全文获取类型
收费全文 | 22039篇 |
免费 | 2401篇 |
国内免费 | 1241篇 |
专业分类
电工技术 | 740篇 |
综合类 | 1418篇 |
化学工业 | 7590篇 |
金属工艺 | 1526篇 |
机械仪表 | 900篇 |
建筑科学 | 731篇 |
矿业工程 | 563篇 |
能源动力 | 1340篇 |
轻工业 | 2792篇 |
水利工程 | 198篇 |
石油天然气 | 1160篇 |
武器工业 | 668篇 |
无线电 | 1045篇 |
一般工业技术 | 2680篇 |
冶金工业 | 1238篇 |
原子能技术 | 312篇 |
自动化技术 | 780篇 |
出版年
2024年 | 108篇 |
2023年 | 482篇 |
2022年 | 616篇 |
2021年 | 795篇 |
2020年 | 820篇 |
2019年 | 821篇 |
2018年 | 738篇 |
2017年 | 872篇 |
2016年 | 926篇 |
2015年 | 789篇 |
2014年 | 1166篇 |
2013年 | 1321篇 |
2012年 | 1421篇 |
2011年 | 1415篇 |
2010年 | 1114篇 |
2009年 | 1110篇 |
2008年 | 966篇 |
2007年 | 1304篇 |
2006年 | 1277篇 |
2005年 | 1150篇 |
2004年 | 1047篇 |
2003年 | 895篇 |
2002年 | 822篇 |
2001年 | 677篇 |
2000年 | 603篇 |
1999年 | 441篇 |
1998年 | 344篇 |
1997年 | 300篇 |
1996年 | 214篇 |
1995年 | 207篇 |
1994年 | 192篇 |
1993年 | 141篇 |
1992年 | 131篇 |
1991年 | 96篇 |
1990年 | 80篇 |
1989年 | 62篇 |
1988年 | 47篇 |
1987年 | 34篇 |
1986年 | 24篇 |
1985年 | 27篇 |
1984年 | 19篇 |
1983年 | 11篇 |
1982年 | 17篇 |
1981年 | 4篇 |
1980年 | 13篇 |
1979年 | 7篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1951年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
M. Bechelany A. Brioude P. Stadelmann G. Ferro D. Cornu P. Miele 《Advanced functional materials》2007,17(16):3251-3257
We present a simple process for the fabrication of very long SiC‐based coaxial nanocables (NCs). The versatility of this technique is confirmed by the ability to change the chemical composition of the NC outer layers from silica to carbon and boron nitride. The NCs consist of a SiC core approximately 30 nm in diameter with lengths up to several hundred of nanometers. The thickness of the coating is in the range 2–10 nm. The morphology and structural characterization of the NCs is investigated by scanning electron microscopy (SEM) and high‐resolution transmission electron microscopy (HRTEM), respectively, and their chemical composition is probed by electron energy loss spectroscopy (EELS). A vapor–solid growth mechanism is proposed to explain the growth of SiC‐based NCs of various chemical compositions, depending on the chemical nature of the vapor phase. Because of the large quantity of very long and interlaced NCs produced during the synthesis, the macroscopic aspect of the as‐grown material is like a self‐supported felt. 相似文献
62.
Wei Wei Craig A. BennettRyuzo Tanaka Gang HouMichael T. Klein Jr. Michael T. Klein 《Fuel Processing Technology》2008
The complexity of many chemical and refining reaction systems and the thus-derived tedious and time-consuming process of building the associated kinetic models have been major obstacles in the use of fundamental kinetics in the solution of chemical engineering problems. This review summarizes work aimed at removing theses obstacles. Our recent work that has led to the enhancement of the Kinetic Modeler's Toolbox (KMT) and the development of the Kinetic Model Editor (KME) presents an end-to-end solution to the kinetic modeling process, including automated feedstock modeling, reaction network construction, kinetic rate estimation, model programming, process system configurations, model customizations, compilations, model execution and results analysis. 相似文献
63.
固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮 总被引:3,自引:0,他引:3
采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。 相似文献
64.
65.
