Structural effect on controllable resistive memory switching in donor–acceptor polymer systems

Controllable bistable electrical conductivity switching behavior and resistive memory effects have been demonstrated in Al/polymer/indium-tin oxide (ITO) sandwich structure devices, constructed from non-conjugated vinyl copolymers of PTPA_nOXD_m with pendant donor–acceptor chromophores. The observed electrical bistability can be attributed to the field-induced intra- and intermolecular charge transfer interaction between triphenylamine electron donor (D) and oxadiazole electron acceptor (A) entities, and is highly dependent on the chemical structure of the copolymers. The vinyl copolymers showed different memory behaviors, which depended on the loading of D/A ratios. The polymers containing only donor or acceptor moieties showed as insulators, the polymers containing both donor and acceptor moieties showed as WORM, flash and DRAM as D/A ratio increased. The structural effect on the physicochemical and electronic properties of the PTPA_nOXD_m copolymers, viz surface morphology, thermal stability, optical absorbance and photoluminescence, and molecular orbital energy levels, were investigated systematically to study the factors that influence the memory characteristics of the devices.     

基于人工免疫的机车二系调簧方法

为进一步提高电力机车二系支承载荷调整优化算法的性能,解决已有算法在加垫数量控制上的欠缺,并避免冗余计算,提出了一种基于人工免疫算法的两级结构机车二系载荷调整方法:免疫优势克隆选择多目标算法。针对调簧问题的偏好结构特点,设计具有调簧寻优阶段和可控加垫量寻优阶段的两级寻优算法,分别定义了两个阶段的寻优目标和可行域,进一步将调簧问题的先验知识作为免疫优势引入算法设计中,并结合调簧问题的具体特点以及人工免疫知识设计了特定的抗体编码形式、变异策略和免疫优势获得算法。对不同车型的多次应用试验统计结果表明:该算法不仅具有良好的优化载荷分布特性,还能稳定地控制调簧产生的加垫数量,并且能够避免冗余计算,极大地提高了调簧效率和实际应用价值。     

A novel PWM control for a bi-directional full-bridge DC–DC converter with smooth conversion mode transitions

A novel CMOS integrated pulse-width modulation (PWM) control circuit allowing smooth transitions between conversion modes in full-bridge based bi-directional DC–DC converters operating at high switching frequencies is presented. The novel PWM control circuit is able to drive full-bridge based DC–DC converters performing step-down (i.e. buck) and step-up (i.e. boost) voltage conversion in both directions, thus allowing charging and discharging of the batteries in mobile systems. It provides smooth transitions between buck, buck-boost and boost modes. Additionally, the novel PWM control loop circuit uses a symmetrical triangular carrier, which overcomes the necessity of using an output phasing circuit previously required in PWM controllers based on sawtooth oscillators. The novel PWM control also enables to build bi-directional DC–DC converters operating at high switching frequencies (i.e. up to 10?MHz and above). Finally, the proposed PWM control circuit also allows the use of an average lossless inductor-current sensor for sensing the average load current even at very high switching frequencies. In this article, the proposed PWM control circuit is modelled and the integrated CMOS schematic is given. The corresponding theory is analysed and presented in detail. The circuit simulations realised in the Cadence Spectre software with a commercially available 0.18?µm mixed-signal CMOS technology from UMC are shown. The PWM control circuit was implemented in a monolithic integrated bi-directional CMOS DC–DC converter ASIC prototype. The fabricated prototype was tested experimentally and has shown performances in accordance with the theory.     

A customized low-rank prior model for structured cartoon–texture image decomposition

The mathematical characterization of the texture component plays an instrumental role in image decomposition. In this paper, we are concerned with a low-rank texture prior based cartoon–texture image decomposition model, which utilizes a total variation norm and a global nuclear norm to characterize the cartoon and texture components, respectively. It is promising that our decomposition model is not only extremely simple, but also works perfectly for globally well-patterned images in the sense that the model can recover cleaner texture (or details) than the other novel models. Moreover, such a model can be easily reformulated as a separable convex optimization problem, thereby enjoying a splitting nature so that we can employ a partially parallel splitting method (PPSM) to solve it efficiently. A series of numerical experiments on image restoration demonstrate that PPSM can recover slightly higher quality images than some existing algorithms in terms of taking less iterations or computing time in many cases.     

Toward High-Performance Dihydrophenazine-Based Conjugated Microporous Polymer Cathodes for Dual-Ion Batteries through Donor–Acceptor Structural Design

Recent studies have demonstrated that dihydrophenazine (Pz) with high redox-reversibility and high theoretical capacity is an attractive building block to construct p-type polymer cathodes for dual-ion batteries. However, most reported Pz-based polymer cathodes to date still suffer from low redox activity, slow kinetics, and short cycling life. Herein, a donor–acceptor (D–A) Pz-based conjugated microporous polymer (TzPz) cathode is constructed by integrating the electron-donating Pz unit and the electron-withdrawing 2,4,6-triphenyl-1,3,5-triazine (Tz) unit into a polymer chain. The D–A type structure enhances the polymer conjugation degree and decreases the band gap of TzPz, facilitating electron transportation along the polymer skeletons. Therefore the TzPz cathode for dual-ion battery shows a high reversible capacity of 192 mAh g⁻¹ at 0.2 A g⁻¹ with excellent rate performance (108 mAh g⁻¹ at 30 A g⁻¹), which is much higher than that of its counterpart polymer BzPz produced from 1,3,5-triphenylbenzene (Bz) and Pz (148 and 44 mAh g⁻¹ at 0.2 and 10 A g⁻¹, respectively). More importantly, the TzPz cathode also shows a long and stable cyclability of more than 10 000 cycles. These results demonstrate that the D–A structural design is an efficient strategy for developing high-performance polymer cathodes for dual-ion batteries.     

