Evaluation of the agronomic effectiveness of natural and partially acidulated phosphate rocks in several soils using32P isotopic dilution techniques

The agronomic effectiveness of two natural phosphate rocks (PRs) from North Carolina (USA) and Togo and their 50% partially acidulated products (PAPRs) was evaluated in two greenhouse experiments using³²P isotopic dilution techniques, namely L and A_L values.In the first experiment rye grass was grown in a soil from Ghana. While the proportion of P in the plant derived from the P fertilizer (Pdff) ranged on. the average from about 10% for the PRs up to 80% for the PAPRs, the P fertilizer recovery was less than 1% for a 60-day growth period. In the second experiment, average values of P in the maize plants derived from the PAPRs ranged from 35% to 75% in 3 different soils. Both PRs were ineffective with the exception of North Carolina PR in the Seibersdorf soil. The P fertilizer recovery was 0.25% for the North Carolina PR in this soil whereas the recovery values ranged from 1.2% to 1.6% for the PAPRs.Mean values of the relative fertilizer efficiency estimated from the L values of each soil were less than 1% for the PRs whereas the values for the PAPRs which were dependent on soil type ranged from 20% up to 45%. The coefficient of relative effect of partial acidulation, that was calculated from the ratio of A_L values for PR and PAPR in each soil indicated that partial acidulation increased the effectiveness of the natural PRs in all soils under study.This study showed that the use of³²P isotope dilution techniques allows an accurate measurement of the P availability from natural and modified PR products to crops. Another advantage is that quantitative comparison of the P sources under study, PRs and PAPRs in this case, can be made even in soils where there is no response to the applied P sources.     

Variable partial-update NLMS algorithms with data-selective updating

We note that some existing algorithms are based on the normalized least-mean square （NLMS） algorithm and aim to reduce the computational complexity of NLMS all inherited from the solution of the same optimization problem, but with different constraints. A new constraint is analyzed to substitute an extra searching technique in the set-membership partial-update NLMS algorithm （SM-PU-NLMS） which aims to get a variable number of updating coefficients for a further reduction of computational complexity. We get a closed form expression of the new constraint without extra searching technique to generate a novel set-membership variable-partial-update NLMS （SM-VPU-NLMS） algorithm. Note that tile SM-VPU-NLMS algorithm obtains a faster convergence and a smaller mean-squared error （MSE） than the existing SM-PU-NLMS. It is pointed out that the closed form expression can also be applied to the conventional variable-step-size partial-update NLMS （VSS-PU-NLMS） algorithm. The novel variable-step-size variable-partial-update NLMS （VSS-VPU-NLMS） algorithm is also verified to get a further computational complexity reduction. Simulation results verify that our analysis is reasonable and effective.     

高频脉冲电流法在在线检测电力变压器局部放电中的应用

介绍高频脉冲电流检测技术的原理,及其在在线检测电力变压器的局部放电中的应用。     

氧分压对TiO2薄膜光学性能的影响

为得到光学性能良好、稳定的TiO2薄膜,采用离子束溅射的方法,改变氧分压,在k9玻璃上制备出不同结晶取向不同光学常数的TiO2薄膜.采用椭圆偏振光谱仪测试、拟合得到薄膜的厚度、折射率和消光系数.薄膜通过400℃退火,利用X射线衍射仪(XRD)对薄膜的成分、结晶和取向进行分析.实验结果发现,随氧分压增加折射率减低,当氧分压达到1.0×10-2Pa时,折射率在2.43附近,变化趋于稳定.氧分压对薄膜的消光系数k影响较大,氧分压高于1.0×10-2Pa时在可见光和近红外区薄膜消光系数近似为0.随氧分压降低,薄膜从(101)向(200)转变.在此氧分压下,得到的薄膜折射率稳定,消光系数相对较小.     

融合语义差别和流型学习的偏标记学习方法

偏标记学习是一种重要的弱监督学习框架。在偏标记学习中,每个实例与一组候选标记相关联,它的真实标记隐藏在候选标记集合中,且在学习过程中不可获知。为了消除候选标记对学习过程的影响,提出了一种融合实例语义差别最大化和流型学习的偏标记学习方法(partial label learning by semantic difference and manifold learning, PL-SDML)。该方法是一个两阶段的方法：在训练阶段,基于实例的语义差别最大化准则和流型学习方法为训练实例生成标记置信度;在预测阶段,使用基于最近邻投票的方法为未知实例预测标记类别。在四组人工改造的UCI数据集中,在平均70%的情况下优于其他对比算法。在四组真实偏标记数据集中,相比其他对比算法,取得了0.3%～13.8%的性能提升。     

