用偏微分方程构造过渡面

用偏微分方程的构造曲面是一种新兴的方法，本文借若干算例说明如何用偏微分方程构造两已知曲面之间的过渡面。论文着重讨论用四阶方程构造一阶连续的过渡面。     

超临界CO2对钢材的腐蚀实验研究

采用静态高温高压釜及SEM现代分析测试手段,在分析超临界CO2存在形式及与原油、水交互作用的基础上,进行了超临界CO2对钢材的腐蚀实验研究。结果表明,在腐蚀系统SCF-CO2气相中,存在CO2腐蚀现象;液相中,腐蚀速率随压力增加而上升,12MPa达到峰值后下降。在纯水中12MPa时,液相和气相中的腐蚀速率趋于一致,腐蚀形貌表现为腐蚀瘤。30％的原油含量可在液相促进钢材腐蚀。腐蚀形貌表现为腐蚀瘤与腐蚀坑并存;但随含油量增加,会抑制钢材腐蚀。     

保单调插值的奇异混合三角/双曲B样条

为了使得插值曲线保单调,设计了两类新的平面参数曲线及其保单调插值算法.计算奇异混合函数,把三角/双曲多项式B样条曲线与奇异多边形通过奇异混合函数混合,无需解方程组或繁琐的迭代,得到自动插值给定平面点列且C2(或G1)连续的带形状参数的复合曲线,尤其能得到摆线、螺旋线、双曲线、悬链线等各类超越曲线.通过把插值曲线的导矢分量转化为类Bernstein多项式,并且利用Bernstein多项式非负的充要条件,得到插值曲线单调的充要条件,获得形状参数合适的取值范围. 该方法简单方便,所得参数范围保证了插值曲线保单调.     

聚丙烯改性技术进展

介绍了近年来聚丙烯改性技术研究方面的进展．研究内容包括用结晶成核剂对聚丙烯的晶型进行设计，用橡胶、矿物填料等对聚丙烯进行改性．     

The role of castor oil in epoxy and polyamide systems for coating and adhesive application

Summary  Over the past few years, the challenges of globalisation, consolidation and economical point of view have meant that manufacturers of epoxy formulations have to constantly improve their capability to meet the needs of customers. An active area for advancement is that of epoxy and polyamide resin with castor oil. Generally, people working in the coating industries are familiar with castor oil, but this paper provides information on the new use of castor oil in epoxy and polyamide resin. This novel product (castor oil-modified epoxy resin/castor oil-modified polyamide) provides a previously unattainable combination and improved flexibility and toughness to a variety of ambient cure applications. This communication will review the performance of these castor oil-modified epoxy and polyamide resin surface coatings and adhesives. Based on the results of this study, these systems offer some advantages without much affecting the traditional properties of epoxy and polyamide resin in a variety of applications.     

补强剂和共混工艺对PA/PVC/NBR三元共混弹性体性能的影响

在选择三元共聚尼龙（PA）、聚氯乙烯（PVC）、丁腈橡胶（NBR）为主体材料，制备PA／PVC／NBR（10／30／60）三元共混弹性体的工作基础上，进一步探讨了填料品种和用量，共混温度，加料顺序等因素PA／PVC／NBR三元共混弹性体的影响。试验结果表明：在PA／PVC／NBR（10／30／60）共混体系中，补强型填料的补强效果优于非补强型的填料，6种填料补强效果依次是：快压出炭黑＞半补强炭黑＞白炭黑＞活性重质，CaCO3＞陶土＞滑石粉，快压出炭黑的适宜用量是20－50份。在制备PA／PVC／NBR三元共混物时，适宜的共混温度是122－140℃，并且采用二段法混工艺制得的共混物性能优于采用一段法共混工艺。     

IIR/EPDM共混物的物理机械性能

研究了IIR／EPDM并用体系中共混比、硫磺硫化体系以对共混性能的影响。结果表明，IIR与EPDM相容性较好，而且可以达到共硫化；IIR。EPDM质量比为75／25时，共混物的物理机械性能和老化性能较好；用硫黄、低硫高促进剂和无硫硫化体系都得到性能良好的共混物，其中以前者硫化的共混物性能最为突出。     

PEN/PTT共混聚酯的熔融行为

利用差示扫描量热仪对不同配比的聚萘二甲酸乙二醇酯/聚对苯二甲酸丙二醇酯(PEN/PTT)共混体系的熔融行为进行了分析,发现在共混体系中两组分形成各自的晶体,PEN和PTT的熔点均随另一组分含量的增加而下降。根据Nishi-Wang方程,按300℃计算,由PEN/PTT共混体系中PEN熔点下降计算所得到的相互作用能密度为-0．214 2 J/cm~3,相互作用参数为-0．006 8,表明PEN/PTY共混体系在熔融态是热力学性质稳定的相容体系。     

Improvement of polymer blend properties by changing sequence of mixing

The basic objective of this article is to improve the polymer blend properties by changing mixing sequence. Blending of two elastomers does not lead to a molecularly homogeneous blend (true solution), but to a heterogeneous system in which both polymer phases are present. In this article, the detailed study of heterogeneous distribution of carbon black as well as blend inhomogenity and the physicomechanical including dynamic mechanical properties of the blend has been carried out. The choice of the blend was natural rubber/polybutadiene rubber as 85:15. Heterogeneous carbon black distribution study was also performed in differential scanning calorimeter. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2735–2742, 2007     

Crystallization behavior of dry‐brush PEO‐PS block copolymer and PEO homopolymer blend

The crystallization behavior of semicrystalline PEO homopolymer/triblock PS‐PEO‐PS copolymer blend system, which exhibited “Dry‐Brush” in the melt. A symmetric polystyrene–poly(ethylene oxide)–polystyrene triblock copolymer was blended with PEO homopolymer (h‐PEO) having the same molecular weight as that of the PEO block in the copolymer. Considering the composition of the blend (W_ps ≥ 0.8), PEO spheres were formed in the blend. Because of the dry‐brush phase behavior of this blend, h‐PEO added was localized in the PEO microdomains, which increases the domain size without changing the microdomain morphology. The crystallization of PEO block was confined within the microdomains and the crystallization temperature was about 60°C lower than normal. Self‐seeding tests were performed to clarify the nucleation mechanism of the blend. Because the droplets size varies greatly, multicrystallization peaks were witnessed in the self‐seeding process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007