Synthesis and characterization of polyimide/polyhedral oligomeric silsesquioxane nanocomposites containing quinolyl moiety

A series of functional polyhedral oligomeric silsesquioxane (POSS)/polyimide (PI) nanocomposites were prepared using a two‐step approach. First, octa(aminophenyl)silsesquioxane (OAPS) was mixed with poly(amic acid) (PAA) prepared by reacting bis(4‐amino‐3,5‐dimethylphenyl)‐3‐quinolylmethane and 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride. Second, the resulting solution was subjected to thermal imidization. The well‐defined ‘hard particles’ (POSS) and the strong covalent bonds in the amide linkage between the carbon atom of the carboxyl side group in PAA and the nitrogen atom of the amino group in POSS lead to a significant improvement in the thermal and mechanical properties. Homogeneous dispersion of POSS cages in the PI is evident from scanning electron microscopy, which further confirms that the POSS molecule becomes an integral part of the organic‐inorganic inter‐crosslinked network system. Differential scanning calorimetry and dynamic mechanical analysis show that the glass transition temperatures of the POSS‐containing nanocomposites are higher than that of the corresponding neat PI system, owing to the significant increase of the crosslinking density in the PI/POSS nanocomposites. Increasing the concentration of OAPS in the PI networks decreases the dielectric constant. Pure PI and PI/POSS systems have good antimicrobial activity. Copyright © 2011 Society of Chemical Industry     

Synthesis and properties of hybrid urethane polymers containing polyhedral oligomeric silsesquioxane crosslinker

The synthesis and properties of novel hybrid silsesquioxane‐containing urethane polymers using octakis(hydroxypropyldimethylsiloxy)octasilsesquioxane (OHPOSS) as a crosslinker and a hydroxyl‐terminated polybutadiene were studied. Mixing of the OHPOSS with polyurethane prepolymer and chain extenders in solution was found to be successful when tetrahydrofuran was used as the solvent. Thin films of hybrid polyurethanes were obtained. The hybrid materials were elastomers with improved water and solvent resistivity and good thermal stability. The studied OHPOSS appeared to be an effective crosslinker of polyurethanes suitable for, for example, surface coatings applications. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2023–2030, 2013     

基于VBA的道路曲线要素表的程序设计

AutoCAD作为一种功能强大的计算机绘图软件,目前已成为应用广泛的设计软件。在AutoCAD基础上二次开发出各专业软件和程序也越来越多,但大多具有一定的广泛适用性;不是针对某个人,或者某个具体专业。针对这些问题,中国中材国际工程股份有限公司(南京)利用VBA语言编写了道路曲线要素表程序,从而实现了水泥原料矿山道路曲线要素表的自动生成。     

半缩合低聚硅氧烷的合成及应用进展

介绍了半缩合低聚硅氧烷（简称半缩合POSS）的类别,阐述了半缩合POSS的制备方法与途径,分析了各自的优缺点,并对半缩合POSS改性材料（包括改性环氧树脂、丙烯酸树脂、有机硅、聚氨酯等）的最新研究进展进行了描述,指出了半缩合POSS的发展与应用前景。     

一种用于多面体加工的圆弧刀轨生成算法

为提高多面体模型的加工效率,提出了一种用于多面体加工的圆弧刀轨生成算法。采用截平面和多面体模型的等距模型求交来计算初始直线刀轨;由等距模型的顶点曲率估算刀位点处沿刀轨方向和刀轨间隔方向的曲率半径,并根据残留高度确定刀轨行距。提出了基于刀位点曲率半径调节的圆弧拟合算法,算法引入拟合约束条件和曲率半径调节系数;在拟合精度范围内,迭代确定曲率半径调节系数,从而确定拟合圆弧。实验结果表明文中方法生成的刀轨保持G1连续且包含的圆弧段数量较少,有利于提高加工效率。     

Polymer dynamics in rubbery epoxy networks/polyhedral oligomeric silsesquioxanes nanocomposites

Dielectric techniques, including thermally stimulated depolarization currents (TSDC, ?150 to 30°C) and, mainly, broadband dielectric relaxation spectroscopy (DRS, 10^?2 – 10⁶ Hz, ?150 to 150°C) were employed, next to differential scanning calorimetry (DSC), to investigate molecular dynamics in rubbery epoxy networks prepared from diglycidyl ether of Bisphenol A (DGEBA) and poly(oxypropylene)diamine (Jeffamine D2000, molecular mass 2000) and modified with polyhedral oligomeric silsesquioxanes (POSS) units covalently bound to the chains as dangling blocks. Four relaxations were detected and analyzed: in the order of increasing temperature at constant frequency, two local, secondary γ and β relaxations in the glassy state, the segmental α relaxation associated with the glass transition and the normal mode relaxation, related with the presence of a dipole moment component along the Jeffamine chain contour. Measurements on pure Jeffamine D2000 helped to clarify the molecular origin of the relaxations observed. A significant reduction of the magnitude and a slight acceleration of the α and of the normal mode relaxations were observed in the modified networks. These results suggest that a fraction of polymer is immobilized, probably at interfaces with POSS, due to constraints imposed by the covalently bound rigid nanoparticles, whereas the rest exhibits a slightly faster dynamics due to increaseof free volume resulting from loosened molecular packing of the chains (plasticization by the bulky POSS units).The increase of free volume is rationalized by density measurements. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

环氧基倍半硅氧烷的合成与表征

以八乙烯基倍半硅氧烷(OvPOSS)为原料,过氧乙酸为氧化剂,采用官能团衍生法制备了环氧基倍半硅氧烷(epoxy-POSS)。讨论了过氧化氢浓度、反应时间、反应温度、酸体积比对OvPOSS环氧化程度的影响。结果表明,当酸体积比CH3COOH∶H2O2=0.5∶1,反应温度60℃,回流反应12h,OvPOSS上参加反应的乙烯基平均数为4,并用FT-IR、NMR对产物结构进行了表征。     

POSS为核的高臂数星型杂化聚乳酸的合成

首先合成了含有8个羟基、结构极为对称的八聚[2-(2-羟基乙氧基)二甲基硅氧基]倍半硅氧烷,再以其为核引发D,L-丙交酯发生开环聚合,制备了含有八臂聚乳酸的星型有机-无机杂化POSS-PDLLA材料,通过FTIR、1H-NMR、GPC、DSC和TGA等手段对八羟基倍半硅氧烷和POSS-PDLLA杂化材料的化学结构和性能等进行了表征。结果表明,成功合成了单分散性的八羟基倍半硅氧烷,而POSS-PDLLA杂化聚合物分子量分布极窄(小于1.1)、玻璃化转变温度为43.6℃、热稳定性良好,具有与线性聚乳酸截然不同的特性。     

曲线插值的一种具有还圆性的细分方法

传统的线性四点插值细分方法不能表示圆等非多项式曲线,为了解决这种问题,基于几何特性提出了一种带有一个参数的四点插值型曲线细分方法。细分过程中,过相邻三插值点作圆,过相邻二插值点的圆弧有两个中点,将其加权平均得到新插值点,文中给出了插值公式和算法描述。所给方法具有还圆性,可以实现保凸性。实例分析对比了本方法与多种细分方法的差异,说明本方法是有效的,当参数取值较小时,曲线靠近控制多边形。     

新疆众和公司800铝带箔轧机技术特性分析

该文从国内外铝轧机技术水平的发展情况出发，与新疆众和公司的８００轧机的性能指标进行比较。从理论上结合实际生产情况对该轧机的一些技术特点进行了分析研究。