High-temperature oxidation of pure titanium in CO2 and Ar-10%CO2 atmospheres

The oxidation behavior of pure titanium has been investigated in the temperature range of 1000 K to 1300 K in CO₂ or Ar-10%CO₂. Optical microscopy, electron probe microanalyses, and X-ray measurements on the oxide scales formed during oxidation indicate that their structures are nearly independent of temperature and the corrosion atmosphere. The scales consisted of two layers, an external one and an internal one, having a rutile (TiO₂) structure. The parabolic rate law was confirmed for growth of the external scale and the permeation depth of oxygen in titanium with apparent activation energies of 266 and 226 kJ/mol, respectively. The rate-determining diffusion species in the oxidation processes are discussed.     

20G高压锅炉管裂纹原因分析

对20G高压锅炉管产生裂纹的原因进行了分析，结果表明是冷拔工艺不当所致。     

Effects of gold plating on the resistance to high temperature discoloration of the cavity for ceramic packages

The effects of thickness and types of gold plating on the resistance to high temperature discoloration of gold plating on cavity surface of ceramic package were investigated. It was found that the thicker gold plating, the less discoloration degree for ceramic packages. Non-cyanide gold plating performed better resistance to high-temperature aging than cyanide gold plating. The relationship between the gold plating thickness and the amount of diffused Ni to the gold plating of ceramic packages with Au/Ni and Au/Ni-Co platings after heating at 420℃for 15 min was also studied. When the gold plating thickness reach 2.0 μm and 1.6 μm for Au/Ni and Au/Ni-Co plating systems, respectively, no discoloration was observed on the gold plating surface of cavity, and the corresponding diffused Ni amounts (mass fraction) are 1.0% and 0.4%, while the diffused Co to the gold plating is 0.04%.     

Synthesis mechanism of titanium carbide nano-fiber during self-propagating high temperature synthesis

Titanium carbide nano-fiber was synthesized by self-propagating high temperature synthesis (SHS) method. The final products after the SHS reaction were titanium carbide containing excess carbon and metallic titanium, which were removed by additional leaching process. TEM observation revealed that the average diameter is about 20 nm. Neutron diffraction analysis was carried out to study non-stoichiometric number of the titanium carbide. The non-stoichiometric numbers of the titanium carbide were 0.89–0.94. The Rietveld refinement of each patterns converged to good agreement (÷2=0.49–1.34). The formation mechanism of the carbide is related to a liquid-solid reaction including the preferential diffusion process of carbon atom into liquid titanium. This article is based on a presentation made in the 2002 Korea-US symposium on the “Phase Transformations of Nano-Materials,” organized as a special program of the 2002 Annual Meeting of the Korean Institute of Metals and Materials, held at Yonsei University, Seoul, Korea on October 25–26, 2002.     

Effect of grain size on high-temperature oxidation behavior of Cu-80Ni alloy

1　INTRODUCTIONTheoxidationofunalloyedcopperandnickelhasalreadybeenstudiedindetail.Whilethehigh tem peratureoxidationofCu Nialloys ,alsostudiedanumberoftimestodate[13] ,isanexampleofarela tivelysimpleclassofscalingofbinaryalloysbyasin gleoxidant,becausethemetalsformacontinuousse riesofsolidsolutions ,whiletheiroxides ,CuO ,Cu2 OandNiO ,exhibitsmallmutualsolubilitiesandshowsignificantdifferencesinthethermodynamicstabilityandparabolicgrowthrates .Thus ,copper richalloysformexternalscales…     

高钒高速钢碳化钒形态的数值化分析

针对碳化钒的不同形态,设计出定量分析软件,并利用形状因子K,实现了高钒高速钢不同碳化物形态数值化处理,当K介于0.785～1.000之间碳化钒形态为团球状;K≤0.223,碳化钒呈开花状.高钒高速钢当碳含量达到4.2%时,K为0.86和当量直径D为0.78μm,碳化物呈团球状均匀分布.     

6×××系汽车车身板铝合金的合金化及组织性能的研究

采用力学性能试验和光学金相分析法,研究了Mg和Mn等元素对6×××系汽车板铝合金组织及性能的影响。结果表明:Mg和Mn是提高6×××系汽车板铝合金时效初期硬化值的元素,但对时效初期硬化速度影响不大。提高Mg和Mn含量,合金经170℃30min时效后的强度增大,伸长率降低。合金固溶处理淬火后的晶粒尺寸和形态不随Mg含量而改变,但随Mn含量增加而显著细化。     

工程机械用800MPa低合金高强度钢焊接接头断裂韧性评价

对调质状态800MPa低合金高强度钢及其焊接接头进行了系列温度的断裂韧性测试,讨论不同焊接方法对焊接接头断裂韧性的影响。发现板材的轧制方向对断裂韧性影响显著,LT方向试件的断裂韧性远超过TL方向试件的断裂韧性。在-60℃以上,母材处于上平台延性断裂范畴。在-80℃,裂纹扩展过程中有延脆断裂模式的转变。焊条电弧焊焊缝的断裂韧性与气体保护焊焊缝的断裂韧性相当。尽管常温下焊缝金属的断裂韧性甚至优于母材,但随着试验温度的降低,焊缝金属的断裂韧性迅速下降。在-20℃已发生断裂模式转变,这在结构服役时要引起重视。本研究为大型工程机械的断裂安全评定奠定了基础。     

Research on graphite powders used for HTR-PM fuel elements

Different batches of natural graphite powders and electrographite powders were characterized by impurity, degree of graphitization, particle size distribution, specific surface area, and shape characteristics. The graphite balls consist of proper mix-ratio of natural graphite, electrographite and phenolic resin were manufactured and characterized by thermal conductivity, anisotropy of thermal expansion, crush strength, and drop strength. Results show that some types of graphite powders possess very high purity, degree of graphitization, and sound size distribution and apparent density, which can serve for matrix graphite of HTR-PM. The graphite balls manufactured with reasonable mix-ratio of graphite powders and process method show very good properties. It is indicated that the properties of graphite balls can meet the design criterion of HTR-PM. We can provide a powerful candidate material for the future manufacture of HTR-PM fuel elements.     

基于字典学习的遥感图像去模糊研究

对高分辨率遥感图像进行去模糊是遥感研究中的一个主要难题,针对此提出了一种新的基于稀疏表示的高分辨率遥感图像去模糊算法。该算法利用快速梯度投影算法实现去模糊,并且保留原图像的有用信息。通过对"高分一号"获取的遥感图像进行验证,表明该算法能较好地滤除遥感图像的模糊,提高图像的峰值性噪比,且比其他字典学习算法具有更好的性能。