振动剪切作用下聚合物熔体的非仿射网络结构模型 Ⅱ．非仿射网络结构模型

假设聚合物熔体的缠结网络形变是非仿射的，运用瞬态网络结构原理，采用在本课题第一部分^[1]中所建立的动态速率方程，并对上随体Maxwell本构方程加以修正来建立一个非仿射网络结构模型，利用这一模型来研究振动剪切作用下LDPE熔体的流变行为，研究表明，随着应变振幅和频率的增加，LDPE熔体的剪切应力也增加，同时指出了非仿射网络结构模型的精确变比仿射结构模型有较大提高，这表明在振动力场作用下，网络形变发生了非仿射形变，因此在建立振动力场作用下聚烯烃熔体本构方程时，不能假设其网络是仿射形变的。     

促进三峡库区和谐稳定发展评价方法研究

三峡库区已完成了百万移民的搬迁安置,进入了移民安稳致富的新阶段,库区社会和谐稳定对促进库区经济社会健康发展和实现全面建成小康社会的目标具有重要作用。本研究重点关注和谐库区建设思路及评价指标体系构建:一方面,从理论层面,重点论述与库区和谐社会相关的理论认识成果;另一方面,从实际管理运用层面,构建了库区和谐评价指标体系,可为移民动态管理提供有力的技术支撑。     

含活性二氧化硅蓖麻油型聚氨酯互穿网络的物理性质

以Ｎ，Ｎ－二甲基苯胺，１％（按ＩＰＮ质量计，下同）过氧化二苯甲酰和二丁基二月桂酸锡（简称有机锡）为固化剂，活性二氧化硅为填充剂（用量为总质量的３０％），由４７％的甲基丙烯酸甲酯与蓖麻油，２，４－甲苯二异氰酸酯型聚氨酯组成的ＩＰＮ为基材，在２５－３０℃下经８－１２ｈ固化。固化材料的体积电阻率和表面电阻率可达１０＾１３数量级，介电常数为５．５－６．０，介电损耗角正切为０．０１８－０．０２０，拉伸强度为     

The role of clay network on macromolecular chain mobility and relaxation in isotactic polypropylene/organoclay nanocomposites

It is well known that a so-called “three-dimensional filler network structure” will be constructed in the polymer/layered silicate nanocomposites when the content of layered clay reaches a threshold value, at which the silicate sheets are incapable of freely rotating, due to physical jamming and connecting of the nanodispersed layered silicate. In this article, the effect of such clay network on the mobility and relaxation of macromolecular chains in isotactic polypropylene(iPP)/organoclay nanocomposites was investigated in detail with a combination of DMTA, DSC, TGA, TEM, rheometry and melt flow index measurements. The main aim is to establish a relationship between the mesoscopic filler network structure and the macroscopic properties of the polymer nanocomposites, particularly to explore the role of the clay network on the mobility and relaxation of macromolecular chains. It was found that the nanodispersed clay tactoids and layers play less important or dominant roles on the mobility of iPP chains depending on the formation of percolating filler network. The turning point of macroscopic properties appeared at 1 wt% organoclay content. Before this point, the effect of organoclay can be negligible, and the increase of chain mobility was ascribed to the decrease of molecular weight of polymer chains, as commonly occurs during dynamic melt processing; after this point, however, a reduced mobility of chains and a retarded chain relaxation were observed and attributed to the formation of a mesoscopic filler network. The essential features of such a mesoscopic organoclay network were estimated and discussed on the basis of stress relaxation and structural reversion measurements. A schematic model was proposed to describe the different relaxation and motion behaviors of macromolecular chains in the unfilled polymer and the filled hybrids with partial and percolated organoclay networks, respectively.     

环氧-聚氨酯互穿网络防腐蚀涂料

研制的环氧-聚氨酯互穿网络(IPN)防腐蚀涂料具有优异的防腐蚀性能和附着力。介绍了该涂料的制法。列举了IPN涂层的性能指标。讨论了影响涂层性能的各种因素。     

Expectations and Experiences With MyLabourParty: From Right to Know to Right to Participate?

Social media are often argued to change political communication, decreasing the distance between politicians and citizens, and increasing citizens' influence on policymaking. This paper presents findings from a study of how the Norwegian Labour Party uses social media, focusing on the community platform MyLabourParty. Interviews with politicians and a survey with citizens as respondents were conducted to examine the experiences of online political discussions. Findings show that citizens and politicians expect MyLabourParty to strengthen citizen participation. Yet, citizens still experience communication asymmetry and politicians may find it challenging to participate to the extent citizens expect. Means for bridging the gap between expectations and experiences are called for, in particular redefinition of the offering, changes of user‐practices, and system improvements.     

Tele‐Cocooning: Mobile Texting and Social Scope

The present study examines the tele‐cocooning hypothesis in the context of general trust using a nationally representative survey of Japanese youth. We find that although frequency of texting is positively correlated with general trust, this correlation is spuriously caused by how heavy mobile texters interpret the words “most people” in the general trust measurement. Heavy users assume that “most people” only refers to friends, family, and others going to the same school. When the effect of the “most people” assumption is controlled, the positive association between texting and general trust disappears. Further exploration of the data shows that heavy texting nevertheless has negative implications for social tolerance and social caution, both of which are theoretically proximate to general trust.     

Investigating Modern‐Day Talaria: Mobile Phones and the Mobility‐Impaired in Singapore

Revisiting the medical and social models of disability, this study adopted the integrated biopsychosocial approach to examine experiences of 25 mobility‐impaired respondents in Singapore with using mobile phones. We found that mobile phones provided respondents a greater degree of mobility, a sense of control, and opportunities to escape the stigma of disability, thus challenging the boundaries between the able‐bodied and the disabled. Mobile phone appropriation allowed the management of personal identities and social networks, leading to a sense of empowerment. However, mobile phone usage might act as a double‐edged sword for disabled people, creating mobile dependencies and a spatial narrowing of social connections. Theoretical and practical implications are discussed.     

Knowledge transfer in IT offshoring relationships: the roles of social capital,efficacy and outcome expectations

Information technology (IT) development in global organisations relies heavily on the transfer of tacit and complex knowledge from onshore units to offshore subsidiaries. A central concern of such organisations is the development of social capital, which is known to facilitate the smooth transfer of knowledge. However, only a few studies in IS research have explicitly examined the role of social capital for knowledge transfer in an IT offshoring context. In this paper, we argue that such knowledge transfer mechanisms can be understood better by considering social capital in concert with knowledge senders' efficacy and outcome expectations, two of the potentially key motivational drivers of knowledge transfer. We develop our arguments through a qualitative case study of a large German multinational company. German IT developers in this firm provided in‐depth accounts of their experience with offshore colleagues in an Indian captive subsidiary unit. Drawing on our analysis, we develop a model that depicts the influence of social capital, efficacy and outcome expectations on onshore IT developers' ability and willingness to transfer knowledge to offshore colleagues. Through the model, we also explain how social capital, efficacy and outcome expectations are interrelated and generate three interlocked, self‐reinforcing circles of knowledge transfer success in IT offshoring relationships.