共轭高分子三阶非线性光学材料

概述了ｎ－共轭高分子材料的三阶非线性光学性质，着重讨论了化学结构对其光学非线性的影响，说明了ｎ－共轭聚合物的三阶非线性极化率主要取决于共轭主链的结构，侧链取代基的变化对其非线性影响不大，文中展望了共轭高分子材料在集成光学中的应用前景。     

Fluctuation X-ray microscopy: a novel approach for the structural study of disordered materials

Measuring medium‐range order is a challenging and important problem in the structural study of disordered materials. We have developed a new technique, fluctuation x‐ray microscopy, that offers quantitative insight into medium‐range correlations in disordered materials at nanometre and larger length scales.In this technique, which requires a spatially coherent x‐ray beam, a series of speckle patterns are measured at a large number of locations in a sample using various illumination sizes. Examination of the speckle variance as a function of the illumination spot size allows the structural correlation length to be measured. To demonstrate this technique we have studied polystyrene latex spheres, which serve as a model for a dense random‐packed glass, and for the first time have measured the correlation length in a disordered system by fluctuation X‐ray microscopy. We discuss data analysis and procedures to correct for shot noise and detector noise. This approach could be used to explore medium‐range order and subtle spatial structural changes in a wide range of disordered materials, from soft matter to nanowire arrays, semiconductor quantum dot arrays and magnetic materials.     

A study of the static and dynamic properties of side-chain liquid crystalline polymers in low molar mass mesogens

The static and dynamic properties of solutions of a side chain polysiloxane liquid crystal polymer have been studied in a cyanobiphenyl nematic host as a function of concentration and temperature. Refractive index measurements were carried out on aligned samples and the data used to determine the macroscopic order parameter, S, using Haller's method. Photon correlation spectroscopy has been used to measure ($\text{k}{}_{22}\text{γ}{}_1$) for the pure nematic solvent and the solutions. From these measurements it appears that the static properties vary slowly and linearly with increasing polymer concentration whilst the dynamic or viscoelastic properties change markedly. This change has been attributed to γ₁, the twist viscosity, and the results have been discussed in terms of the function of the siloxane polymer backbone.     

Kerr介质中"耦合双原子-单模光场"模型的反聚束效应

利用全量子理论,研究了在Kerr介质中,耦合二能级双原子与单模光场相互作用过程的反聚束效应,着重讨论了Kerr介质对场的二阶相干度的影响,并揭示了初始场强及原子间耦合系数的变化与场的二阶相干度的关系。     

Design of internal model control based fractional order PID controller

This article presents a design of the internal model control(IMC)based single degree of freedom(SDF) fractional order(FO)PID controller with a desired bandwidth specification for a class of fractional order system(FOS). The drawbacks of the SDF FO-IMC are eliminated with the help of the two-degree of freedom(TDF)FO PID controller. The robust stability and robust performance of the designed controller are analyzed using an example.     

基于VC的自动配料系统研究

伴随着科技的日益进步、控制理论的不断的研究与发展,结合当今科技的先进技术,目前传统的自动配料控制系统将面临规模化、信息化、高效化的严峻挑战。在自动配料系统生产过程中,涵盖了工业控制技术的各个领域,包括现场总线技术（ProFieldbus）、网络及通信技术、工业控制技术、数据库技术和机电技术等技术。     

Bicriteria scheduling of a material handling robot in an m-machine cell to minimize the energy consumption of the robot and the cycle time

This study considers a flowshop type production system consisting of m machines. A material handling robot transports the parts between the machines and loads and unloads the machines. We consider the sequencing of the robot moves and determining the speeds of these moves simultaneously. These decisions affect both the robot’s energy consumption and the production speed of the system. In this study, these two objectives are considered simultaneously. We propose a second order cone programming formulation to find Pareto efficient solutions. We also develop a heuristic algorithm that finds a set of approximate Pareto efficient solutions. The conic formulation can find robot schedules for small cells with less number of machines in reasonable computation times. Our heuristic algorithm can generate a large set of approximate Pareto efficient solutions in a very short computational time. Proposed solution approaches help the decision-maker to achieve the best trade-off between the throughput of a cell and the energy efficiency of a material handling robot.     

一种DVE中通用的因果消息序时间管理分布式中间件

对于遵循高层体系结构(HLA)标准构建的分布式虚拟环境(DVE),时间管理服务的性能将直接影响分布式仿真的效率和正确性。目前的时间管理服务实现了两种消息排序机制:接收序和时戳序。接收序对消息按其接收顺序进行处理,实时性高,但无法正确处理接收顺序与产生顺序相违背的消息;时戳序通常指保守时戳序机制,能对消息按其产生的时间顺序进行处理,但时间开销较大,难以到达DVE的实时性要求。因此,本文以分布式中间件的方式为DVE设计实现了一种因果消息序时间管理服务,提供符合HLA标准的程序接口,使分布式仿真应用在不改变原有调用接口的情况下,能够通过中间件对消息实现因果序时间管理。实验表明,使用该中间件可以有效维护消息的处理顺序,同时时间开销小,能够较好地满足DVE的实时性要求。     

Aluminum. II. Derivation of C v0from C p and comparison to C v0 calculated from anharmonic models

The specific heat at constant pressure, C _p, of aluminum measured by Ditmars, Plint, and Shukla has been reduced to the volume V ₀ appropriate for 0 K employing the Murnaghan equation. The C _v0 thus obtained is compared with the theoretical C _v0 calculated in the harmonic and the lowest-order anharmonic approximation from three different pseudopotentials (Harrison, Ashcroft, and Dagens-Rasolt-Taylor) as well as a phenomenological Morse potential. The higher-order ( ⁴) anharmonic contributions are calculated from the same nearest-neighbor Morse potential as in the lowest-order anharmonic theory. The role of the vacancy and the higher-order anharmonic contributions to C _v0 has been examined and we conclude that the ⁴ contributions to C _v0 are much smaller than the vacancy contribution. After removal of the vacancy contribution, the reduced C _v0 is found to be in excellent agreement with the Ashcroft and Harrison pseudopotentials as well as the Morse potential including the ² and ⁴ contributions to C _v0.     

丁腈橡胶硫化反应动力学研究

设计了促进剂A 4种不同用量的丁腈橡胶配方;基于配方,先利用密炼机将丁腈橡胶、硬脂酸和ZnO混炼,再利用开炼机加入硫黄、促进剂和防老剂,再利用无转子硫化仪分别测试了160℃、170℃和180℃下胶料硫化曲线;基于硫化曲线计算出了每组配方胶料硫化反应速率常数K和活化能Ea。结果表明,在焦烧期时,NBR硫化反应为非一级反应,真正的一级反应开始于硫化速率达到最大时,即tdis;焦烧期后的反应可分为2个阶段且遵循一级动力学反应规律。