Decomposition of nitric oxide over perovskite oxide catalysts: effect of CO2, H2O and CH4

Direct nitric oxide decomposition over perovskites is fairly slow and complex, its mechanism changing dramatically with temperature. Previous kinetic study for three representative compositions (La_0.87Sr_0.13Mn_0.2Ni_0.8O_3−δ, La_0.66Sr_0.34Ni_0.3Co_0.7O_3−δ and La_0.8Sr_0.2Cu_0.15Fe_0.85O_3−δ) has shown that depending on the temperature range, the inhibition effect of oxygen either increases or decreases with temperature. This paper deals with the effect of CO₂, H₂O and CH₄ on the nitric oxide decomposition over the same perovskites studied at a steady-state in a plug-flow reactor with 1 g catalyst and total flowrates of 50 or 100 ml/min of 2 or 5% NO. The effect of carbon dioxide (0.5–10%) was evaluated between 873 and 923 K, whereas that of H₂O vapor (1.6 or 2.5%) from 723 to 923 K. Both CO₂ and H₂O inhibit the NO decomposition, but inhibition by CO₂ is considerably stronger. For all three catalysts, these effects increase with temperature. Kinetic parameters for the inhibiting effects of CO₂ and H₂O over the three perovskites were determined. Addition of methane to the feed (NO/CH₄=4) increases conversion of NO to N₂ about two to four times, depending on the initial NO concentration and on temperature. This, however, is still much too low for practical applications. Furthermore, the rates of methane oxidation by nitric oxide over perovskites are substantially slower than those of methane oxidation by oxygen. Thus, perovskites do not seem to be suitable for catalytic selective NO reduction with methane.     

Advancements in the design and validation of an air pollution integrated assessment model for Spain

This paper describes the design and application of the Atmospheric Evaluation and Research Integrated model for Spain (AERIS). Currently, AERIS can provide concentration profiles of NO₂, O₃, SO₂, NH₃, PM, as a response to emission variations of relevant sectors in Spain. Results are calculated using transfer matrices based on an air quality modelling system (AQMS) composed by the WRF (meteorology), SMOKE (emissions) and CMAQ (atmospheric-chemical processes) models. The AERIS outputs were statistically tested against the conventional AQMS and observations, revealing a good agreement in both cases. At the moment, integrated assessment in AERIS focuses only on the link between emissions and concentrations. The quantification of deposition, impacts (health, ecosystems) and costs will be introduced in the future. In conclusion, the main asset of AERIS is its accuracy in predicting air quality outcomes for different scenarios through a simple yet robust modelling framework, avoiding complex programming and long computing times.     

基于相位调制器倍频技术产生56GHz毫米波的光载无线通信系统

提出并实验研究了一种基于光相位调制器(PM)倍频技术产生56GHz毫米波的光载无线通信(RoF)系统。在中心站,通过28GHz射频(RF)信号驱动PM产生了56GHz光毫米波,并将下行的2.8Gb/s开关键控(OOK)信号调制到该光载波上,然后经过20km标准单模光纤(SSMF)传输至基站,最后由天线进行发射。用户终端接收后,采用相干解调恢复出基带信号。实验结果表明,56GHz光载毫米波信号经SSMF传输20km后其功率代价小于1dB,通过无线方式传输1.1m后其功率代价小于2.5dB。     

Bezier三角曲面凸性的证明

Bezier曲面造型是计算机图形学的重要研究方向,在实际工作中有着非常广泛的应用.讨论了二次及三次Bezier三角曲面凸性的充分必要条件,这些条件对于控制曲面造型中的保凸性有重要意义.     

副井提升系统安全回路及上位机优化改造

针对煤矿副井提升系统安全回路软硬件及上位机中存在的不足进行了优化改造,改进了过卷试验方式,将闸系统紧停信号引入安全回路,并将安全回路各节点状态信号引入RSView32人机界面,实时显示安全回路状态;根据现场检修需要,在上位机增加了复位显示功能及行程偏差大报警信号。实际应用表明,该优化改造可迅速定位故障节点,实现软硬件互查。     

快速卷积算法的综述研究

卷积神经网络是深度学习算法应用最广泛的方向之一,目前卷积神经网络的应用不仅仅是停留在科技领域,已经扩展到医学、军事等领域,并且已在相关领域发挥着巨大的作用。卷积是卷积神经网络中最为核心的一部分,卷积运算占整个网络70%以上的时间,所以针对卷积运算的加速研究就显得十分重要。首先介绍近年来的卷积算法,并对其复杂度进行分析,总结了这些算法各自的优点和不足,最后对其理论研究和应用领域可能存在的突破进行了探讨和展望。     

QoE-driven voice quality evaluation model of VoIP based on network simulation

The quality of experience (QoE) evaluation model for voice over IP (VoIP) service is studied to analyze the impact of network parameters on voice quality and monitor voice quality in real-time for operators. Firstly, the influence of some network parameters on the voice quality of VoIP is investigated. Then, a simulation platform for VoIP transmission is built to collect voice data under different network enviornments. According to the simulation results, a new mapping model between these arguments and VoIP voice quality is deduced. Finally, the accuracy of this voice quality evaluation model is examined and the results demanstrate that it has high reliability and feasibility.     

空气预热器漏风控制装置常见问题分析及改进

针对空气预热器机械传感器漏风控制系统的常见故障进行了详细分析,并提出了具体解决方案,通过机组大修对漏风控制装置进行技术改造后,消除了影响漏风控制装置正常运行的重大故障,解决了空预器漏风控制系统运行时对于间隙测量的准确性问题,完善了漏风控制系统的远程监视和多重保护,提高了系统运行的可靠性和安全性,而且降低了设备维护成本,本空气预热器漏风控制装置技术改造取得了预期效果。     

基于投影浸入边界法的流固耦合计算模型

针对建立的刚体和流体相互作用的浸入边界法数学模型,借助求解不可压缩N-S方程组的分步投影方法的思想来求解基于浸入边界法的耦合系统方程.在空间离散上,对流项采用Quick格式,扩散项采用中心差分格式.时间推进采用显式欧拉法,固体对流体的作用力源项引入流体体积(VOF)方法中的体积比函数,通过龙贝格算法高效求解每个网格单元中浸入刚体所占的体积比.利用VC++编写投影浸入边界法的数值计算程序,并以单圆柱绕流为基准数值算例,通过与其他文献和实验结果的对比,验证了数值计算结果的准确性和可靠性,并进一步分析了不同雷诺数下圆柱绕流场的涡结构分布特征.     

饱和粘土中球孔扩张问题弹塑性解析

为了研究静力触探试验及沉桩扩孔等工程问题,基于修正剑桥模型,推导了不排水条件下球孔扩张问题的半解析解。将扩张球孔周围土体分为临界状态区、塑性区以及弹性区三个区域。弹性区内,利用弹性理论得到应力和孔隙水压力的解答;临界状态区及塑性区内,利用相关联的流动法则、拉格朗日分析法建立了关于应力的一阶非线性常微分方程组,以弹塑性界面处的应力分量作为初值,求解微分方程组可得到应力和孔隙水压力的解答。研究结果表明：各向同性超固结比对扩孔压力、土体应力、超孔隙水压力以及塑性区范围均具有显著影响,且扩孔过程中土体剪切模量并非常量,其随扩孔半径、各向同性超固结比的变化而变化;同时通过与已有解答进行比较,对本文方法的可靠性进行了验证。