The electroactive species in the catalysis of cyclohexadiene to benzene by Rh2(TM4) 4 +2 (TM4=2,5-diisocyano-2,5-dimethylhexane)

Upon further investigation of the recently reported electrocatalytic oxidation of 1,4-cyclohexadiene to benzene by Rh₂(TM4) ₄ ⁺² (TM4=2,5-diisocyano-2,5-dimethylhexane), we have obtained data which strongly implicates the 2e^– oxidized d⁷-d⁷ complex as the electroactive species. This contrasts with the original report which suggested that the le^– oxidized d⁷-d⁸ radical acted as the key species via hydrogen atom abstraction from 1,4-cyclohexadiene. A possible mechanism for the catalysis is proposed.     

海空背景下红外弱小目标检测方法

针对在海上搜救中弱小目标难以被发现的情况,提出了一种海空背景下红外弱小目标的检测方法.该方法首先进行背景预测,然后将原图像和背景预测后的图像差分进行目标提取,使用Top-Hat变换对目标提取后的差分图像进行滤波处理以去除残余波浪噪声影响,最后使用自适应阈值检测,检测出弱小目标所在的方位.通过和传统的对单帧图像采取Top-Hat变换滤波做法的比较,可以看出来该方法可以较好的去除海浪的影响,检测出亮度较高的红外运动弱小目标,辅助海上搜救工作的完成.     

支持关键词搜索的空间连接查询研究

近年来,许多实际应用不仅需要支持空间连接查询而且需要具备关键词搜索功能,以帮助用户查找那些既满足空间连接条件又包含指定关键词的空间对象组合.正是在这种需求的驱动之下,定义了一种具备关键词搜索功能的空间连接查询(Spatial Join with Keyword Search,缩写SJKS),并提出了一种基于IR2-Tree的SJKS查询处理算法(IR2-TreeSJKS算法),旨在实现关键词搜索与空间连接查询的高效结合.实验表明,本算法可有效支持具有关键词搜索功能的空间连接查询处理.     

Ordinal Regression for Information Retrieval

This letter presents a new discriminative model for Information Retrieval （IR）, referred to as Ordinal Regression Model （ORM）. ORM is different from most existing models in that it views IR as ordinal regression problem （i.e. ranking problem） instead of binary classification. It is noted that the task of IR is to rank documents according to the user information needed, so IR can be viewed as ordinal regression problem. Two parameter learning algorithms for ORM are presented. One is a perceptron-based algorithm. The other is the ranking Support Vector Machine （SVM）. The effectiveness of the proposed approach has been evaluated on the task of ad hoc retrieval using three English Text REtrieval Conference （TREC） sets and two Chinese TREC sets. Results show that ORM significantly outperforms the state-of-the-art language model approaches and OKAPI system in all test sets; and it is more appropriate to view IR as ordinal regression other than binary classification.     

ATR Contributes More Than ATM in Intra-S-Phase Checkpoint Activation after IR,and DNA-PKcs Facilitates Recovery: Evidence for Modular Integration of ATM/ATR/DNA-PKcs Functions

The intra-S-phase checkpoint was among the first reported cell cycle checkpoints in mammalian cells. It transiently slows down the rate of DNA replication after DNA damage to facilitate repair and thus prevents genomic instability. The ionizing radiation (IR)-induced intra-S-phase checkpoint in mammalian cells is thought to be mainly dependent upon the kinase activity of ATM. Defects in the intra-S-phase checkpoint result in radio-resistant DNA synthesis (RDS), which promotes genomic instability. ATM belongs to the PI3K kinase family along with ATR and DNA-PKcs. ATR has been shown to be the key kinase for intra-S-phase checkpoint signaling in yeast and has also been implicated in this checkpoint in higher eukaryotes. Recently, contributions of DNA-PKcs to IR-induced G₂-checkpoint could also be established. Whether and how ATR and DNA-PKcs are involved in the IR-induced intra-S-phase checkpoint in mammalian cells is incompletely characterized. Here, we investigated the contributions of ATM, ATR, and DNA-PKcs to intra-S-phase checkpoint activation after exposure to IR of human and hamster cells. The results suggest that the activities of both ATM and ATR are essential for efficient intra-S-phase checkpoint activation. Indeed, in a wild-type genetic background, ATR inhibition generates stronger checkpoint defects than ATM inhibition. Similar to G2 checkpoint, DNA-PKcs contributes to the recovery from the intra-S-phase checkpoint. DNA-PKcs–deficient cells show persistent, mainly ATR-dependent intra-S-phase checkpoints. A correlation between the degree of DSB end resection and the strength of the intra-S-phase checkpoint is observed, which again compares well to the G2 checkpoint response. We conclude that the organization of the intra-S-phase checkpoint has a similar mechanistic organization to that of the G₂ checkpoint in cells irradiated in the G₂ phase.     

基于红外辐射特性的单波段红外图像被动测距

以单波段红外图像被动测距为研究背景,首先分析了凝视型红外探测系统的工作原理,将其工作过程分为入瞳前和入瞳后两个不同的阶段,其中第一阶段与目标距离相关,而第二阶段则决定于红外探测系统本身的传递函数,而后对图像像素灰度与入瞳处辐亮度之间的关系进行了表述;然后针对点目标与面目标的成像特点,分别计算了相应的目标与背景的入瞳处幅亮度差,得出:两者的红外辐射特性存在一致性.基于短时间内目标近似匀速运动的假设,推导了单波段红外图像被动测距方法.最后利用外场实测中长波红外图像对该算法进行了验证,并对测距结果和测距误差进行了详细分析.     

红外制导武器的现状及发展趋势

红外制导可分为红外半自动制导、点源寻的制导、成像制导和未敏制导等几类。综述了各国研制的红外制导武器及其发展趋势。     

IR2304半桥驱动集成电路的功能原理及应用

IR2304是美国IR公司生产的新一代半桥驱动集成芯片，该芯片内部集成了互相独立的控制驱动输出电路，可直接驱动两个中功率半导体器件如MOSFET或IGBT，动态响应快，驱动能力强，工作频率高，且具有多种保护功能。文中介绍了IR2304的功能特点、工作原理和典型应用电路。     

高帧频MOS电阻阵红外成像目标模拟器实时控制研究

针对高帧频MOS电阻阵的特点,对红外成像目标模拟器实时控制方法进行研究,在控制部分硬件设计方面,就通讯协议、图像数据传输驱动、图像逻辑控制驱动等提出了较为详细的设计思路。     

降温涂料在红外隐身中的应用

本文介绍了降温涂料的作用原理,并对大型军事目标的红外伪装方法作了阐述。结合降温涂料在红外伪装中的应用研究,从理论上提出了降温涂料的改进方法。