Molecular simulation of phase coexistence: Finite-size effects and determination of critical parameters for two- and three-dimensional Lennard-Jones fluids

Abstact The subject of this paper is the investigation of finite-size effects and the determination of critical parameters for a class of truncated Lennard-Jones potentials. Despite significant recent progress in our ability to model phase equilibria in multicomponent mixtures from direct molecular simulations, the accurate determination of critical parameters remains a difficult problem. Gibbs ensemble Monte Carlo simulations with systems of controlled linear system size are used to obtain the phase behavior in the near-critical region for two- and three dimensional Lennard-Jones fluids with reduced cutoff radii of 3, 3.5, and 5. For the two-dimensional systems, crossover of the effective exponent for the width of the coexistence curve from mean field ( = 1/2 in the immediate vicinity of the critical point to Ising-like (= 1/8) farther away is observed. Critical parameters determined by fitting the data that follow Ising-like behavior are in good agreement with literature values obtained with finite-size scaling methods. For the three-dimensional systems, no crossover to mean field-type behavior was apparent. Extrapolated results for the critical parameters are consistent with literature estimates for similar fluids. For both two- and three-dimensional fluids, system size effects on the coexistence curves away from the critical point are small, normally within simulation statistical uncertainties.Invited paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder. Colorado, U.S.A.     

考虑天然气混氢的园区综合能源系统电制氢优化配置

电制氢和天然气混氢技术在促进可再生能源消纳、降低系统碳排放量方面具有良好的理论研究和工程应用前景。面向含高比例可再生能源的园区综合能源系统,提出一种计及天然气混氢及跨季节存储的电制氢优化配置方法。首先梳理了含氢园区综合能源系统的运行框架和能量流动关系,建立园区内部能源生产、转换与存储设备的数学模型,其次以设备的年化投资成本、园区综合能源系统的年度运行成本和碳交易成本最优为目标,提出电制氢优化配置模型。最后通过算例分析表明电制氢及天然气混氢技术的引入可提升可再生能源的消纳能力,降低系统的整体经济成本和碳排放量,并分析了电解槽投资成本、混氢体积分数上限以及经济性和低碳性成本权重系数变化对规划运行结果的影响。关键词：园区综合能源系统;电制氢;天然气混氢;碳交易;跨季节储氢;优化配置 中图分类号：TM732     

Improvisation of Node Mobility Using Cluster Routing-based Group Adaptive in MANET

In today's Internet routing infrastructure, designers have addressed scaling concerns in routing constrained multiobjective optimization problems examining latency and mobility concerns as a secondary constrain. In tactical Mobile Ad-hoc Network (MANET), hubs can function based on the work plan in various social affairs and the internally connected hubs are almost having the related moving standards where the topology between one and the other are tightly coupled in steady support by considering the touchstone of hubs such as a self-sorted out, self-mending and self-administration. Clustering in the routing process is one of the key aspects to increase MANET performance by coordinating the pathways using multiple criteria and analytics. We present a Group Adaptive Hybrid Routing Algorithm (GAHRA) for gathering portability, which pursues table-driven directing methodology in stable accumulations and on-request steering strategy for versatile situations. Based on this aspect, the research demonstrates an adjustable framework for commuting between the table-driven approach and the on-request approach, with the objectives of enhancing the output of MANET routing computation in each hub. Simulation analysis and replication results reveal that the proposed method is promising than a single well-known existing routing approach and is well-suited for sensitive MANET applications.     

地铁站场景下的可行驶区域检测

在室内环境下的机器人视觉导航任务中,可行驶区域检测是不可或缺的一部分,这是保证自动驾驶任务实现的基础.目前较多的解决方法是对数据集中出现过的障碍物进行识别来检测可行驶区域,缺乏灵活性,因此本文提出了一种针对地铁站等室内平坦地面的可行驶区域检测方法,提高实用性.本文采用经典的MobileNetV3网络对采集到的前方图像进行分类,判断是否为地面区域.由于室内地面的地标、箭头等贴纸的影响,因此需要对非地面区域进一步判断,与常规的立体障碍物进行区分.本文利用连续帧之间的特征点匹配获得相机移动距离,并利用直线拟合计算斜率的方法达到区分立体障碍物与平面地标的目的.实验表明,本文提出的方法能较好地检测机器人前方可行驶区域,具有较高的实用价值.     

