应用溶剂萃取处理金泥的新技术

用溶剂萃取法代替目前广泛使用的金泥处理方法，可以节约资源，降低成本，提高金的回收率，还能回收金泥中的银，产品金的纯度在９９．９％以上；连续作业，操作方便，大大减轻劳动强度和改善工作条件，而且便于自动化操作管理，是一种社会，环境，经济三种效益都佳的成熟技术，应大力推广应用。     

Target differentiation with simple infrared sensors using statistical pattern recognition techniques

This study compares the performances of various statistical pattern recognition techniques for the differentiation of commonly encountered features in indoor environments, possibly with different surface properties, using simple infrared (IR) sensors. The intensity measurements obtained from such sensors are highly dependent on the location, geometry, and surface properties of the reflecting feature in a way that cannot be represented by a simple analytical relationship, therefore complicating the differentiation process. We construct feature vectors based on the parameters of angular IR intensity scans from different targets to determine their geometry and/or surface type. Mixture of normals classifier with three components correctly differentiates three types of geometries with different surface properties, resulting in the best performance (100%) in geometry differentiation. Parametric differentiation correctly identifies six different surface types of the same planar geometry, resulting in the best surface differentiation rate (100%). However, this rate is not maintained with the inclusion of more surfaces. The results indicate that the geometrical properties of the targets are more distinctive than their surface properties, and surface recognition is the limiting factor in differentiation. The results demonstrate that simple IR sensors, when coupled with appropriate processing and recognition techniques, can be used to extract substantially more information than such devices are commonly employed for.     

Interfacial activity and rate of palladium(II) extraction with decyl pyridine monocarboxylates

Decyl isonicotiniate and decyl nicotiniate permit a rapid extraction of palladium(II) from its hydrochloride solutions. Decyl picoliniate is not a suitable extractant. 4-Octylphenylamine can act as a phase transfer catalyst when its concentration in the organic phase is at least 2·5 × 10^?4 M . It seems that the interfacial adsorption of pyridine carboxylates and of 4-octylphenylamine is not the decisive phenomenon in palladium(II) extraction. The negligible protonation of the pyridine-type extractants and the phase transfer catalysis explains well the quick extraction of palladium(II) with the commercial and highly hydrophobic extractant ACORGA CLX-50.     

微波高压提取快速测定饲料含氟量的探讨

采用微波高压制样技术,快速提取饲料中的氟元素,结合氟离子选择性电极标准添加和电位极差测试方法,能够快速、准确地测试饲料中的含氟量     

Influence of solvents on extraction of U(Ⅵ) by N,N'-didecanoylpiperazine

Extraction behavior of N, N'-didecanoylpiperazine (DDPEZ) for U(Ⅵ)in a series of solvents from aqueous nitric acid media was investigated for the first time.The dependence of distribution ratios on the concentration of aqueous nitric acid.extractant and temperature has been discussed. The increasing sequence of extractiveability of DDPEZ is given: chloroform, carbon tetrachloride, dimethylbenzene, toluene,benzene.``     

钇、钪分离工艺的新进展

本文简要介绍中国科学院长春应用化学研究所近年来在钇、钪分离工艺研究方面的新进展。     

混合溶剂对Ru(Ⅳ)萃取的研究

一、前言 在一定浓度盐酸介质中,Ru(Ⅳ)以RuCl_6~(2-)络阴离子状态存在,可被C类溶剂TOA(三辛胺)以离子缔合机制定量地萃入有机相。由实验得到在相同条件下,TOA对Ru(Ⅳ)的萃取率随稀释剂介电常数的增加而下降。     

萃取预分离法分离富铕中钇矿新工艺

采用一种新的串级萃取方式--萃取预分离法分离富铕中钇矿的新工艺.原料首先流入十几的三出口预先粗分离工艺,其萃余液La～Gd(TbDy)直接流入Nd/Sm工艺;中间出口流入(Gd)Tb～HoY(Er)Gd～Dy/Ho～LuY细分离工艺;出口负载有机相(Ho)Er～LuY流入Gd～Dy/Ho～LuY的洗涤段.结果表明,新工艺的粗分离工艺将占原料约70%的La～Gd(TbDy)预分离掉,使流入Gd～Dy/Ho～LuY工艺的稀土量减少约70%;由于Gd～Dy/Ho～LuY分组的萃余液GdTbDy含Ho2O3小于0.03%,省去原工艺的GdTbDy/HoY分离;新工艺的处理能力提高30%,酸碱消耗减少20%以上,贵重稀土元素Eu和Tb的存槽量大大减少.     

碱土金属在萃取剂与树脂间反应平衡常数的测定

研究了碱土金属离子在Ｄ００１树脂与８－羟基喹啉三氯甲烷溶液间的平衡常数Ｏ－ｔＫ的测定。其值依Ｍｇ、Ｃａ、Ｓｒ、Ｂａ次序减小。并得出萃取剂浓度［ＨＡ］。与金属离子在两相分配的关系。