Study on the performance of Cd2+ sorption using dimethylethylenediamine-modified zinc-based MOF (ZIF-8-mmen): optimization of the process by RSM technique

ABSTRACT

Cadmium as a highly toxic metal is released into the environment through paper production, metal processing, phosphate fertilizers, insecticides, and treatment of wastewater. Cadmium also inhibits the body activities and is very toxic for kidney and other organisms. In the current study, zinc-based metal–organic framework, zeolitic imidazolate framework (ZIF)-8, was synthesized and modified by dimethylethylenediamine (ZIF-8-mmen) for the removal of cadmium. To optimize the experiments, response surface methodology was applied with three variables including pH, adsorbent dosage, and contact time using central composite design. The optimum conditions for pH, dosage, and time were 2, 0.1 g, and 89 min, respectively, with removal efficiency of 85.38%. The Langmuir isotherm (q _m = 1000 mg/g) indicates the monolayer adsorption. The kinetic studies reveal that the Lagergren model was predominant and cadmium was not chemisorbed. Thermodynamic parameters show spontaneous, endothermic, and physisorption processes.     

Effect of SiO2 addition on the dielectric properties and microstructure of BaTiO3-based ceramics in reducing sintering

The effect of SiO2 doping on the sintering behavior,microstructure,and dielectric properties of BaTiO3-based ceramics has been investigated.Silica was added to the BaTiO3-based powder prepared by the solid state method with 0.075mo1%,0.15mo1%,and 0.3mo1%,respectively.The SiO2-doped BaTiO3-based ceramic with high density and uniform grain size were obtained,which were sintered in reducing atmosphere.A scanning electron microscope,X-ray diffraction,and LCR meter were used to determine the microstructure as well as the dielectric properties.SiO2 can form a liquid phase belonging to the ternary system of BaO-TiO2-SiO2,leading to the formation of BaTiO3 ceramics with high density at a lower sintering temperature.The SiO2-doped BaTiO3-based ce-ramics can be sintered to a theoretical density higher than 95% at 1220℃ with a soaking time of 2 h.The dielectric constants of the sample with 0.15mo1% SiO2 addition sintered at 1220℃ is about 9000.Doping with a small amount of silica can improve the sinter-ing and dielectric properties of BaTiO3-based ceramics.     

大学生创业支持系统的构建研究

剖析和梳理了大学生创业的内、外部环境的利弊因素,建构了以政府、社会、高校等为主体,以创业教育、创业政策、创业资金、创业服务等为支撑的＂三主体、四维度＂的大学生创业支持系统,并探讨了＂发掘优势,规避障碍＂的多维路径。     

高速镗孔技术在压路机零件加工中的应用研究

针对深长孔加工的同轴度问题,通过分析高速调头镗的效率和加工精度,论述了调头镗孔工艺方法在压路机铰接架零件加工中的应用及高速加工的可行性.     

磁控溅射AI／Pb纳米多层膜调制结构研究

用磁控交替沉积制备Al／Pb纳米多层膜,运用XPS,AFM,TEM考察表面状况及膜结构．结果表明,实验条件下,当Al层厚60nm时,Pb子层标定厚度从20nm增至30nm,可形成较完整埋层调制结构．随Pb层厚度增加,连续性变好、表面糙度降低,Al层对Pb层表面糙度克服能力提高,改善层状结构完整性．多层膜中Al,Pb子层均存在（111）择优取向特征,由fcc结构的表面自由能最小化引起．     

框架的行置换和列置换——处理复杂系统的新思维系列之四

本系列论文基于《多边矩阵理论》,由东方整体性思维所启迪,试图提供并完善一套从整体到局部处理复杂系统多指标问题、非均匀性问题、非线性问题的强有力的数学工具,并对其进行严格的理论推导和证明。本文利用群论的相关概念和结论,将其和框架的剖分运算相结合,引入了导出框架和对称框架的定义,证明了框架的行置换等价于列置换的结论,从而以后可以统一地处理指标间的置换问题。     

基于多层动态索引的相似炉型检索方法研究

针对炉型设计涉及的原始数据量庞大,合理炉型的界定范围广,界限模糊等问题,提出应用基于实例的推理方法辅助炉型初始方案的生成.分析了高炉炉型设计的特征属性,并建立了层次结构,针对其特征索引较多,权重系数小,检索效率低等问题,建立一种多层动态索引策略来改进传统的最近邻法,实现了炉型初始设计方案的智能生成.从而提高了相似实例检索的准确性和有效性,为后续对比调整提供了具有可比性和高参考价值的设计方案.     

.NET设计模式在粮食收发业务管理系统中的应用研究

粮食收发业务管理系统在.NET3.5平台上采用了分层架构、单件、简单工厂、策略等设计模式进行设计,不仅满足了基本的粮食收发业务管理需求,同时大大提高了系统的可扩展性和易维护性,缩短同类软件的开发周期,为提高系统的通用性和可重用性提供了一种思路和方法.     

混合测试框架的研究与实现

为有效解决NP(网络处理器)仿真器测试问题,研究了自动化测试框架的原理与技术.针对NP仿真器的特点,基于混合测试驱动框架,提出了一种简单的测试框架.只需编写少量脚本即可实现复杂的测试.测试框架降低了测试成本,提高了效率和质量.     

DCAM平台下的分布式方面构件模型及协同框架的研究*

由于方面化中间件平台DCAM的方面内核实现机制没有提供对分布式环境下方面构件通信的支持,扩展了DCAM中方面内核的方面调用机制,提出了分布式方面构件模型以及分布式环境下方面构件的协同框架。扩展后的DCAM平台不仅保持了原平台对POJO的支持,同时通过对分布式协同框架的引入,使平台在分布式环境下具有更好的可扩展性和容错性,满足了按需计算的需求。最后通过应用实例对DCAM的分布式模型进行了可行性验证并给出了性能分析。