超支化聚酰胺强化热塑性聚氨酯结晶及发泡性能的研究

在热塑性聚氨酯（TPU）中引入超支化聚酰胺HyPer,利用傅里叶红外光谱研究了HyPer对TPU分子间氢键的影响;同时采用旋转流变仪及差示扫描量热仪研究了HyPer对TPU的结晶及流变性能的影响规律。结果表明,HyPer可以与TPU中的氨基甲酸酯形成分子间氢键,显著提高了TPU中羰基峰的氢键化程度; 另外,HyPer的加入对TPU有显著的增塑作用,特性黏度降低,分子间活动能力增加,提高了TPU的结晶速率和结晶度;添加0.25 %（质量分数,下同）的HyPer降低了TPU的熔体黏弹性,有利于泡孔生长,发泡倍率提高30 %,而HyPer含量提高增强了 TPU的结晶度,结晶度的提高一方面可以促进泡孔成核,另一方面可以抑制泡孔生长,有利于泡孔密度的提高,泡孔尺寸的减小。     

陶瓷结合剂化学组成的计算与配方优化设计

本文利用计算机技术．对陶瓷结合剂化学成分进行精密计算．在此基础上，根据结合剂所需要的化学成分，采用数学模型精确优化设计出陶瓷结合剂配方(即各种原材料的配比)，文章介绍了上述算法具体实现方法，给出了算法模型和精确的程序语言描述，算法重点解决了误差放大．计算稳定性等工程计算问题，对实际系统运行样本数据进行了验证，同时，文章描述了算法所引用的数据库表的结构设计方法及提高数据库应用效率和灵活性的技巧；分析了整个软件系统模块组成，描述了系统功能。通过实际应用与测试．验证了该系统算法和软件系统的可用性，对研究开发新型陶瓷结合剂具有重要指导作用。     

Ceramic coating on ceramic with metallic bond coating

The change in structure and adhesion strength of the interface by heating in air has been investigated for a plasma- sprayed alumina coating on a ceramic substrate with a 50Ni- 50Cr alloy bond coating. A veined structure composed of NiO, NiCr ₂O₄, and NiAl₂O₄ oxides grew from the bond coating into cracks or pores in the top coating and the alumina substrate after heating at 1273 K for 20 h in air. The NiAl₂O₄ spinel may have formed by the oxidization of nickel, which subsequently reacted with the alumina coating or the substrate. The mechanism of the penetration of the spinel oxides into the cracks or pores is not clear. The adhesion strength of the coating is increased to about 15 MPa after heating at 1273 K for 20 h in air, compared to an as- sprayed coating strength of only 1.5 MPa.     

Self-assembled monolayers of p-toluene and p-hydroxymethylbenzene moieties adsorbed on iron by the formation of covalent bonds between carbon and iron atoms for protection of iron from corrosion

An iron electrode was modified by electrolytic reduction in deaerated acetonitrile solution of p-toluenediazonium tetrafluoroborate CH₃C₆H₄N₂BF₄ (TDFB) or p-hydroxymethylbenzenediazonium tetrafluoroborate HOCH₂C₆H₄N₂BF₄ (HOTDFB) below 10 °C to form a self-assembled monolayer (SAM) of toluene CH₃C₆H₄- or hydroxymethylbenzene HOCH₂C₆H₄- (HOMB) moiety, probably adsorbed on the electrode by the formation of a covalent bond between carbon and iron atoms, as shown in references. The protective ability of the layer was examined by polarization measurement of the electrode in an aerated 0.5 M NaCl solution. The protective efficiencies of these two SAMs were not high, around 30%, a little higher than that of the toluenethiol CH₃C₆H₄SH SAM which was anchored on iron via a coordinate bond between sulfur and iron atoms. The iron surfaces modified with TDFB and HOTDFB were characterized by contact angle measurement, FTIR reflection spectroscopy and X-ray photoelectron spectroscopy. The persistence in protection of iron against corrosion by coverage with the HOMB SAM was confirmed by polarization measurements after immersion in 0.5 M NaCl for a long period of the time.     

