GTL 工艺技术评述

介绍了1990年以来GTL工艺技术开发的进展情况，其中以Sasol-SSPD和Syntruleum两种工艺最受关注，从现有数据分析。Syntruleum虽采用含氮合成气生产工艺，但并未使装置的单位投资明显改善，因此，近10年来GTL工艺技术开发虽取得了长足的进步，但其装置投资仍偏高，从而又严重影响了产品成本，按南非Sasol公司的经验。开展资源综合利用是降低液体燃料生产成本的有效途径，目前国外GTL工艺技术的开发仍很活跃，我国也已形成大量实验室成果。建议尽快组织力量完成工业性试验。     

Simulation of Natural Depletion and Miscible Gas Injection Effects on Asphaltene Stability in Petroleum Reservoir Fluids

Natural depletion of petroleum reservoirs as well as gas injection for enhance oil recovery, are unavoidable processes in the oil industry. Foremost, prediction of the problems due to these two processes is very necessary and important. So many field and experimental experiences have shown that heavy organic depositions, especially asphaltene deposition, are principal results during these processes. Results of laboratory simulation of asphaltene deposition during the natural depletion of petroleum reservoirs and also during gas injection and enhanced oil recovery (EOR) processes are reported here. This is achieved through the design of a new experimental setup for the investigation of pressure and composition effects on asphaltene deposition in petroleum fluids at high pressure and high temperature conditions. In this work, asphaltene deposition during decreasing pressure, from pressures greater than reservoir pressure to pressures below the bubble point pressure (natural depletion) and also asphaltene deposition during natural gas injection in reservoir conditions, are studied for three samples—one recombined sample and two bottomhole samples. All of the obtained results from this work conform to theoretical and other experimental works.     

The importance of information localization in scene gist recognition.

People can recognize the meaning or gist of a scene from a single glance, and a few recent studies have begun to examine the sorts of information that contribute to scene gist recognition. The authors of the present study used visual masking coupled with image manipulations (randomizing phase while maintaining the Fourier amplitude spectrum; random image structure evolution [RISE]; J. Sadr & P. Sinha, 2004) to explore whether and when unlocalized Fourier amplitude information contributes to gist perception. In 4 experiments, the authors found that differences between scene categories in the Fourier amplitude spectrum are insufficient for gist recognition or gist masking. Whereas the global 1/f spatial frequency amplitude spectra of scenes plays a role in gist masking, local phase information is necessary for gist recognition and for the strongest gist masking. Moreover, the ability to recognize the gist of a target image was influenced by mask recognizability, suggesting that conceptual masking occurs even at the earliest stages of scene processing. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

某抽水蓄能电站地下厂房动力特性研究

抽水蓄能电站具有高水头、大容量、快转速的特点导致振动问题特别突出,强烈的振动会导致机组以及厂房薄弱结构部位发生破坏,影响电站的安全稳定运行。结合某在建抽水蓄能电站,分析了可能与厂房结构发生共振的振源,研究了边界条件、材料特性对结构自振特性的影响,结合粘弹性人工边界条件,分析了在机组动荷载作用下厂房各部位的动力响应规律。     

Mechanical procedure for proof construction via closed terms in typed λ calculus

In this paper is presented an algorithm for constructing natural deduction proofs in the propositional intuitionistic and classical logics according to the analogy relating intuitionistic propositional formulas and natural deduction proofs, respectively, to types and terms of simple type theory. Proofs are constructed as closed terms in the simple typed calculus. The soundness and completeness of this method are proved.     

