Synthesis of polypropylene‐graft‐maleic anhydride compatibilizer and evaluation of nylon 6/polypropylene blend properties

Polymer blends based on polyolefins are of a great interest owing to their broad spectrum of properties and practical applications. However, because of poor compatibilities of components, most of these systems generally exhibit high interfacial tension, a low degree of dispersion and poor mechanical properties. It is generally accepted that polypropylene (PP) and nylon 6 (N6) are not compatible and that their blending results in poor materials. The compatibility can be improved by the addition of a compatibilizer, and in this study PP was functionalized by maleic anhydride (MAH) in the presence of an optimized amount of dicumyl peroxide (DCP). The reaction was carried out in the molten state using an internal mixer. Then, once the compatibilizer polypropylene‐graft‐maleic anhydride (PP‐g‐MAH) was prepared, it was added at various concentrations (2.5–10 wt%) to 30/70 glass fibre reinforced N6 (GFRN6) PP, and the mechanical properties were evaluated. It was found that the incorporation of the compatibilizer enhanced the tensile properties (tensile strength and modulus) as well as the Izod impact properties of the notched samples. This was attributed to better interfacial adhesion as evidenced by scanning electron microscopy (SEM). The optimum in these properties was achieved at a critical PP‐g‐MAH concentration. Copyright © 2005 Society of Chemical Industry     

Morphology development in polyethylene/polystyrene blends: the influence of processing conditions and interfacial modification

The influence of processing conditions and interfacial modification on the morphology evolution and the composition range within which fully co‐continuous high density polyethylene/polystyrene blend structures can exist during blending in a single screw extruder was studied. Blends ranging from pure A to pure B component, with and without compatibilizer, were prepared under two different shear rates. It was found that high shear rates displaced the breakdown–coalescence balance of the dispersed nodules to the side of coalescence, narrowing the percolation domain and the critical composition for full co‐continuity decreased with increasing shear rates. The addition of a tri‐block compatibilizer induced the percolation threshold of the polystyrene phase to begin at lower percentages of polyethylene but the phase inversion point did not change. The experimental results are discussed in the light of various theoretical models. Copyright © 2005 Society of Chemical Industry     

降低过滤机滤饼水分和细粒煤脱水浅析

根据对选煤厂细粒煤样的实验室优化脱水试验、工业试验及分析结果 ,对真空系统、气水分离器和分配头实施了技术改造 ,细粒煤脱水系统的运行状况得到显著改善 :圆盘真空过滤机滤饼水分降到 2 0 %左右 ,脱饼率在 95 %以上 ,每年的直接经济效益可达 30 0多万元     

Dynamic photorheological analysis of photopolymerizable urethane dimethacrylate resins with varying diluent content and light fluence

The in situ measurement of dynamic changes in viscosity induced by illumination has been performed on a range of photosensitive urethane dimethacrylates (UDMA) evaluating the response at three different illuminations intensities (1, 2, and 5 W cm^?2) and at three different diluent concentrations (15, 30, and 50%), using 1,6‐hexanediol dimethacrylate (HDDMA). The initial viscosity value ranged between 1 and 10 Pa s for the mixtures with final viscosities approaching 1 × 10⁷ Pa s after illumination. The initial rise in viscosity was analyzed using an exponential model with an exponent ranging from 1.0 to 2.5 with time under exposure. Higher conversion rates were observed with both higher intensity and lower HDDMA content. The analytical approach taken here could aid in developing more sophisticated models that consider simultaneous flow and cure advancement in other thermosets. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

铸造湿型小件缺陷产生的原因与控制

通过对铸造湿型小件产品缺陷典型实例的原因分析，从型砂的选择及配制、造型工艺、浇注工艺等方面提出控制缺陷产生的工艺方法。     

首钢2号高炉的技术进步

介绍首钢2号高炉大修采用的新技术、开炉操作和投产以来的生产情况。     

云台山隧道进口黄土段施工技术

从防排水、边仰坡支护、洞口加固、洞内超前支护、钢拱架锚喷联合支护等方面详细介绍了云台山隧道进口黄土段的施工技术,总结了该隧道的施工效果,强调了黄土隧道施工中防排水超前支护预注浆、施工监控的作用,积累了隧道施工经验.     

"摩圣"技术在空气压缩机上的应用

介绍了4L-20/8型空气压缩机采用"摩圣"技术后的运行情况。"摩圣"技术在设备正常运行条件下能成功修复摩擦副的磨损,使之恢复原设计的尺寸和要求,因而提高了生产效率,取得了显著的经济效益。     

高职高专现代教育技术管理体制之我见

本文从教育技术的含义和发展的历史出发，分析目前高职高专院校的教育技术管理体制现状，提出应建立完善的教育技术管理体制，以推进教育技术工作的协调发展。