Reliability analysis on systems with self-healing and self-repairing under different environments and shock models

Inspired by the process of self-healing of biological damage, high technology materials with self-healing and self-repairing mechanisms have been developed for high reliability and long lifetime. Therefore, the reliability modeling on intelligent systems with healing performance has become a research hotspot. Based on the diversity of healing mechanisms, this paper proposes a two-phase reliability model method on self-healing and self-repairing systems. Impacts of environments, shock loads, self-healing, and self-repairing mechanisms are taken into account in this novel model. Besides, system lifetime and some reliability indexes under two shock models are derived, respectively. Moreover, Monte Carlo simulations are conducted to verify the accuracy of reliability under two models. Finally, an engineering case of metallized film capacitor is provided to illustrate the effectiveness and applicability of the proposed models by comparing numerical results and simulation results.     

从测角后交最佳点位规律看规范规定之不足

本文分析了文献[1]所总结的测角后交两类公式在取得最佳点位时的规律,指出当前规范对此问题规定之不足.     

Influence of ions on the critical behavior of a binary mixture near the consolute point

The lower critical point of stratification of a 3-methylpyridine (MP)+heavy water (D₂O) mixture in the presence of Na⁺ and CI^– ions has been studied by the Toepler shadow method. Addition of 0.3% ions lowered the critical temperature and reduced the equilibration time and the gradient of the refractive index (compressibillity). The analysis of the form of the near-critical isotherm demonstrated the ionic mixture to be described by the index = 3.05 ± 0.15. which corresponds to the classical mean-field theory. The results obtained provide evidence that even small admixtures of charged particles result in a substantial suppression of fluctuations near the critical point by the long-range Coulomb interaction.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A.     

商业诽谤犯罪中网络服务提供者行为的技术与法律分析

在本案中,刑法及其司法解释完全从商业诽谤犯罪实行行为的角度进行解释,没有重视网络信息服务提供者的行为特点,实际上导致难以根据刑法以及司法解释分析网络服务提供者在网络商业诽谤违法犯罪中的责任。在商业诽谤刑事案件中,网络服务提供者不仅有义务向侦查机关提供有关资料,而且由于其在信息监管责任缺位,必须对其设置责任追究的机制,从而推动其履行商业诽谤信息审查义务。     

A quantitative multimodal discourse analysis of teaching and learning in a web-conferencing environment – The efficacy of student-centred learning designs

This paper presents a quantitative approach to multimodal discourse analysis for analyzing online collaborative learning. The coding framework draws together the fields of systemic functional linguistics and Activity Theory to analyze interactions between collaborative-, content- and technology-related discourse. The approach is used to examine how the task subject matter, the activity design, and the choice of interface affected interaction and collaboration for a computing course conducted in a web-conferencing environment. The analysis revealed the critical impact of activity design on the amount and type of discourse that transpired. Student-centred designs resulted in over six times more student discourse as compared to teacher-centred designs and created a learning environment where students took greater ownership over the tasks and contributed more to the content-based discussion. The paper also incorporates a rationale for the approach to coding and a reflection on its efficacy for discourse analysis in technology-based learning environments.     

Is compulsive internet use related to sensitivity to reward and punishment,and impulsivity?

Aim of the present study was to examine whether the personality correlates sensitivity to reward and to punishment, and impulsivity predict compulsive internet use (CIU). Furthermore, the predictive value of these personality correlates was compared to the predictive value of factors relating to psychosocial wellbeing. The results showed that particularly rash spontaneous impulsivity predicts CIU and that this personality factor is more important than psychosocial wellbeing factors. Sensitivity to reward, which is supposed to play a role in craving processes associated with substance abuse and eating disorders, could not be related to CIU. The data suggest that internet users who are characterized by an impulsive personality feature, are less able to control their use of the internet, which makes them more vulnerable to develop CIU.