Molecular weight distributions and size fractionations of H-coal liquids

This Paper deals with a comparative study on the use of gel permeation chromatography (g.p.c.) and vapour pressure osmometry (v.p.o.) to obtain molecular weight data for the hexane-soluble fractions of three H-coal liquids. The use of two types of column packing materials, polyvinylacetate and styrene-divinylbenzene copolymer gels, is described. A successful, preparative use of the polyvinylacetate gel to fractionate the hexane-soluble fraction of H-coal liquid, atmospheric still overhead (ASO), has been established. Molecular weight data obtained by v.p.o. for the benzene-soluble fraction and the pyridine-soluble fraction of the three H-coal liquids are reported. Solvent extraction has been utilized also to find the amount of oil, asphaltenes and asphaltols in the three H-coal liquids.     

Direct Measurement of Transformation Zone Strains in Toughened Zirconia

Residual strains responsible for crack tip shielding have been measured within transformation zones surrounding cracks in Mg-PSZ. Two techniques were used for strain measurement: moiré interferometry and high-resolution image matching. Both methods provide maps of differential in-plane displacements within the specimen surface intersected by the crack, the latter method with the higher resolution. The results are compared with finite-element analysis to assess surface relaxation effects, and the measured strains are used to evaluate the crack tip shielding stress intensity factor. Calculations based on the assumption that the unconstrained transformation strain is hydrostatic dilatation yielded results that were significantly smaller than the measured toughness increases.     

关于控制氯代烃的政策选择

本文分析了氯代烃的生产所引起的环境问题,并提出了减少氯代烃环境影响的政策选择的基本原则。     

Viscoelastic properties of cellulose derivatives: 1. Cellulose acetate

The dynamic mechanical spectrum of cellulose acetate (CA) from −130°C to 240°C has been determined at different frequencies (from 0.1 to 30 Hz). Three relaxations, designated , β and γ in order of decreasing temperature, and one shoulder (β*) above room temperature were found. Comparison with calorimetric and thermogravimetric measurements yields the conclusion that the relaxation (197°C at 3 Hz) is related to the glass-to-rubber transition and the β* shoulder (50°C–100°C) is due to loss of moisture. The β relaxation (−38°C at 3 Hz, ΔH = 100 kJ mol⁻¹) is tentatively assigned to local motions of the main chain (glucopyranose rings). The low-temperature γ relaxation (−88°C at 3 Hz, ΔH = 46 kJ mol⁻¹), is humidity-dependent: its intensity decreases when the samples are dried to moisture contents lower than that obtained by normal room conditioning (about 3%). Higher water contents shift the relaxation to lower temperatures without increasing the intensity of the mechanical loss. It is suggested that water associated with the unesterified methylol groups of cellulose acetate is responsible of the dynamic mechanical γ dispersion.     

基于主成分分析中的几类问题的计算公式及结论

讨论了主成分分析中的几类问题的计算方法,重点揭示在协方差矩阵中对角元素相同时的第一主成分及贡献率和对角元素不同时的主成分贡献率．经讨论后给出有关计算公式,并说明这些计算公式在多元统计分析中的实际作用     

梁端翼缘扩大型梁柱节点抗震性能和设计方法

为使钢框架梁柱节点满足强柱弱梁的抗震设计原则,并使梁上塑性铰远离梁柱节点区,对梁端翼缘扩大型(包括侧板加强型和翼缘端部放大型)钢框架梁柱节点进行了往复荷载下的试验研究,得到了节点类型和梁端翼缘扩大尺寸对节点滞回性能、延性和耗能能力等指标的影响规律.在使用非线性有限元程序对试验结果进行数值模拟的基础上,研究了梁端翼缘扩大段的长度及宽度等参数对节点性能的影响规律和有效取值范围,给出了实用设计方法.使用梁端翼缘扩大型钢框架节点可以有效实现梁端塑性铰外移,是一种在抗震设计中值得推广的具有良好延性和塑性转动能力的新型节点形式.     

道路交通状态预测研究

针对道路交通状态预测的研究成果,综述了基于实时数据分析的道路交通状态预测理论和方法的相关研究.从分析基于实时数据分析的道路交通预测的基本流程、特点和要求和单一断面交通状态预测和多断面交通状态预测角度回顾了道路交通状态预测的研究现状.结果表明:在不断发展完善单一断面预测方法的同时,需要发展以多个断面交通状态为研究对象的多断面预测方法,以促进我国智能交通系统的基础理论发展及其应用水平的提高.     

有侧移半刚性连接组合框架柱的稳定分析

为了研究有侧移半刚性连接组合框架的稳定性能,利用三柱子框架模型,考虑了梁端和柱远端不同约束情况对柱有效长度系数的影响,提出柱有效长度系数的简化方法.通过算例研究了节点的非线性弯矩-转角关系和荷载水平大小对柱有效长度系数的影响,比较了简化方法、Barakat-Chen方法与精确方法的计算结果.研究表明:简化方法比Barakat-Chen方法有更好的精确度,与精确方法计算结果接近.     

用指针实现的程序的标准化及其应用

为了消除指针程序实现形式的多样化,简化程序分析,提出一种对用指针实现的程序进行标准化的方法.首先将程序表示成系统依赖图,分析指针别名信息;然后制定指针标准化规则并结合已有的代码多样化消除规则,对系统依赖图进行保持语义不变的转换,将语法表示不同但语义等价的程序转换为相同的系统依赖图表示,从而消除代码多样化.最后,将该方法应用到C语言编程题的自动评分系统中,并与人工评分和正确评分结果进行对比,验证了该方法的有效性.