东河储层损害机理分析

钻井液和酸化体系与储层流体不配伍是造成油层损害的主要原因。东河砂岩含有不同类型敏感性矿物,利用常规钻井液和酸化技术难以达到保护储层的目的。本文在分析东河储层敏感性损害机理前提下,提出保护油层的2项措施。     

PH敏感性水凝胶的分子热力学模型

本工作是在非离子凝胶的分子热力学模型基础，引入Ｄｏｎｎａｎ平衡项和大分子离子链的静电排斥项对凝胶自由能的贡献，建立了一个新的离子凝胶的分子热力学模型。该模型在解释离子凝胶的ＰＨ敏感性及其各种影响因素，以及预测ＰＨ溶胀曲线方面都取得了较好的效果。     

Platinum particle size effect on the oxidative dehydrogenation of aqueous ethanol

The effect of the platinum particle size was investigated for the catalytic oxidative dehydrogenation of aqueous ethanol to ethanal at a temperature of 303 K, an ethanol concentration of 260 mol m^–3, a partial oxygen pressure 60 kPa, a pH of 9, and an ethanal and ethanoate concentration of 20 mol m^–3. A particle size effect on the turnover frequency was observed but only for particle sizes smaller than 2 nm. Hence, the reaction shows a limited structure sensitivity.     

Hydrogen evolution during the oxidation of formaldehyde on Au:: The influence of single crystal structure and Tl-upd

Hydrogen evolution during formaldehyde oxidation in alkaline solution has been monitored by Differential Electrochemical Mass Spectrometry on Au(111) and polycrystalline gold. The current efficiency for hydrogen evolution increases with higher concentration and is in the same range on both, polycrystalline Au and Au(111) electrode. The onset potentials and half-wave potentials are higher on Au(111). Reaction orders for the faradaic current on the bare gold electrodes have been determined as 0.21 for higher and 0.76 for lower concentrations. Reaction orders for hydrogen evolution during formaldehyde oxidation are 1.4 times higher in each case. Tafel slopes in the range of 140-160 mV are found. This signifies that the first reaction step involving the formation of adsorbed hydrogen is largely determining the overall reaction rate. In the presence of thallium adlayers hydrogen evolution from formaldehyde oxidation is largely suppressed. On the thallium modified polycrystalline Au, formaldehyde oxidation is shifted for 100 mV to higher potentials where Tl is partially desorbed and hydroxide is coadsorbed on the modified surface. On thallium modified Au(111), a similar process takes place, but in the same potential region as the onset of formaldehyde oxidation on the bare surface and therefore the formaldehyde oxidation is only slightly shifted. Tafel slopes are decreased to 80 mV/dec in the presence of thallium. In the presence of adsorbed thallium, the first reaction step is in equilibrium, the coverage with adsorbed hydrogen is smaller and its recombination to H₂ is largely suppressed.     

Humidity sensitivity of polypyrrole and polypyrrole/SBA‐15 host–guest composite materials

Polypyrrole (PPY) and PPY/SBA‐15 host–guest composite materials have been prepared using chemical synthesis route and characterized by XRD, IR, N₂ adsorption–desorption isotherms, and SEM. The humidity sensitive properties (HSP) of this kind of materials have been studied by analyzing the variation curve of impedance as a function of relative humidity. It was found that the PPY/SBA‐15 host–guest composites materials exhibit better HSP than that of the corresponding pure PPY. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3301–3305, 2006     

含防爆剂农用硝酸铵的感度研究

实验在169℃左右加热硝酸铵到熔融状态,加入防爆剂,冷却到室温,得到含防爆剂的硝酸铵。测试其摩擦感度、5 s延滞期爆发点、静电火花感度以及配成铵油炸药后的撞击感度、雷管感度。结果表明,含防爆剂硝酸铵较普通硝酸铵撞击感度从88%降到24%,摩擦感度降为0%,5 s爆发延滞期从462℃增加到474℃,静电火花感度和雷管感度无明显变化。     

金沙江典型水库水温影响因素敏感性分析

在拱坝温度应力计算等领域,库水温是重要的边界条件,对其计算精度要求较高,尤其对于高拱坝上游库水温而言,需要进行详细研究。库水温的影响因素较多,如河道的类型、水库的来水流量、来水温度、气象条件等,如何合理考虑各项因素对库水温分布的影响,对于计算的精确度意义重大。利用横向平均的二维水动力模型来研究金沙江上向家坝、溪洛渡、白鹤滩、乌东德等4座水动力特征相似水库的水温时空动态分布,并以典型水库溪洛渡为例,对该水库的来水流量、来水温度和气象条件等因素进行敏感性分析。研究成果可为后续几座水库的水温计算分析提供参考。     

精密注塑件的生产稳定性探讨

针对精密注塑件的生产,介绍了设计,成型精密注塑件的基本要求,探讨了原材料,注塑机,电压,环境温湿度及模具积垢等因素对生产精密注塑件稳定性的影响,研究了评估工艺参数敏感性的试验方法和获得稳定工艺的手段;说明了统计过程控制（SPC）的基本原理,以及如何利用控制图和工序能力指数CP,CPK来评估,预测工序能力,确保工序确定性。     

基于密度调整的改进自适应谱聚类算法

针对谱聚类存在构造相似度矩阵时对尺度参数敏感以及处理多重尺度数据集效果不理想的缺陷, 提出一种基于密度调整的改进自适应谱聚类算法. 该算法将样本点所处领域的密度引入谱聚类, 利用密度差来调整样本点之间的相似度, 使其更符合实际簇类中样本点间的内在关系, 在一定程度上解决了多尺度聚类问题; 同时, 通过样本点的近邻距离自适应得到尺度参数, 使算法对尺度参数相对不敏感. 仿真实验验证了所提出算法的有效性和优越性.

     

敏感性问题的一种调查方法

基于调查数量特征的敏感性问题的随机变量乘法模型提出了一种改进模型,该模型比随机变量乘法模型有着更高的精度．由此,将此改进模型推广到最优分配下的分层抽样情形,在总体适合分层时,能提高总体估计量的估计精度;另外,由于在不同层中可以使用不同的随机化装置,这在实际的调查操作中有着更强的可行性．