合成氨工艺参数优化技术开发及应用

以氨净值为响应值,影响响应值的17个过程参数为变量,经逐步回归选入触媒温度左3,触媒温度左4,循环CH_4%,H/N,NH_3%(进口)5个过程参数建立预测方程,并根据该方程对响应值的拟合结果和误差分布对样本进行分类。在此基础上,采取图形显示技术和统计分析的方法对分类样本集的过程参数进行比对分析,由此获取优类信息制订优化的工艺参数方案,经仿真验证后用于指导合成氨装置的生产试验。试验结果与试验前的对照期比较,氨净值均值由13.86提高到14.54,吨氨气耗减少15.9887m~3,吨氨电耗减少15.8kWh,节能效益十分明显     

Conformance Tests for Real-Time Systems with Timed Automata Specifications

A method is introduced for testing the conformance of implemented real-time systems to timed automata specifications. Uppaal timed automata are transformed into testable timed transition systems (TTTSs) using a test view. Fault hypotheses and a test generation algorithm for TTTSs are defined. Results of applying the method are presented. Received October 1999 / Accepted in revised form November 2000     

Structure-activity relationships for analogs of (+)-(E)-endo-Β-bergamoten-12-oic acid,an oviposition stimulant ofHelicoverpa zea (Boddie)

-Bergamotenoic acid, a compound previously shown to stimulate oviposition inH. zea, was converted into a set of bicyclic analogs and tested with a set of acyclic side chain analogs to ascertain the molecular structure that maximizes insect behavioral response. While changes in the bicyclic ring elicited no variation in response, alteration in the side chain structure of-bergamotenoic acid resulted in significant changes in moth preference. Free rotation about the C-C bond proximal to the carboxylic acid group appears to be an important structural factor, since saturation of the side chain double bond significantly increased activity. The carboxylic acid group seems to be required for strong oviposition stimulation, since analogs lacking the carboxylic acid group exhibited no significant oviposition activity. Oviposition preference ofH. zea was also influenced by the length of the hydrocarbon chain to which the carboxylic acid is attached. While hexanoic acid was found inactive, the ovipositional preference for the heptanoic and octanoic acids was greatest for the one 8-carbon tested. This and other work suggest that carboxylic acids of specific chain lengths influence the oviposition behavior of bothHelicoverpa andHeliothis species and may be associated with host-plant selection. The potential use of this information in designing integrated pest management strategies for control ofH. zea is discussed.     

乌江沙沱水电站水轮机选型分析

沙沱水电站水头运行范围50～74.9 m.电站受阻出力多为汛期季节性电能,在综合考虑减少受阻出力及水轮机稳定运行的情况下,对61、62.5、64、65.5、67m五个额定水头方案进行了比较分析,最终确定了经济、合理的水轮机参数.     

中型山区河流水电站下游的鱼类生态需水量计算

为更好地对河流水电开发后的鱼类进行保护,探讨中型山区河流水电站下游的鱼类生态需水量计算.参照大型河流鱼类水力生境参数标准,根据中型山区河流的特点,得到中型山区河流鱼类水力生境参数的参考标准.选取有代表性的四川中型山区河流杂谷脑河进行鱼类生境原型观测,原型观测结果证实了该参考标准能够满足杂谷脑河鱼类对生境的实际需求.基于所得到的参考标准,应用生态水力学法对杂谷脑河红叶二级、理县以及甘堡3座电站减水河段的鱼类生态需水量进行计算分析,得到3座电站的生态需水量推荐值.通过分析可知,所得到的生态需水量推荐值占年均天然流量以及设计引用流量的比例都不高,在3座电站的运行实践中,具有可操作性.     

Noise analysis compact differential evolution

This article proposes a compact algorithm for optimisation in noisy environments. This algorithm has a compact structure and employs differential evolution search logic. Since it is a compact algorithm, it does not store a population of solutions but a probabilistic representation of the population. This kind of algorithmic structure can be implemented in those real-world problems characterized by memory limitations. The degree of randomization contained in the compact structure allows a robust behaviour in the presence of noise. In addition the proposed algorithm employs the noise analysis survivor selection scheme. This scheme performs an analysis of the noise and automatically performs a re-sampling of the solutions in order to ensure both reliable pairwise comparisons and a minimal cost in terms of fitness evaluations. The noise analysis component can be reliably used in noise environments affected by Gaussian noise which allow an a priori analysis of the noise features. This situation is typical of problems where the fitness is computed by means of measurement devices. An extensive comparative analysis including four different noise levels has been included. Numerical results show that the proposed algorithm displays a very good performance since it regularly succeeds at handling diverse fitness landscapes characterized by diverse noise amplitudes.     

Development of a fish‐based index of biotic integrity (FIBI) for monitoring riverine ecosystems in the Lake Victoria drainage Basin,Kenya

The long term monitoring of aquatic ecosystems based on chemical analysis is expensive resulting in a lack of time series data for management purposes thus necessitating the need for new cost effective methodologies. This study developed a fish‐based index of biotic integrity (FIBI) for monitoring environmental conditions in riverine ecosystems within the Lake Victoria Basin, Kenya. The fish fauna in the basin is poorly studied, less diverse and ecologically specialized than the temperate fauna that provided the origins of the Index of Biotic Integrity. Fish samples were collected by electrofishing from 24 sites during baseflow periods in February, March and July 2004. Validation data were collected from 7 sites with varying levels of degradation. Fish samples were identified, counted and grouped into different trophic groups, relative tolerance to pollution, habitat guild and whether exotic or native to riverine environment. Thirty‐three candidate metrics were evaluated for responsiveness to habitat quality and twelve were selected for inclusion in the final index. The index classified 6 of the 7 validation sites according to their levels of degradation. As a bioassessment tool, the index was useful in laying the basis for long‐term monitoring of rivers in the Lake Victoria drainage basin. Copyright © 2010 John Wiley & Sons, Ltd.     

水泵选型应用系统中CAD在线绘图的设计与实现

水泵选型应用研究的目的是用计算机来代替传统的纸质资料。系统地介绍了在水泵选型应用系统中利用网络进行CAD在线绘图的特点、CAD在线绘图的设计构思以及实现方法,为B/S结构的水泵选型应用系统奠定基础。     

基于李雅普诺夫函数法的扩张状态观测器参数优化

针对ESO参数不易整定的问题,研究了扩张状态观测器(ESO)参数优化的李雅普诺夫函数法.首先建立关于误差的线性定常状态方程和误差指标函数J,在误差指标函数J中综合考虑了跟踪误差的权重和系统的稳定性以及实际运行时的饱和值限制等因素.仿真结果表明,此方法具有概念清晰,实用简便,计算量小的优点.所提ESO参数整定方法是有效的.     

工艺参数对TiO2碳热还原合成Ti（C,N）粉末的影响

本文探讨了ＴｉＯ２碳热还原法合成Ｔｉ（Ｃ，Ｎ）粉末过程中合成温度，保温时间，Ｎ２气流量，Ｃ／Ｔｉ比值等工艺参数的变化对粉末性状的影响，实验表明，Ｎ比Ｃ更易于Ｔｉ结合，改变工艺对数可调整Ｔｉ（Ｃ１－ｘＮｘ）的ｘ值。在１４００～１７００℃间可获得ｘ值的０．６～０．８５的Ｔｉ（Ｃ１－ｘＮｘ）粉末。