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12.
David C. Apperley Robin K. Harris Gregory L. Marshall Derek P. Thompson 《Journal of the American Ceramic Society》1991,74(4):777-782
The 29 Si MAS NMR spectra of the 2H, 4H, 6H, and 3C polytypes of silicon carbide are presented. An attempt is made to correlate differences in the chemical shifts with local atomic environment. The results of the analysis of the spectra of pure polytypes are used as a basic for the interpretation of the spectra of mixed polytypes and a discussion of the crystallinity and impurity levels of different samples. Carbon-13 chemical shifts obtained from spectra of the same polytypes are also tabulated. 相似文献
13.
渗透率是反映储层渗流能力的重要参数,目前对于单一储层的渗透率表征方法,通常是在岩心分析渗透率或测井解释渗透率的基础上进行厚度加权算术平均。这种方法对于均质的储层来说是适用的,但对于非均质严重的储层,不能准确反映该储层的实际渗流能力。本文提出一种应用可动流体体积权衡表征渗透率的方法,经实际资料验证,能较好地反映储层的实际渗透能力。 相似文献
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To date, it has been reliably shown that the lipid bilayer/water interface can be thoroughly characterized by a sophisticated so-called “dynamic molecular portrait”. The latter reflects a combination of time-dependent surface distributions of various physicochemical properties, inherent in both model lipid bilayers and natural multi-component cell membranes. One of the most important features of biomembranes is their mosaicity, which is expressed in the constant presence of lateral inhomogeneities, the sizes and lifetimes of which vary in a wide range—from 1 to 103 nm and from 0.1 ns to milliseconds. In addition to the relatively well-studied macroscopic domains (so-called “rafts”), the analysis of micro- and nanoclusters (or domains) that form an instantaneous picture of the distribution of structural, dynamic, hydrophobic, electrical, etc., properties at the membrane-water interface is attracting increasing interest. This is because such nanodomains (NDs) have been proven to be crucial for the proper membrane functioning in cells. Therefore, an understanding with atomistic details the phenomena associated with NDs is required. The present mini-review describes the recent results of experimental and in silico studies of spontaneously formed NDs in lipid membranes. The main attention is paid to the methods of ND detection, characterization of their spatiotemporal parameters, the elucidation of the molecular mechanisms of their formation. Biological role of NDs in cell membranes is briefly discussed. Understanding such effects creates the basis for rational design of new prospective drugs, therapeutic approaches, and artificial membrane materials with specified properties. 相似文献
16.
Margarida Taborda Duarte H. Y. Liu S. Q. Kou P. -A. Lindqvist K. Miskovsky 《Journal of Materials Engineering and Performance》2005,14(1):104-111
The importance of the microstructural parameters in rock mechanical behavior has been investigated by several authors. Moreover,
the Weibull statistical model has been used to characterize the heterogeneity of several materials on the basis of the concept
that the microscopic defects within the material determine their mechanical strength. The modeling of different rocks is a
topic that is fundamental for the prediction of rock fragmentation. In this article, the analysis of rock microstructure is
performed using the microstructural modeling approach, which consists of the simplification, quantification, and modeling
of the main properties of rock microstructure. The grain size, grain shape, and microcracks are modeled by means of statistical
density functions, namely, Cauchy, chi-squared, exponential, extreme value, gamma, Laplace, normal, uniform, and Weibull.
It is found that the Weibull distribution is the most appropriate statistical model of the grain size and grain shape, when
compared with the other eight statistical models. Regarding microcracks, the results show that the gamma distribution is the
most appropriate model. The Weibull and gamma distributions are then used to analyze the heterogeneity of the microstructure.
This is done by comparison of the statistical models of each microstructural property evaluated in several thin sections of
the same rock. It is found that with respect to grain size and grain shape, the rock is homogeneous, while the size distribution
of the microcracks shows a clear trend toward less homogeneity. The microstructural modeling approach is important for modeling,
characterizing, and analyzing the microstructure of rock material. Among other applications, it can be used to explain differences
in the mechanical behavior obtained in testing several specimens. 相似文献
17.
