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51.
52.
By analyzing the extended X-ray absorption fine structure (EXAFS) of the Mo K-absorption edge, structural information for both oxidic and sulfided K-MoO3/-Al2O3 catalysts with different potassium content was obtained. The oxidic samples show two backscatterer peaks in the radial distribution function (RDF), which correspond to the Mo-O coordinations in the nearest Mo-O shell. The nearest oxygen atoms are present with large configurational disorder. The RDF for the K/Mo = 0 sample is significantly different from that for crystalline MoO3 and ammonium heptamolybdate. The RDFs for potassium promoted samples are, in some extent, similar to that for ammonium heptamolybdate. The sample with K/Mo = 0.8 and that with K/Mo=1.5 do not show obvious difference in their local Mo-O structures. The EXAFS results support the earlier conclusions from Raman spectroscopy studies on identical samples [7]. When the samples are sulfided, a rearrangement of the local neighbors around Mo atoms takes place, to form small MoS2-like crystallites. The Mo-S and Mo-Mo coordination distances on these catalysts are the same as those in crystalline MoS2, but the coordination numbers are significantly lower than in MoS2. The EXAFS results indicate that Mo species on the K/Mo=0 catalyst mainly consist of Mo-S-Mo units (the basic building units of MoS2), which are highly dispersed and show a higher level of disorder than in MoS2. With the modification by the potassium promoter, Mo species are significantly aggregated and their local neighbors are more similar to those in MoS2, but the Mo species still exist in a state of high dispersion. 相似文献
53.
Imran M. Mirza 《Journal of Modern Optics》2013,60(13):1048-1060
We study how to control the dynamics of tripartite entanglement among optical cavities using non-Markovian baths. In particular, we demonstrate how the reservoir engineering through the utilization of non-Markovian baths with different types of Lorentzian and ohmic spectral densities can lead to an entanglement survival for longer times and in some cases considerable regain of seemingly lost entanglement. Both of these behaviours indicate a better sustainability of entanglement (in time) compared to the usual Markovian bath situations which assumes a flat spectrum of the bath around the system resonant frequency. Our scheme shows these effects in the context of optical cavities starting off in a maximally entangled W and Greenberger–Horne–Zeilinger tripartite states. In Lorentzian cases, we find that the far detuned double Lorentzian baths with small coupling strengths and for ohmic-type baths super-ohmic environments with smaller cutoff frequencies are the best candidates for preserving entanglement among cavities for significant amount of time. A non-Markovian quantum jump approach is employed to understand the entanglement dynamics in these cases, especially to recognize the collapse and revival of the entanglement in both W and GHZ states. 相似文献
54.
Adiabatic transfer between two degenerate cavity modes is investigated theoretically using a counter-intuitive pulse sequence. Several measures of successful state transfer are shown to correlate strongly with anomalous values of the photon statistics of the initial mode. The detailed behaviour of theses anomalies originate from the way the state approaches vacuum and their features are found to give a good indication of the effciency and robustness of the state transfer. 相似文献
55.
R.Z. Valiev 《Advanced Engineering Materials》2003,5(5):296-300
Severe plastic deformation (SPD) can lead to emergence of microstructural features and properties in materials which are fundamentally different from the ones well known for conventional cold deformation. In particular, the instances of unusual phase transformations resulting in development of highly metastable states associated with formation of supersaturated solid solutions, disordering or amorphization and their further decomposition during heating, high thermal stability of the SPD‐produced nanostructures, and the paradox of strength and ductility in some SPD‐processed metals and alloys are discussed. 相似文献
56.
This study examined the modulatory function of Duchenne and non-Duchenne smiles on subjective and autonomic components of emotion. Participants were asked to hold a pencil in their mouth to either facilitate or inhibit smiles and were not instructed to contract specific muscles. Five conditions--namely lips pressing, low-level non-Duchenne smiling, high-level non-Duchenne smiling, Ducherme smiling, and control--were produced while participants watched videoclips that were evocative of positive or negative affect. Participants who displayed Duchenne smiles reported more positive experience when pleasant scenes and humorous cartoons were presented. Furthermore, they tended to exhibit different patterns of autonomic arousal when viewing positive scenes. These results support the facial feedback hypothesis and suggest that facial feedback has more powerful effects when facial configurations represent valid analogs of basic emotional expressions. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
57.
大孔距小排距的孔网参数在中深孔爆破中的应用 总被引:8,自引:0,他引:8
天铁集团的石矿厂多年来爆破效果不理想,粉矿率高,通过对爆破孔网参数的优化,采用大孔距、小排距的孔网参数在中深孔爆破中取得了较好的效果。 相似文献
58.
Emotional states might selectively modulate components of cognitive control. To test this hypothesis, the author randomly assigned 152 undergraduates (equal numbers of men and women) to watch short videos intended to induce emotional states (approach, neutral, or withdrawal). Each video was followed by a computerized 2-back working memory task (spatial or verbal, equated for difficulty and appearance). Spatial 2-back performance was enhanced by a withdrawal state and impaired by an approach state; the opposite pattern held for verbal performance. The double dissociation held more strongly for participants who made more errors than average across conditions. The results suggest that approach–withdrawal states can have selective influences on components of cognitive control, possibly on a hemispheric basis. They support and extend several frameworks for conceptualizing emotion–cognition interactions. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
59.
采用车辆轨道路基垂向耦合动力学模型,研究了轨道高低不平顺下有砟轨道路基动力影响系数φ_i的概率分布特性;根据循环荷载下路基粗粒土典型填料单元模型试验反映出的累积变形状态特征与荷载水平的关系,明确了基床以下填料处于无时间效应变形状态、基床填料处于微弱时间效应变形状态的设计工作状态;以基床结构的动强度、长期动力稳定性、循环变形为设计控制指标,开展了高速铁路有砟轨道基床结构的技术条件分析。研究表明:表征路基承受列车动力效应程度的φ_i沿线路纵向服从对数正态分布;列车荷载作用下,路基各结构层的累积变形状态与填料性质密切相关;基床结构的长期动力稳定性为设计主控因素,据此,提出了适用于350km/h有砟轨道高铁基床双层结构型式的技术标准建议。 相似文献
60.
多分支隧道的排烟与补风路径较多,热压与风机动力的竞争可能造成其通风排烟模式具有多解性。针对某一多分支隧道的防排烟工况,利用理论分析建立了各种气流模式的控制方程,通过数学方法获得了理论解。结果证明,在按照预期设计选定通风排烟模式与风机以后,多分支隧道内的排烟气流仍然可能存在多种状态,风机的运行工况点也会随之漂移,导致排烟方向可能与设计预期完全相反。研究还发现,通过改变风机选型能起到抑制排烟气流出现多解的作用。 相似文献