有机/无机复合透明耐磨薄膜的制备

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质,引入正硅酸乙酯(TEO S)水解产物硅溶胶作为无机增强物,调节两种混合溶液pH值,利用两者羟基之间的共缩聚反应在聚碳酸酯(PC)板表面制备有机/无机复合透明耐磨薄膜;采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。结果表明,KH-570和TEO S水解聚合产物通过共缩聚反应在PC板表面形成带有有机基团的无机交联网络,基本骨架由S i-O-S i组成,经120℃热处理后,薄膜均匀致密,提高了PC板的耐磨性,并有一定的增透作用。     

Hybrid Nanostructures for Energy Storage Applications

Materials engineering plays a key role in the field of energy storage. In particular, engineering materials at the nanoscale offers unique properties resulting in high performance electrodes and electrolytes in various energy storage devices. Consequently, considerable efforts have been made in recent years to fulfill the future requirements of electrochemical energy storage using these advanced materials. Various multi‐functional hybrid nanostructured materials are currently being studied to improve energy and power densities of next generation storage devices. This review describes some of the recent progress in the synthesis of different types of hybrid nanostructures using template assisted and non‐template based methods. The potential applications and recent research efforts to utilize these hybrid nanostructures to enhance the electrochemical energy storage properties of Li‐ion battery and supercapacitor are discussed. This review also briefly outlines some of the recent progress and new approaches being explored in the techniques of fabrication of 3D battery structures using hybrid nanoarchitectures.     

Oriented Multiwalled Organic–Co(OH)2 Nanotubes for Energy Storage

In energy storage materials, large surface areas and oriented structures are key architecture design features for improving performance through enhanced electrolyte access and efficient electron conduction pathways. Layered hydroxides provide a tunable materials platform with opportunities for achieving such nanostructures via bottom‐up syntheses. These nanostructures, however, can degrade in the presence of the alkaline electrolytes required for their redox‐based energy storage. A layered Co(OH)₂–organic hybrid material that forms a hierarchical structure consisting of micrometer‐long, 30 nm diameter tubes with concentric curved layers of Co(OH)₂ and 1‐pyrenebutyric acid is reported. The nanotubular structure offers high surface area as well as macroscopic orientation perpendicular to the substrate for efficient electron transfer. Using a comparison with flat films of the same composition, it is demonstrated that the superior performance of the nanotubular films is the result of a large accessible surface area for redox activity. It is found that the organic molecules used to template nanotubular growth also impart stability to the hybrid when present in the alkaline environments necessary for redox function.     

TLCD基础隔震框架结构的减振控制研究

为了避免和减轻由过大隔震层位移引起的损害,对基础隔震框架结构装设调频液柱阻尼器(tuned liquid column damper,简称TLCD)后混合系统的减振效果进行研究。建立了单层和多层混合控制系统在地震作用下的运动方程,采用TLCD-结构体系转化为调频质量阻尼器(tuned mass damper,简称TMD)-结构体系的等效方法,利用TMD参数优化公式,得到单个TLCD初始设计参数,并采用状态空间方程得到多个TLCD最优设计参数。通过对某8层基础隔震结构进行模拟,证明了该理论设计方法的合理性。该混合结构不仅可以减小隔震层位移和加速度,而且对上部结构位移和加速度反应都能更有效的控制。     

Al-Cu合金片对钢/铝异种金属激光-MIG复合焊接头组织和性能的影响

采用PLC系统控制的激光-MIG复合焊接工艺对Q890钢/6063铝合金进行异种金属焊接,研究了钢侧坡口表面添加Al-Cu合金片对接头显微组织、硬度和拉伸性能的影响。结果表明:激光-MIG复合焊接接头具有典型的熔钎焊特征;未添加Al-Cu合金片的接头界面层由舌状相Fe2Al5和粗大针状相Fe4Al13组成,厚度约18μm,添加Al-Cu合金片后由舌状相(Fe,Cu)2Al5和细小絮状相(Fe,Cu)4Al13组成,厚度约为9μm,焊缝区与热影响区的组织与未添加Al-Cu合金片时的相似;添加Al-Cu合金片的接头界面层硬度比未添加Al-Cu合金片的低约59HV;添加Al-Cu合金片的焊接接头的抗拉强度比未添加Al-Cu合金片的提高了109.8%,未添加和添加Al-Cu合金片的焊接接头均在界面层断裂。     

