Ti—C—Al体系热爆合成过程

采用整体加热燃烧合成法（即热爆合成）制备了ＴｉＣ－Ａｌ复合体系，利用差热分析（ＤＴＡ）、Ｘ射线衍射分析（ＸＲＤ）和扫描电镜（ＳＥＭ）等手段研究了Ｔｉ－Ｃ－Ａｌ体系中升温速度及Ａｌ含量对ＴｉＣ反应合成过程的影响，分析了Ａｌ基体对ＴｉＣ粒子的形成机理．结果表明，在ＴｉＣ反应合成过程中，首先是Ｔｉ与Ａｌ反应形成Ｔｉ与Ａｌ的化合物，放出热量，随后促使Ｔｉ与Ｃ的放热反应发生，合成ＴｉＣ时放热产生的高温使Ｔｉ与Ａｌ的化合物分解，从而制得ＴｉＣ－Ａｌ复合体系；升温速度及Ａｌ含量只有超过一定值时，该体系才能在较低温度发生热爆反应；当Ａｌ的质量分数从１０％升至５０％时，ＴｉＣ的粒度从５．０μｍ阵至０．５μｍ．     

水上无人机自主着水控制系统设计

针对水上无人机在高海况下的着水问题,本文在分析了不同着水阶段特性的基础上,提出了一种自主着水控制系统设计方案.该方案将整个系统分为速度控制子系统和姿态控制子系统.速度控制子系统包含速度动态逆控制器和油门切换模块,姿态控制子系统包含海浪滤波器俯仰角反步控制器、高度PID控制器、俯仰角切换模块和T-S模糊推理模块.其中,海浪滤波器能有效滤除受扰姿态角中的海浪高频扰动,避免了着水之后舵面的频繁抖动;俯仰角反步控制器采用指令滤波的反步法设计,有效缓解了高海况下的舵面饱和问题.最后,在不同海况条件下进行了仿真.仿真结果表明所设计的控制系统具有良好的控制性能.     

CNG加气站爆炸燃烧的交通疏散仿真分析

随着石油资源的日益短缺和国家能源战略的调整,环保要求和汽车技术的不断提高,燃气车辆不断增多,与之相对应的车用加气站的数量也越来越多。但是接连发生的加气站燃气泄漏与火灾事故使得加气站的使用安全问题成为日益关注的问题。当加气站出现燃气泄漏与火灾事故时,天然气未立即着火可形成爆炸气体云团,遇火就会发生爆炸,在危险距离以内,人会受到爆炸冲击波的伤害。重点将对CNG加气站爆炸事故后的交通疏散条件制定分级标准,结合实例采用计算机软件仿真疏散分析,对以后进行新建加气站的安全评估分析工作开展提供定量依据。     

Interference automata

We propose a computing model, the Two-Way Optical Interference Automata (2OIA), that makes use of the phenomenon of optical interference. We introduce this model to investigate the increase in power, in terms of language recognition, of a classical Deterministic Finite Automaton (DFA) when endowed with the facility of interference. The question is in the spirit of Two-Way Finite Automata With Quantum and Classical States (2QCFA) [A. Ambainis, J. Watrous, Two-way finite automata with quantum and classical states, Theoret. Comput. Sci. 287 (1) (2002) 299–311] wherein the classical DFA is augmented with a quantum component of constant size. We test the power of 2OIA against the languages mentioned in the above paper. We give efficient 2OIA algorithms to recognize languages for which 2QCFA machines have been shown to exist, as well as languages whose status vis-a-vis 2QCFA has been posed as open questions. Having a DFA as a component, it trivially recognizes regular languages. We show that our model can recognize all languages recognized by 1-way deterministic blind counter automata. Finally we show the existence of a language that cannot be recognized by a 2OIA but which can be recognized by an O(n³)$O\left(n^3\right)$ space Turing machine.     

水下刚性壁装药爆炸气泡简化模型和数值仿真

为预测沉底装药水下爆炸产生气泡的最大半径和脉动周期,建立了水下刚性壁上的装药爆炸产生气泡的动力学模型.从Bernoulli方程和能量守恒两个角度推导出描述半球形气泡径向运动的流体动力学方程,通过能量法确定了方程的初始条件.对方程数值求解得到第一脉动周期内气泡半径和径向运动速度随时间变化的曲线.利用ANSYS-AUTODYN软件的高精度Euler-Godunov求解器和计算结果映射技术,建立了水下刚性壁上装药爆炸产生气泡运动的数值仿真模型.计算得到了气泡膨胀、收缩、上浮和脉动压力时程曲线及其几何形状变化规律.理论模型与仿真计算得到的气泡半径、脉动周期和径向运动速度均吻合,说明该理论模型满足工程所需精度要求.     

Probing into Reverse Bias Dark Current in Perovskite Photodiodes: Critical Role of Surface Defects

Minimizing reverse bias dark current density (J_dark) while retaining high external quantum efficiency is crucial for promising applications of perovskite photodiodes, and it remains challenging to elucidate the ultimate origin of J_dark. It is demonstrated in this study that the surface defects induced by iodine vacancies are the main cause of J_dark in perovskite photodiodes. In a targeted way, the surface defects are thoroughly passivated through a simple treatment with butylamine hydroiodide to form ultrathin 2D perovskite on its 3D bulk. In the passivated perovskite photodiodes, J_dark as low as 3.78 × 10^-10 A cm^-2 at -0.1 V is achieved, and the photoresponse is also enhanced, especially at low light intensities. A combination of the two improvements realizes high specific detectivity up to 1.46 × 10¹² Jones in the devices. It is clarified that the trap states induced by the surface defects can not only raise the generation-recombination current density associated with the Shockley–Read–Hall mechanisms in the dark (increasing J_dark), but also provide additional carrier recombination paths under light illumination (decreasing photocurrent). The critical role of surface defects on J_dark of perovskite photodiodes suggests that making trap-free perovskite thin films, for example, by fine preparation and/or surface engineering, is a top priority for high-performance perovskite photodiodes.     