饮用水中天然有机物的分析与表征方法

天然有机物(NOM)是一类分布广泛、成分复杂的有机混合物,可严重影响饮用水的处理效率,并可能对出水水质产生严重的不利影响。因此,为了改进和优化饮用水的处理过程,在研究和实际应用阶段对NOM进行表征和定量以了解其结构特性和反应性具有重要意义。文中先对NOM的富集方法进行了介绍,接着梳理了不同分离方法的依据及作用,最后总结了各类表征方法的原理及应用,以期有助于对NOM和饮用水处理的深入研究。     

关于输气管线内衬聚乙烯管可防止其腐蚀的商榷

本文参照德国一实例，即利用多种类型PE衬层，在一定温差及有气体扩散阻挡层和无气体扩散阻挡层的条件下，详细地叙述了高压酸性气体对其进行长期渗透作用的试验。结果显示：水蒸气和腐蚀性气体（如H2S）的渗透作用是不能忽视的，甚至当PE层为5mm时亦有一定渗透性；此外，在衬层底部尚产生了化学腐蚀作用，从而促使人们必须考虑须正确选择PE下边的防腐底层。     

The Role of Chronic Inflammation in Various Diseases and Anti-inflammatory Therapies Containing Natural Products

Chronic inflammation represents a long-term reaction of the body's immune system to noxious stimuli. Such a sustained inflammatory response sometimes results in lasting damage to healthy tissues and organs. In fact, chronic inflammation is implicated in the development and progression of various diseases, including cardiovascular diseases, respiratory diseases, metabolic diseases, neurodegenerative diseases, and even cancers. Targeting nonresolving inflammation thus provides new opportunities for treating relevant diseases. In this review, we will go over several chronic inflammation-associated diseases first with emphasis on the role of inflammation in their pathogenesis. Then, we will summarize a number of natural products that exhibit therapeutic effects against those diseases by acting on different markers in the inflammatory response. We envision that natural products will remain a rich resource for the discovery of new drugs treating diseases associated with chronic inflammation.     

Screening of Inhibitors Targeting Heat Shock Protein 47 Involved in the Development of Idiopathic Pulmonary Fibrosis

Heat shock protein 47 (HSP47), a collagen-specific molecular chaperone, is causally related to fibrotic diseases, including idiopathic pulmonary fibrosis. The identification of Compounds that interfere with the HSP47-collagen interaction is essential for the development of relevant therapeutics. Herein, we prepared human HSP47 as a soluble fusion protein expressed in E. coli and established an assay system for HSP47 inhibitor screening. We screened a natural and synthetic Compound library established at Nagasaki University. Among 1023 Compounds, 13 exhibited inhibitory activity against human HSP47, of which three inhibited its function in a dose-dependent manner. Epigallocatechin-3-O-gallate, one of these three Compounds, is a typical polyphenol Compound derived from tea leaves. Structurally related Compounds were synthesized and examined for their activity, revealing a hydroxyl group at A-ring position 5 as important for its activity. The present findings provide valuable insight for the development of natural product-derived therapeutics for fibrotic diseases, including idiopathic pulmonary fibrosis.     

Natural Polysaccharides as Multifunctional Components for One-Step 3D Printing Tough Hydrogels

Natural polysaccharides (NPS) are regarded as biomolecular and structural components for preparing high-performance tough hydrogels. But the one-step fabrication of NPS-containing hydrogels in seconds and the template-free design of complicated high-resolution structures are still significant challenges in this field. To meet these requirements, various NPS-containing tough hydrogels are fabricated and processed into 2D/3D structures via the combination of Ru(bpy)₃²⁺-mediated photochemistry and extrusion 3D printing technique. The whole fabrication process is one-step, completed in tens of seconds under visible light irradiation. It is found that the used NPS plays a key role in achieving the fabrication of high-performance structured tough hydrogels. The high reactivity of functional groups in the used NPS can shorten their gelation times. Long rigid chains of the used NPS, their hierarchical assemblies, and contrasting multinetworks benefit from the efficient dissipation of mechanical energy and enhancement of its operational stability. Strong supramolecular interactions enable hydrogel precursors to have high viscosities, therefore providing good controllability to design high-resolution and complicated tough hydrogel structures via extrusion 3D printing. It is anticipated that this straightforward fabrication strategy and findings will open new horizons for NPS-containing materials.