阻尼模型对混合结构地震耗能分析的影响

本文采用14条地震波对3个不同阻尼模型下的钢框架-钢筋混凝土剪力墙混合结构进行动力时程分析,以了解不同阻尼模型对结构耗能分析的影响,结果表明：阻尼模型的选取对结构总输入能的计算影响不大,但对于滞回耗能在总输入能中所占比例（滞回耗能比）有很大影响。采用刚度比例和瑞雷阻尼模型进行地震耗能分析获得的滞回耗能比随结构自振周期的增大而减小,但质量比例阻尼模型的计算结果受结构周期影响不大;采用刚度比例阻尼模型计算获得的结构滞回耗能比与采用瑞雷阻尼模型相近,随着结构自振周期的增大,瑞雷阻尼模型会略大于刚度比例阻尼模型;采用质量比例阻尼模型计算获得的结构滞回耗能比最大,随着地震波峰值速度与峰值加速度比值（V／A）的增大,刚度比例和瑞雷阻尼模型的计算结果会与质量比例阻尼模型趋于一致。     

Nano-structural Modification of Amorphous Carbon Thin Films by Low-energy Electron Beam Irradiation

CARBON-BASED MATERIALS have been regardedas one of the most important materials in nano-technology.Not only nanotubes and fullerenes but alsoa new form of carbon incorporating distinct graphiticconfigurations in amorphous carbon networks hasrecently attracted extensive interests in order toaccomplish high performances by combining diversephysical properties which arise from carbon structuresfl,2].In particular,the establishment of functionallyhybridized carbon systems with a thin film f…     

Microstructure and mechanical properties of wrought magnesium alloy AZ31B welded by laser-TIG hybrid

The laser-TIG hybrid welding was mainly used to weld the wrought magnesium alloy AZ31B. The tech-nical characteristics of laser-TIG hybrid welding process was investigated and the interactional mechanism between laser and arc was discussed, at the same time the microstructure and mechanical properties of the wrought magnesi-um alloy AZ31B using laser-TIG hybrid welding were analyzed by optical microscope, EPMA, SEM, tensile ma-chine, hardness machine. The experimental results show that the presence of laser beam boosts up the stability of the arc during high speed welding and augments the penetration of weld； the crystal grains of magnesium alloy weld are fine without porosity and cracks in the best welding criterion and the microstructure of HAZ does not become coarse obviously. The elements profile analysis reveals that Mg content in the weld is lower than that of the base metal, but Al content is higher slightly. Under this experimental condition, the wrought magnesium alloy AZ31B joint can be achieved using laser-TIG hybrid process and the tensile strength of the joint is equivalent to that of the base metal.     

Processing of yttria partially stabilized zirconia thermal barrier coatings implementing a high-power laser diode

Several studies have been undertaken recently to adapt yttria partially stabilized zirconia (YPSZ) thermal barrier coating (TBC) characteristics during their manufacturing process. Thermal spraying implementing laser irradiation appears to be a possibility for modifying the coating morphology. This study aims to present the results of in situ (i.e., simultaneous treatment) and a posteriori (i.e., post-treatment) laser treatments implementing a high-power laser diode. In both cases, the coatings underwent atmospheric plasma spraying (APS). Laser irradiation was achieved using a 3 kW, average-power laser diode exhibiting an 848 nm wavelength. Experiments were performed to reach two goals. First, laser post-treatments aimed at building a map of the laser-processing parameter effects on the coating microstructure to estimate the laser-processing parameters, which seem to be suited to the change into in situ coating remelting. Second, in situ coating remelting aimed at quantifying the involved phenomena. In that case, the coating was treated layer by layer as it was manufactured. The input energy effect was studied by varying the scanning velocity (i.e., between 35 and 60 m/min), and consequently the irradiation time (i.e., between 1.8 and 3.1 ms, respectively). Experiments showed that coating thermal conductivity was lowered by more than 20% and that coating resistance to isothermal shocks was increased very significantly.     

光催化氧化法降解有机污染物影响因素及其效率提高途径

分析了催化剂类型、污染物性质、反应条件等因素对光催化氧化法降解有机污染物的影响,从催化剂改性、高效光催化氧化反应器及光催化与其他技术联用等方面探讨了提高光催化氧化效率的途径,展望了光催化氧化法发展前景及其工业化应用时需解决的关键问题。