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The purpose of this paper is the modelling of the mechanical behaviour of an elastomeric material, through detailed experimental and numerical procedures, specific to large strains. The experimental technique is based on in-plane kinematics measurements using a speckle extensometer, from which the whole two-dimensional field of in-plane displacements is obtained by a digital image processing [Polymer (2002)]. This part of the work concerns the identification of the constitutive equation for a carbon black natural rubber (NR) vulcanizate. We start by quoting some theoretical considerations relative to rubber elasticity and stress-softening effect, which is the counterpart of the filler reinforcement. Then, we describe the experimental procedure and present data for both non-preconditioned and preconditioned samples. Next, the identification of the constitutive law parameters using a minimization algorithm is driven. Finally, we present the validation of the constitutive model, by its implementation into the finite element code SYSTUS and the numerical simulation of the response of a double edge notched tensile (DENT) specimen. 相似文献
23.
Denis Rodrigue 《加拿大化工杂志》2002,80(2):289-292
Recently, the author (Rodrigue, 2001 a, b) proposed a generalized correlation for the steady rise of gas bubbles in uncontaminated viscous Newtonian fluids of infinite extent. It is the purpose of this note to show that this model can be modified for inelastic non‐Newtonian power‐law fluids. Using data taken from six different studies, it is shown that the modified model can predict quite nicely the bubble velocity for these non‐Newtonian inelastic fluids. 相似文献
24.
Zhang Sheng-ming Yangtze River Scientific Research Institute Wuhan Hubei P. R. China 《水动力学研究与进展(B辑)》1992,(2)
Through a series of model tests of five scales for 2-D free hydraulic jump, the da-ta of fluctuating pressure acting on the floor level within the hydraulic jump were obtained. Dur-ing the experiments, Froude number varied from 2.94 to 8.61, and Reynolds number rangedfrom 2×10~4 to 6×10~5. Experiment results indicate that the amplitude scale of fluctuating pres-sure is the length scale of model, i. e. P'=L, which agrees with gravity similarity law: Thefrequency scale of the fluctuating pressure is a unity i. e., f=1, which does not satisfy thegravity similarity law. 相似文献
25.
The equilibrium CO2 sorption isotherms and isobars for rubbery EVA containing various amounts of vinyl acetate (VA) over a wide pressure range 10-340 atm and 25-52 °C were investigated. The normalized CO2 sorption concentration (in cm3 (STP) CO2/mole VA) isotherms of these polymers as a function of pressure consisted of two distinct regions turning at near Pc. The normalized sorption isotherms in these two distinct regions could be fairly described by two respective power laws: C=KaPna for above Pc and C=kbPnb for below Pc. The normalized CO2 sorption isotherms were found to be about the same for four EVA samples having different VA contents for below Pc, suggesting that the sorption process at below Pc may be mainly driven by the presence of carbonyl groups. At above Pc, the degree of crystallinity of the polymer appeared to be a major factor to affect the sorption process, with the higher the degree of crystallinity, the lower the normalized CO2 sorption concentration in the polymer. The sorption isobars of the polymer as a function of temperature were governed by the interplay of density, viscosity, and diffusivity of CO2 depending on the pressure studied. 相似文献
26.
A generalized diffusion coefficient correlation for a binary system of liquids has been developed to represent the data for a wide range of temperatures. Detailed analysis shows that the proposed correlation fits the experimental measurements of diffusivity with the corresponding calculated values with an acceptable percentage error. 相似文献
27.
Theprecipitationofpro eutectoidferritefromausteniteiscontrolledbydiffusioninFe Calloys .Withtheassumptionthatthemigratinginterfaceisalwaysinlocalequilibrium ,earlyin 194 9,ZenerC[1] explainedthediffusionalgrowthofpro eutec toidferritebyusingtheFick’slaw .Since… 相似文献
28.
Tai-Shang ChenJia-Ming Chern 《Chemical engineering science》2002,57(3):457-467
The network reduction technique and the Bodenstein approximation of quasi-stationary behavior of reaction intermediates were systematically applied to derive general yield ratio and rate equations for multi-cycle reaction networks in homogeneous catalysis. Dual-cycle reaction networks connected by a linear pathway, multi-cycle networks stemming from the same intermediate, and single-cycle with arbitrary number of pathways between two intermediates were considered. The general yield ratio and rate equations derived in this study are applicable for most enzymatic reactions and for homogeneous catalytic reactions. Examples of homogeneous catalysis were used to illustrate the application of the general yield ratio and rate equations for network elucidation. 相似文献
29.
A new method for characterization of stratified thermal energy stores (TES) that integrates both the first law and the second law concerns is presented here. The first law concern is incorporated into a quantity called energy response factor and the second law concern into an entropy generation ratio. A product of these two quantities is at the heart of the TES efficiency definitions. This approach removes the overemphasis of the existing methods either on the first or the second law of thermodynamics which often biases the characterization results. The information about the evolution of the temperature field of the system in time is the prerequisite of the new method. It may be obtained from experiments or from suitable numerical simulations. The current method can be easily integrated into computational fluid dynamic (CFD) simulations and thus facilitate CFD-based design analysis. As an example of such CFD-integrated analysis, a large-scale hot water seasonal heat store is numerically studied to identify the effects of aspect ratio, containment shape, internal structures, and containment size on their efficiency. The results suggest the effectiveness of the new method in deriving useful design insights. 相似文献
30.
JOHANNA C.M. JACOBS† JACQUES H. HOUBEN† TON VAN VLIET‡ PIETER S. VAN ROON† BEREND KROL† 《International Journal of Food Science & Technology》1994,29(3):321-329
A specially designed tube viscometer was used to measure apparent viscosity during flow of Bologna type sausage emulsions moving through a pipe. Emulsions varied in fat content (from 21.8 to 44.3%) and in moisture/protein ratio (from 3.7 to 5.6), and the effects of added sodium chloride, sodium diphosphate, starch and blood plasma were investigated in a 36% fat, 3.7 moisture/protein emulsion.
The shear stresses determined as a function of shear rate were fitted by a power law. Yield stress of the emulsions was negligible relative to the applied stress. However, inspection of the flow profiles indicated that considerable slip of the sausage emulsion occurred at the pipe wall. Both emulsion flow and slip contribute to overall flow behaviour, so a kind of effective viscosity is determined. Intrinsic rheological properties and wall slip will both be affected by the composition of the sausage emulsion. 相似文献
The shear stresses determined as a function of shear rate were fitted by a power law. Yield stress of the emulsions was negligible relative to the applied stress. However, inspection of the flow profiles indicated that considerable slip of the sausage emulsion occurred at the pipe wall. Both emulsion flow and slip contribute to overall flow behaviour, so a kind of effective viscosity is determined. Intrinsic rheological properties and wall slip will both be affected by the composition of the sausage emulsion. 相似文献