Adaptation of the microscopic properties of redox catalysts to the type of gas-solid reactor 总被引:1,自引:0,他引:1
Catalysts of selective oxidation usually work in a simultaneous redox mode in reactant/air cofed reactors. The solid must provide selective lattice oxygen according to a kinetic mechanism depending on operating conditions that differ from one reactor to another. Better catalytic performance can be obtained in a recirculating solids reactor because it allows separate optimization of the reduction and oxidation steps. Among the microscopic properties of the catalyst, the crystal morphology is to be taken into account because it influences its reactivity on stream. These considerations lead to a new approach of the catalyst-reaction-reactor trio. 相似文献
66.
液相对流对固液界面稳定性的影响 总被引:1,自引:0,他引:1
以模型合金丁二腈-乙醇的强制性晶体生长为基础,利用自行研制的液相对流驱动装置,详细考查了液相自然对流及强迫对流作用下,模型合金平界面失稳的动态生长过程,证实了液相的流动加快了液相温度与浓度分布的均匀化,从而增强了液/固界面的稳定性。并且随流动速度的增加,界面稳定性提高。 相似文献
67.
聚氧乙烯 - 聚氧丙烯 - 聚苯乙烯多嵌段聚合物的力学和导电性能研究 总被引:1,自引:0,他引:1
研究了聚苯乙烯含量对聚氧乙烯-聚氧丙烯-聚苯乙烯多嵌段聚合物的力学性能及其与LiClO4络合物的离子导电性能的影响;并以电导率较高的络合物为电解质,Na1+xV3O8复合物和Li片分别为正、负极组装了薄型锂电池并测定其放电性能。 相似文献
68.
Studies of the complete oxidation of methane on a Pt electrode-catalyst in the cell with a solid proton-conducting electrolyte (CH4 + O2, Pt ¦ SrCe0.92Dy0.08O3 ¦ Pt, H2O + N2) were carried out. The non-Faradaic effect of electrochemical hydrogen pumping on the rate of methane oxidation has been demonstrated. The induced change in the reaction rate at anodic polarization of a Pt electrode-catalyst was over two orders of magnitude higher than the rate of hydrogen pumping from the reaction zone through the electrolyte. 相似文献
69.
Catalytic chlorination of methane was studied over SO
4
2–
/ZrO2, Pt/SO
4
2–
/ZrO2, and Fe/Mn/SO
4
2–
/ZrO2 solid superacid catalysts. The reactions were carried out in a continuous flow reactor under atmospheric pressure, at temperatures below 240°C, with a gaseous hourly space velocity of 1000 ml/g h and a methane to chlorine ratio of 4 to 1. At 200°C with 30% chlorine converted the selectivity in methyl chloride exceeds 90%. At more elevated temperatures, the selectivity decreases but stays above 80% in methyl chloride at 225°C using the sulfated zirconia catalysts. The selectivity can be enhanced by adding platinum to sulfated zirconia catalysts. An iron and manganese-doped catalyst exhibited excellent selectivities at somewhat lower conversions. Methyl chloride is obtained at 235°C in selectivities greater than 85%. No chloroform or carbon tetrachloride is formed. The electrophilic insertion involves electron-deficient metal-coordinated chlorine into the methane C-H bond.Catalysis by solid superacids, 29. For part 28 see ref. [14]. 相似文献
70.
Savitree Jungsakulrujirek & Athapol Noomhorm 《International Journal of Food Science & Technology》1998,33(4):367-374
The effect of fruit size and harvesting of Thai tangerine fruit ( Citrus reticulata , Blanco) at different growth stages, 8–12 months after fruit set, on the distribution of limonin in whole fruit as well as in the individual fruit parts and extracted juice was investigated. The highest limonin concentration was observed in seed, followed by albedo, flavedo, segment membrane and juice sacs in decreasing order. The limonin concentration in juice as well as in whole fruit was decreased when fruit was harvested 8–12 months of fruit set. Increasing harvesting time from 8 to 12 months showed corresponding decreases in the amount of limonin in flavedo, albedo and seed. There was a decrease in titrable acidity and increase in total soluble solid and total soluble solid/titrable acidity ratio of juice with a later than normal harvesting time. However, fruit size showed no effect on limonin content and other properties of juice extracted from tangerine. 相似文献