一种新型金刚石磨具树脂结合剂的制备

本文介绍了一种新型的操作工艺简单、耐水、耐热、耐酸碱溶液的环氧树脂结合剂的制备方法：结合剂采用环氧树脂和聚酰胺固化体系，并用液体端羧基丁腈橡胶(CTBN)对环氧树脂进行改性，在固化剂中添加改性固化利A提高固化物的耐热性。此树脂结合剂初始固化温度为3min，成型方便，是一种适于异形金刚石磨具使用的树脂结合剂C在150℃固化3h并在室温放置1天后，固化物具有高的硬度和耐热性以及优异的粘接性能，可以在150℃长期使用。     

磨PCD刀具陶瓷结合剂金刚石砂轮的研究

本文研究制备Na2O-B203-Si02-Al203多元系基玻璃料,并配制成低温陶瓷结合剂,研究发现:耐火度为685℃,流动性为110%～130%,线膨胀系数为5.35×10-6℃-1的低温陶瓷结合剂具有优异的性能.制备的陶瓷结合剂金刚石砂轮在725℃烧成后,磨具的抗弯强度和洛氏硬度达到最佳值,分别58.61 MPa和77.9.用其磨削PCD刀片时锋利性好,磨削中间不需修整,砂轮耐用度高.运用扫描电子显微镜(SEM)分析了陶瓷结合剂金刚石磨具的断面形貌、磨削后磨削面形貌,表明结合剂对磨粒黏结牢固,断面组织均匀.     

陶瓷高速砂轮结合剂中不同成份对砂轮强度影响的探讨

针对我国陶瓷高速砂轮特别是粗粒度高速砂轮回转强度不稳定的问题，本文主要对粘土—钾长石—硼玻璃、粘土—钾／钠长石—硼玻璃、粘土—钾长石—钙玻璃、粘土—钾长石—锂辉石等系统的结合剂进行研究。在现行的同一工艺条件下，用白刚玉WA46#磨料90％、陶瓷结合剂10％制备成磨具进行陶瓷结合剂的性能比较，对结合剂中不同成份对砂轮强度的影响进行了探讨，以找到一种既能满足现行生产工艺，又能提高粗粒度陶瓷高速砂轮回转强度的陶瓷结合剂。研究结果表明：在常用的粘土一钾长石～硼玻璃系统中引入钠长石，当钠长石达到适当比例(2l％)，所制备的结合剂生产的陶瓷砂轮回转强度提高，且与现行生产工艺匹配，工艺性能稳定，有望成为改进陶瓷结合剂的一种新的途径。     

树脂砂轮研磨钢球专用磨削液的研制

本文针对钢球磨削液存在的问题，研究了反应时间、温度、搅拌速度、加料时的温度以及冷却方式等条件对磨削液性能的影响。适宜的工艺条件为聚乙二醇：邻苯二甲酸酐=10：1，反应温度110—130℃，搅拌速度500—650n／min，加入配料时温度70-80℃。该磨削液专门适用于树脂砂轮研磨钢球，可以解决树脂砂轮在磨削液中的腐烂问题，并有利于环境保护。     

Composition and microstructure characteristics in bond area of TIG welding for high strength ZA alloy

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Experimental and numerical life prediction of thermally cycled thermal barrier coatings

This article addresses the predominant degradation modes and life prediction of a plasma-sprayed thermal barrier coating (TBC). The studied TBC system consists of an air-plasma-sprayed bond coat and an air-plasma-sprayed, yttria partially stabilized zirconia top layer on a conventional Hastelloy X substrate. Thermal shock tests of as-sprayed TBC and pre-oxidized TBC specimens were conducted under different burner flame conditions at Volvo Aero Corporation (Trollhättan, Sweden). Finite element models were used to simulate the thermal shock tests. Transient temperature distributions and thermal mismatch stresses in different layers of the coatings during thermal cycling were calculated. The roughness of the interface between the ceramic top coat and the bond coat was modeled through an ideally sinusoidal wavy surface. Bond coat oxidation was simulated through adding an aluminum oxide layer between the ceramic top coat and the bond coat. The calculated stresses indicated that interfacial delamination cracks, initiated in the ceramic top coat at the peak of the asperity of the interface, together with surface cracking, are the main reasons for coating failure. A phenomenological life prediction model for the coating was proposed. This model is accurate within a factor of 3.