一种基于分段偏最小二乘模型的土壤重金属遥感反演方法

土壤中重金属由于其毒性而成为最有害的环境污染物之一,利用遥感进行土壤重金属检测和分布制图是目前最为高效的手段。采用哨兵二号（Sentinel-2）多光谱影像与实测样品光谱数据,对山西省铜矿峪铜矿尾矿库及其周边农田土壤的铜（Cu）含量进行估算,利用68个土壤样品的反射光谱,优选出适合土壤铜含量预测的波段,结合分段偏最小二乘法（Piecewise Partial Least Squares Regression,P-PLSR）,对土壤铜含量进行估算,将模型用于Sentinel-2影像获得了Cu含量的空间分布。通过P-PLSR对实测样品光谱建模反演Cu含量的决定系数（R²）为0.89,预测偏差比（RPD）为2.82;利用Sentinel-2多光谱影像获得了该区域Cu元素含量空间分布,其Cu含量的估算精度R²为0.74,RPD为1.73,Cu含量高值区空间分布与尾矿库关系密切。Sentinel-2多光谱数据具有高空间分辨率（10、20和60 m）、高时间分辨率和幅宽大（290 km）等优势,通过敏感波段选择并建立反演模型,可实现大范围土壤环境制图。     

基于非负最小二乘法的一维MT正则化反演研究

为了有效地解决在大地电磁反演过程中出现的不适定性、解的不稳定性和非唯一性等问题,提出了基于非负最小二乘法的MT正则化反演算法,该算法的思想是通过引入正则化思想,模型约束目标函数被采用最光滑模型约束正则化矩阵,有效地改善了不适定问题得到有效改善。为了避免常规方法需要对电阻率取对数的情况,引入了快速非负最小二乘法(这里把反演参数设为电阻率,因而必须为正值),从而简化了反演过程中偏导数矩阵的计算。最后试算不同的地电模型,得到稳定的反演结果,表明了此反演算法是有效的。     

反映的规律为本构关系的变分原理

为证明经典变分原理中存在反映的规律为本构关系的变分原理,从非线性弹性动力学的基本方程出发,应用变积方法建立非线性弹性动力学Hamilton原理.再应用对合变换法、Lagrange乘子法和局部代入法,将Hamilton原理变换为本构变分原理.论证了该变分原理反映的规律为本构关系,本研究以非线性材料为例,找到了一个新的材料本构关系的获得途径,为数值建模提供了理论依据.研究结果表明,补充和完善了经典变分原理中对3类基本规律的反映,即:最小势能原理反映的规律为平衡关系、最小余能原理反映的规律为连续关系和本构变分原理反映的规律为本构关系.     

pH对高氨废水限氧半亚硝化过程中N2O释放的影响

为获得半亚硝化系统中强温室气体N2O减量化释放的控制参数,采用SBR处理人工合成高氨废水(进水氨氮质量浓度约为600 mg·L-1),考察不同进水pH(7.5,8.0和8.5)对N2O释放特性的影响.结果表明,不同进水pH下均释放N2O,每个周期内N2O的释放量随进水pH的升高而减小.pH为7.5,8.0及8.5时,N2O释放量分别占进水氨氮的3.81%、2.35%和2.00%.当pH为7.5时,曝气初始50 min内,N2O释放速率先增大后减小,峰值速率为44.5μg·min-1·g-1,之后维持在16.5μg·min-1·g-1;当p H为8.0及8.5时,曝气初期N2O释放峰值速率分别为33.7,22.9μg·min-1·g-1,之后释放速率随pH降低和NO2-积累而逐渐增大.     

Seismic Behaviour of Beam-Column Joints of Precast and Partial Steel Reinforced Concrete

A beam-column joint of precast and partial steel reinforced concrete( PPSRC) is proposed for precast reinforced concrete frames. The PPSRC consists of partial steel and reinforced concrete. The partial steel is located in the core joint region and the connections between concrete members. This paper presents an experimental study of a series of PPSRC specimens. These specimens are tested under low cyclic loading.Experimental results demonstrate that the bearing capacity of the PPSRC specimens is 3 times that of the ordinary reinforced concrete( RC) beam-column joints. The strength and stiffness degradation rates are slower compared with that of the RC beam-column joints. In addition,the strength of the core joint region and the connections is higher than other parts of the PPSRC specimens. Beam failure occurs firstly for the PPSRC specimens,followed by column failure and connections failure. The failure of the core joint region occurs finally.Test results show that the seismic performance of the PPSRC is better than that of the ordinary RC beam-column joints.