This paper presents an overview of the theory of upscaling hydraulic conductivity and describes two case studies in which some of this theory has been applied. The representative hydraulic conductivity of a numerical model block (block conductivity for short) is defined in terms of smaller scale hydraulic conductivities. Also, using elementary examples, some general properties of block conductivities are given. Analytical solutions for the block conductivity are presented that were derived by various authors for uniform flow conditions both in a deterministic and in a stochastic setting. Some results of the hydraulic upscaling theory are illustrated by two case studies from the Netherlands. The first case study deals with deriving the representative hydraulic conductivity tensor of a clay layer. Upscaling results are compared with traditional harmonic averaging. In the second case study the upscaling is used to derive the three-dimensional distribution of block conductivities for a numerical groundwater model of a confining layer of complex deposits. Here stochastic upscaling is used together with a geostatistical simulation approach. The simulated block conductivities are used in a numerical groundwater model and results are compared with pumping tests. When the upscaling is ignored groundwater flow through the deposits is predicted wrongly. 相似文献
18.
Geomorphic diversity as a river management tool and its application to the Ganga River,India 总被引:1,自引:0,他引:1
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Understanding of geomorphic processes and the determination of geomorphic diversity in catchments are prerequisites for the sustainable rehabilitation of river systems and for reach‐scale assessment of river health. The Ganga River system in India is a large, complex system consisting of several long tributaries, some >1,000 km, originating from 2 distinct hinterlands—the Himalaya to the north and the cratons to the south. Traversing through a diverse climatic regime across the Plain and through precipitation zones ranging from 600 mm/year near Delhi to 1,200 mm/year in the eastern plains, the Ganga River system has formed very diverse landform assemblages in 3 major geomorphic domains. We have recognized 10 different river classes for the trunk river from Gangotri (source) to Farakka (upstream of its confluence with the Brahmaputra) based on (a) landscape setting, (b) channel and active floodplain properties, and (c) channel planform parameters. The mountainous stretch is characterized by steep valleys and bedrock channels and is dominated by large‐scale sediment production and transport through hill slope processes. The alluvial part of the river is characterized by 8 different river classes of varying reach lengths (60–300 km) many of which show sharp transitions in landscape setting. We have highlighted the application of this approach for the assessment of habitat suitability, environmental flows, and flood risk all of which have been significantly modified during the last few decades due to large‐scale anthropogenic disturbances. We suggest that the diversity embedded in this geomorphic framework can be useful for developing a sustainable river management programme to “work with” the contemporary character and behaviour of rivers. 相似文献
19.
Fluid flow in coupled free and porous domain, particularly when the porous medium is heterogeneous, is encountered in many hydro-environmental conditions, e.g., leakage from underground pipe, combined groundwater lake-subsurface interactions. One of the most difficult problems in the study of coupled flow behaviour has been the development of a universally applicable modelling scheme for combining the flow regimes. This is because the free/porous interfacial properties (e.g., shear-stress; velocity slip) that govern the coupled flow behaviour are difficult to determine experimentally under hydro-environmental conditions. On the other hand, the implications of various forms of heterogeneity in the porous media properties can be very different on the fluid-flow behaviour. Difficulties may also arise in direct coupling of the model equations that govern the fluid flow in the individual regions (e.g., Navier-Stokes for free-flow region and the Darcy's equation for the porous flow region). Consequently, models of coupled free and porous flow for hydro-environmental conditions are not very well developed at the moment. While there are some indications that fluids in coupled free and porous domains may circulate (i.e., development of flow cells), there is a lack of appropriate 3D analysis on how heterogeneities in porous media may affect such flow patterns. In this paper, we aim to analyse how porous media heterogeneity affects the dynamics of flow circulation in the porous side of a coupled free and porous domain. For this purpose, we analyse flow patterns in several model domains made up of two porous layers with differing permeabilities. The governing model equations are discretised and solved using the standard finite volume method on a staggered cell-centred mesh. The temporal discretisation is done using the explicit method. An in-house graphical user interface (GUI) has been created specifically to aid in the visualisation of otherwise complex flow patterns. The GUI contains many post-processing options and provides a comprehensive tool for the analysis of hydrodynamics and contaminant motion (not discussed in this paper) in coupled free and porous flow domains. This GUI is described in this paper briefly. The effects of altering the aspect ratio (i.e., multi-scale) of the domain on the coupled flow pattern have also been discussed. 相似文献
20.