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101.
In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C5H4XNH+ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed. 相似文献
102.
本文分析了锌基合金模具制造及使用过程中容易出现热裂、翘曲、收缩的问题,并提出了解决这些问题的措施。 相似文献
103.
104.
Composition Range of Amorphous Mg-Ni-Y Alloys 总被引:1,自引:0,他引:1
Based on the thermodynamic point of view, a method for predication of the composition range of amorphous ter-nary alloys was proposed. The composition range of amorphous ternary alloys is determined by the comparison of the excess free energy of the amorphous alloy and the free energy of competing crystalline states. The free energy is extrapolated from the data of three binary alloys by using Toop‘s model. The method was applied to predict the composition range of amor-phous Mg-Ni-Y alloys. The theoretical results are in good agreement with the available experimental results. It indicates that the present method can be used to predict the composition range for amorphous ternary alloys. 相似文献
105.
M 2highspeedsteel (M 2steel)isamaterialwidelyusedintoolsanddies[1,2 ] .M 2steelischarac terizedbyalongsolidificationrangeandcomplexeu tecticreactions ,whichresultsinsegregationofalloy ingelementsandformationofseveraldifferenttypesofcarbidesduringsolidification[3,4 ] .Forconventionallyprocessedhigh speedsteels ,itisinevitablethatacoarsecarbidenetworkwillbeformedduringsolidifi cation .Coarseprimarycarbidestendtoresultinun evencarbidebandsdistributionafterasubstantialamountofhotprocessing[5] .Ma… 相似文献
106.
Marina Fomina Geoffrey M Gadd 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(1):23-34
The sorption of toxic metals by fungal mycelia grown in clay‐containing medium is reported in this work. Biomass of melanin‐producing microfungi of the genus Cladosporium (C cladosporioides, C resinae and C herbarum) and Aureobasidium pullulans, clay minerals and fungal mycelia grown in clay‐containing medium were compared for their equilibrium Cu and Cd uptake from pH‐buffered solutions using experimental sorption isotherms. Bentonite (Cherkassy) in the natural form was shown to be the best Cu sorbent compared with the other clays and clay minerals tested. Cu sorption isotherms fitted the Langmuir sorption model for all cases. Comparison of Cu and Cd uptake for biomass and bentonite showed a lower biomass uptake capacity but a considerably higher affinity of the biosorbent for the solute. The presence of kaolinite and palygorskite in the medium generally reduced both Cu and Cd sorption capacity and the metal‐binding ability of the fungal–clay mixtures. In contrast, addition of bentonite into the medium did not appreciably alter the Cd sorption ability but increased the sorption of Cu by A pullulans and C cladosporioides grown in this medium. A common feature for all fungi grown in the presence of bentonite was an increase in the Cu sorption capacity (Qmax) of the biomineral sorbents and a reduction in their affinity (Langmuir parameter b) compared with control biomass. A difference between predicted and experimental data obtained for biomass grown on bentonite medium was also observed. The connection between the sorption capacity of biomass grown in clay‐containing medium, mycelial morphology and the structure of fungal pellets is discussed and a mechanism for the changed sorption capacity of the combined biomineral sorbents is proposed which involves blocking or modification of binding sites on biotic and abiotic components of the ‘biomineral’ association. © 2002 Society of Chemical Industry 相似文献
107.
对达县广电城域网运行状况进行了检测,认为不能满足用户上网需要的原因除了网内病毒感染之外,设备与设备之间链路层协商及连接线出现故障。改进措施主要有两点:解决NE08E与S8505的连接问题,解决S8505上的DHCP服务器不能分配IP地址问题。 相似文献
108.
A generic method has been developed for the synthesis of crystalline metal nanowires or nanotubes (such as bismuth nanotubes, tungsten nanowires) from lamellar structures. In a typical process, lamellar surfactant/inorganic composite precursors are first prepared by reacting cationic or anionic surfactants with inorganic species under appropriate conditions. After treating these precursors by hydrothermal pyrolysis, or other processes, crystalline metallic nanotubes or nanowires are obtained. 相似文献
109.
分析了现有移动通信网络存在的问题,阐述了第2代移动通信核心网向第3代移动通信核心网演进的必然性:讨论了第2代移动通信核心网向第3代移动通信核心网演进所采用的演进策略,介绍了两种可供选择的全IP核心网络的参考结构。 相似文献
110.