Unraveling the Significance of Li+/e−/O2 Phase Boundaries with a 3D-Patterned Cu Electrode for Li–O2 Batteries

The reaction kinetics at a triple-phase boundary (TPB) involving Li⁺, e⁻, and O₂ dominate their electrochemical performances in Li–O₂ batteries. Early studies on catalytic activities at Li⁺/e⁻/O₂ interfaces have enabled great progress in energy efficiency; however, localized TPBs within the cathode hamper innovations in battery performance toward commercialization. Here, the effects of homogenized TPBs on the reaction kinetics in air cathodes with structurally designed pore networks in terms of pore size, interconnectivity, and orderliness are explored. The diffusion fluxes of reactants are visualized by modeling, and the simulated map reveals evenly distributed reaction areas within the periodic open structure. The 3D air cathode provides highly active, homogeneous TPBs over a real electrode scale, thus simultaneously achieving large discharge capacity, unprecedented energy efficiency, and long cyclability via mechanical/electrochemical stress relaxation. Homogeneous TPBs by cathode structural engineering provide a new strategy for improving the reaction kinetics beyond controlling the intrinsic properties of the materials.     

基于腔输入-输出过程的原子Bell态分析器和GHZ态分析器

如何能够在不破坏纠缠态且能将其辨认区分出来是量子信息处理过程中一个很重要的问题,方案首先利用相干光与腔-原子系统的输入-输出过程构造受控相移门,然后利用受控相移门和零差探测技术构造宇称分析器,最后利用宇称分析器和Hadamard等操作构造非破坏性的原子Bell态分析器和原子GHZ态分析器。方案的优势在于:（1）利用到相干光源和零差探测技术,比以往方案中的单光子源和单光子探测较易实现;（2）构造的原子Bell态分析器和原子GHZ态分析器是非破坏性的。方案用到的所有方法和技术在目前的实验上都是可以实现的。     

An angle difference of directions arrival algorithm with channel inconsistency

This article proposes a new angle difference of directions arrival (ADOA) estimation algorithm. It can estimate the values of ADOA of incidence signals even under channel incoherence environments. It performs an eigenvalue decomposition of a covariance matrix to obtain signal and noise subspace eigenvectors, then estimates the values of ADOA of signals based on the orthogonality between the noise subspace eigenvectors and steering vectors. Its main advantage is that the performance is not degenerated by array elements channel incoherence. In addition, the system complexity is also reduced. Finally, the numerical simulations have been conducted to verify the performance improvement of this algorithm.     

Side information creation for efficient Wyner–Ziv video coding: Classifying and reviewing

Video coding technologies have played a major role in the explosion of large market digital video applications and services. In this context, the very popular MPEG-x and H-26x video coding standards adopted a predictive coding paradigm, where complex encoders exploit the data redundancy and irrelevancy to ‘control’ much simpler decoders. This codec paradigm fits well applications and services such as digital television and video storage where the decoder complexity is critical, but does not match well the requirements of emerging applications such as visual sensor networks where the encoder complexity is more critical. The Slepian–Wolf and Wyner–Ziv theorems brought the possibility to develop the so-called Wyner–Ziv video codecs, following a different coding paradigm where it is the task of the decoder, and not anymore of the encoder, to (fully or partly) exploit the video redundancy. Theoretically, Wyner–Ziv video coding does not incur in any compression performance penalty regarding the more traditional predictive coding paradigm (at least for certain conditions). In the context of Wyner–Ziv video codecs, the so-called side information, which is a decoder estimate of the original frame to code, plays a critical role in the overall compression performance. For this reason, much research effort has been invested in the past decade to develop increasingly more efficient side information creation methods. This paper has the main objective to review and evaluate the available side information methods after proposing a classification taxonomy to guide this review, allowing to achieve more solid conclusions and better identify the next relevant research challenges. After classifying the side information creation methods into four classes, notably guess, try, hint and learn, the review of the most important techniques in each class and the evaluation of some of them leads to the important conclusion that the side information creation methods provide better rate-distortion (RD) performance depending on the amount of temporal correlation in each video sequence. It became also clear that the best available Wyner–Ziv video coding solutions are almost systematically based on the learn approach. The best solutions are already able to systematically outperform the H.264/AVC Intra, and also the H.264/AVC zero-motion standard solutions for specific types of content.     

A multi-object image segmentation C–V model based on region division and gradient guide

The Chan–Vese (C–V) model is an ineffective method for processing images in which the intensity is inhomogeneous. This is especially true for multi-object segmentation, in which the target may be missed or excessively segmented. In addition, for images with rich texture information, the processing speed of the C–V is slow. To overcome these problems, this paper proposes an effective multi-object C–V segmentation model based on region division and gradient guide. First, a rapid initial contour search is conducted using Otsu’s method. This contour line becomes the initial contour for our multi-object segmentation C–V model based on a gradient guide. To achieve the multi-object segmentation the image is then converted to a single level set whose evolution is controlled using an adaptive gradient. The feasibility of the proposed model is analyzed theoretically, and a number of simulation experiments are conducted to validate its effectiveness.