Kinetically Accelerating Elementary Steps via Bridged Ru-H State for the Hydrogen-Evolution in Anion-Exchange Membrane Electrolyzer

Designing hydrogen evolution reaction (HER) electrocatalysts for facilitating its sluggish adsorption kinetics is crucial in generating green hydrogen via sustainable water electrolysis. Herein, a high-performance ultra-low Ruthenium (Ru) catalyst is developed consisting of atomically-layered Ru nanoclusters with adjacent single Ru sites, which executs a bridging-Ru-H activation strategy to kinetically accelerate the HER elementary steps. Owing to its optimal electronic structure and unique adsorption configuration, the hybrid Ru catalyst simultaneously displayed a drastically reduced overpotential of 16 mV at 10 mA cm⁻² as well as a low Tafel slope of 35.2 mV dec⁻¹ in alkaline electrolyte. When further coupled with a commercial IrO₂ anode catalyst, the ensembled anion-exchange membrane water electrolyzer achievs a current density of 1.0 A cm⁻² at a voltage of only 1.70 V_cell. In situ spectroscopic analysis verified that Ru single atom and atomically-layered Ru nanoclusters in the hybrid materials play a critical role in facilitating water dissociation and weakening *H adsorption, respectively. Theoretical calculations further elucidate the underlaying mechanism, suggesting that the dissociated proton at the single atom Ru site orients itself adjacently with Ru nanoclusters in a bridged structure through targeted charge transfer, thus promoting Volmer-Heyrovsky dynamics and boosting the HER activity.     

Proximity-Induced Fully Ferromagnetic Order with Eightfold Magnetic Anisotropy in Heavy Transition Metal Oxide CaRuO3

Ferromagnetic materials with a strong spin-orbit coupling (SOC) have attracted much attention in recent years because of their exotic properties and potential applications in energy-efficient spintronics. However, such materials are scarce in nature. Here, a proximity-induced paramagnetic to ferromagnetic transition for the heavy transition metal oxide CaRuO₃ in (001)-(LaMnO₃/CaRuO₃) superlattices is reported. Anomalous Hall effect is observed in the temperature range up to 180 K. Maximal anomalous Hall conductivity and anomalous Hall angle are as large as ∼15 Ω⁻¹ cm⁻¹ and ∼0.93%, respectively, by one to two orders of magnitude larger than those of the typical 3d ferromagnetic oxides such as La_0.67Sr_0.33MnO₃. Density functional theory calculations indicate the existence of avoid band crossings in the electronic band structure of the ferromagnetic CRO layer, which enhances Berry curvature thus strong anomalous Hall effects. Further evidences from polarized neutron reflectometry show that the CaRuO₃ layers are in a fully ferromagnetic state (∼0.8 μ_B/Ru), in sharp contrast to the proximity-induced canted antiferromagnetic state in 5d oxides SrIrO₃ and CaIrO₃ (∼0.1 μ_B/Ir). More than that, the magnetic anisotropy of the (001)-(LaMnO₃/CaRuO₃) superlattices is eightfold symmetric, showing potential applications in the technology of multistate data storage.     

基于高维纠缠态的量子密钥分发协议

为了提高量子密钥分发的效率和安全性,利用高维Hilbert空间中的Bell态和Hadamard门设计了一种量子密钥分发协议。首先通过量子态的动态演变验证了三维Bell纠缠态在Z基和X基下具有不同的表示特性,然后以此为基础进行协议设计,其中利用Z基测量来检测窃听,利用X基测量来产生密钥。安全性分析表明,该协议可以抵抗截获重发、纠缠附加粒子和特洛伊木马三种常见的攻击。最后将协议与其他方案进行了比较,该协议在保证量子比特效率50%的基础上,安全性也有所提升。     

基于无人机影像的电网绝缘子自爆识别

电网因其在电能传输方面的关键性作用,在我国民生项目建设领域一直扮演着至关重要的角色。电网杆塔上的绝缘子一旦发生自爆(也称“缺陷”),绝缘子会自动剥落,输电线路就会产生安全隐患,严重时会降低输电线路的运行寿命,甚至会引发供电中断,发生大范围的停电事故,造成巨大的财产损失。目前,主流的巡检方法为人工巡检,该方法不仅耗时耗力,而且也存在一定主观出错率,已不适用于目前电路巡检的实际情况。本设计采用YOLO V5网络模型,对无人机航拍影像中绝缘子串及绝缘子自爆进行自动识别。首先通过平移、翻转、裁剪等,对航拍绝缘子影像数据集进行数据增广,并对增广后的数据集在LabelImg中进行标注,然后利用YOLO V5网络模型对绝缘子串及绝缘子自爆进行识别,最后采用PyQt5框架在PyCharm中设计了绝缘子自爆识别的系统界面,对模型进行调用,实现了绝缘子串及绝缘子自爆识别。本设计采用从网络上下载、国家电网提供、数据增广所得到的500张无人机航拍影像作为数据集,对所得数据集进行人工标注,再使用YOLO V5网络模型进行训练和测试,结果表明YOLO V5网络模型对绝缘子串具有较高的识别精度,最高识别精度为90.2%,对绝缘子自爆的最高检测精度为80.8%。这说明了YOLO V5网络模型在绝缘子串识别方面有较好的表现,但是由于训练集中绝缘子自爆的样本影像数量有限,所以该网络模型对绝缘子的自爆识别存在一定局限性,本实验能够部分代替人力实现电网绝缘子智能巡检,提高了检测效率。