笼型倍半硅氧烷基聚合物的制备和结构性能及应用

笼型聚倍半硅氧烷基聚合物是一种典型的多面体有机/无机分子复合物材料,因其具有优异的光、电、热、磁、声、力学和化学相容性等性能,所以近年来被极力的引入较为尖端的技术领域进行研究和应用。本文详尽归纳总结了笼型倍半硅氧烷基聚合物的现行制备方法,讨论了笼型倍半硅氧烷结构对材料性能的影响。最后,对笼型倍半硅氧烷基聚合物材料的应用领域和发展趋势进行了详细说明。     

曲轴不平衡量多面校正的优化分解算法研究

针对生产实际中曲轴动平衡效率低的问题,以最少去重面、总去重量最小为目标,提出一种应用于全自动曲轴动平衡量分解的优化算法——多面校正法。首先对曲轴不平衡量进行测量分解,然后根据分解结果,自动选择去重面,进行去重。多面校正法成功减少了曲轴总去重量,实现了平衡去重的优化。另外,该算法可根据实际曲轴结构的不同,选择与之对应的去重块和扇面角度,显著扩大了测试系统的适用范围。应用此算法对曲轴不平衡量进行优化分解,能够有效提高曲轴生产效率和产品合格率,降低曲轴制造成本。     

抽象凸空间中KKM点的稳定性

记M为所有抽象凸空间中KKM映射T组成的集合,F(T)为T的所有KKM点组成的集合.证明了存在一M的稠密剩余子集Q,使得T∈Q,T为稳定的,即T的KKM点的通有稳定性以及T∈M,至少存在一F(T)的本质连通区.     

Microstructure control in precious metal coatings for high temperature applications,obtained by metallorganic chemical vapour deposition

In most high temperature applications, efficiency increases with service temperature of the component. Especially in combustion chambers, higher efficiency is translated into less propellant consumption and therefore a lower weight and a reduction of operational cost. In these components, the use of high performance coatings may simultaneously increase the service temperature and decrease its price. From the many available coating processes, Metal organic Chemical Vapour Deposition (MO‐CVD) is one of the few capable of producing coatings of most precious metals in internal surfaces with intricate geometry. Nevertheless the microstructure control of the films is extremely complicated and characterised by the formation of dendrite structures. This morphology eliminates the coating efficiency, as it is not compact. EADS has had the chance to use the research infrastructure of the AMTT in Seibersdorf to characterise the coatings and determine how the transformation from the compact to the non‐compact microstructure takes place. The understanding of this phenomenon should allow us to develop a process able to produce 100 % dense coatings independently of the coating thickness in an industrial scale.     

热轧板凸度控制研究

针对热轧板卷对板凸度的不同要求，从研究精轧工作辊热凸度，轧制计划编排，精轧负荷分配与平衡力控制，轧辊原始辊形和辊周期入手，详细分析了各影响因素对板凸度的作用，提出了现阶段热轧板凸度的控制策略。     

Syntheses, thermal properties, and phase morphologies of novel benzoxazines functionalized with polyhedral oligomeric silsesquioxane (POSS) nanocomposites

We have successfully synthesized a novel benzoxazine ring-containing polyhedral oligomeric silsesquioxane (BZ-POSS) monomer by two routes: (1) hydrosilylation of a vinyl-terminated benzoxazine using the hydro-silane functional group of a polyhedral oligomeric silsesquioxane (H-POSS) and (2) reaction of a primary amine-containng POSS (Amine-POSS) with phenol and formaldehyde. The benzoxazine-containing POSS (BZ-POSS) monomer can be copolymerized with other benzoxazine monomers through ring-opening polymerization under conditions similar to that used for polymerizing pure benzoxazines. Thermal properties of these POSS-containing organic/inorganic polybenzoxazine nanocomposites have been improved over the pure polybenzoxazine analyzed by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The BZ-POSS monomer is poorly miscible with the benzoxazine monomer and tends to aggregate and forms its own domains, both before and after polymerization. At a higher BZ-POSS content, gross aggregation occurs and results in a lower than expected improvement in the thermal properties.     

多面体低聚倍半硅氧烷的合成研究进展

首先介绍了多面体低聚倍半硅氧烷(POSS)的结构、分类和性质,然后综述了三官能度硅烷或四官能度硅烷在酸、碱和有机盐催化下通过水解缩合反应合成POSS的研究进展,以及以POSS为母体、通过封端关笼法、闭环法和官能团转化法合成POSS的研究进展。     

1+1热轧机组中凸度控制技术

试验以解决带材中凸度过大为目的,制定了把带材中凸度控制在1%以下的试验目标。重点关注两点:弯辊调整对板形中凸度的影响和不同工作辊凸度对板中凸度的影响。     

余留统计迭代(RBSI)优化模型的凸性研究

本文给出了有关RBSI优化模型的几个性质,证明了余留统计迭代算法中描述的水库群非线性优化模型是一个凸规划问题。     

接枝法制备聚苯乙烯/笼型倍半硅氧烷复合材料

以工业级的3-氯丙基三氯硅烷和七聚(苯基)倍半硅氧烷三硅醇钠为原料,通过顶端封角法合成了含有一个3-氯丙基、七个苯基的单官能团POSS(3-氯丙基POSS),并以其作为聚苯乙烯的添加剂,采用化学接枝的方法制备POSS/PS复合材料.利用傅立叶转变红外光谱(FT-IR)、核磁共振(1H-NMR、29Si-NMR)和X-射...