H+ irradiation over a range of fluences was analyzed using FTIR spectroscopy and dissolution studies. Although H+ ion irradiation at very low ion fluences induced little modification in the chemical structure, irradiation at relatively high ion fluences resulted in crosslinking of the irradiated films. The branched structure of the aliphatic methyl (CH3) was the most sensitive to the H+ ion irradiation. The para‐disubstituted aromatic ring showed the strongest resistance toward ion irradiation and required fairly high doses to induce degradation. Two potential crosslinking mechanisms related to the degradation of the aliphatic methyl and the benzophenone carbonyl were presented. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2010–2019, 2003 相似文献
945.
Mei‐Rong Huang Sheng‐Xian Li Zhi‐Qing Dong Wei Feng Xin‐You Wang Shu‐Ying Gu Yan‐Hui Wu Xiang‐An Huang 《应用聚合物科学杂志》2002,83(14):3013-3021
Several multilayer thin low‐density polyethylene (LDPE) films were fabricated by blown thin film having a thickness of 7 μm and an area of 130 cm2. They were characterized for their oxygen‐enrichment performance from air by a constant pressure–variable volume method in a round permeate cell with an effective area of 73.9 cm2. The relationship between oxygen‐enrichment properties, including oxygen‐enriched air (OEA) flux, oxygen concentration, permeability coefficients of OEA, oxygen, nitrogen, as well as separation factor through the multilayer LDPE films, and operating parameters, including transfilm pressure difference, retentate/permeate flux ratio, temperature, as well as layer number, are all discussed in detail. It is found that all of the preceding oxygen‐enrichment parameters increase continuously with an increase of transfilm pressure difference from 0.1 to 0.65 MPa, especially for the trilayer and tetralayer LDPE films. The oxygen concentration and separation factor appear to rapidly increase within the retentate/permeate flux ratio below 200, and then become unchangeable beyond that, whereas the OEA flux and the permeability coefficients of OEA, oxygen, and nitrogen seem to remain nearly constant within the whole retentate/permeate flux ratio investigated, especially for the monolayer and bilayer LDPE films. The selectivity becomes inferior, whereas the permeability becomes superior, as the operating temperature increases from 23 to 31°C. The highest oxygen concentration was found to be 44.8% for monolayer LDPE film in a single step with air containing oxygen of 20.9% as a feed gas and operating pressure of 0.5 MPa at a retentate/permeate flux ratio of 340 and 23°C. The results demonstrate a possibility to prepare an oxygen‐enriching membrane directly from air, based on the easily obtained thin LDPE films. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 3013–3021, 2002; DOI 10.1002/app.2331 相似文献
946.
本文介绍了一种新型的能在较高压力环境下进行细过滤的PE井口高压滤芯的结构特征、关键技术研究、技术特性,以及应用效果。 相似文献
947.
948.
工业过程中的废热排放造成了可用能的损失 ,又造成热污染和环境污染。针对一种利用热管回收废热的LiBr制冷机 ,采用柴油机烟气废热制冷实测后 ,对该系统的实测结果进行了火用分析 ,分析结果表明了这种新型废热LiBr制冷机有效利用了柴油机烟气余热 ,提高了系统的火用效率 相似文献
949.
PVAm/PAN复合膜的制备及其对CO2/CH4的分离性能 总被引:1,自引:0,他引:1
New polymeric membrane materials——polyvinyl amine (PVAm) with different primary amine contents were synthesized.By covering polyacrylonitrile(PAN) ultrafiltration membranes with PVAm, the PVAm/PAN composite membranes for CO2/CH4 separation were prepared. The composite membranes containing more primary amino groups have higher selectivity for CO2/CH4.The cross-linking of acid or glutaradehyde could improve the gas permselectivity of the composite membranes. With decreasing CO2 content in the feed gas, the CO2/CH4 separation factor increased.When the feed gas was 25%(vol) CO2 and 75%(vol) CH4, the CO2 permeation rate was 4.1×10-9cm3(STP) 8226;cm-28226;Pa-18226;s-1, and the CO2/CH4 separation factor was 180. 相似文献
950.
Experimental investigations have been carried out for spherical and non-spherical particles using beds comprised of single-sized particles and mixtures in the size and particle density ranges of 439 to 1524 μm and 1303 to 4948 kg/m3, respectively. Five conical fluidizers with varying apex angles of 8.86, 14.77, 19.60, 32.0 and 43.2 degrees were used. Experimental values of minimum velocity and bed pressure drop with air as the fluidizing medium have been compared with their respective values obtained from different models available in the literature. Deviations for each chosen model have been presented. 相似文献