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Weak bonding strength between interlayers can seriously affect the quality of ceramic parts manufactured by stereolithography. Therefore, the possibility of using chemical bonds to strengthen the adhesion within these parts and the extent to which may be effective are of interest. Thus, a multi-exposure model was built to illustrate the state of this interface. The secondary conversion of a cured layer defined as conversion rate increment caused by decayed ultraviolet (UV) light in a subsequent exposure was selected to represent the extent of a chemical bond. The level of UV light attenuation occurred when travelling through a suspension layer was determined using the Attenuation Law. When decayed light illuminated a cured layer, it underwent further photopolymerization, which was detected by temperature change. The secondary conversion was affected by parameters including the incident energy dose and the propagating length. Optimization of these parameters helped to achieve higher chemical bond ratio. 相似文献
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基于光敏树脂体系制备煤系高岭土光固化浆料,采用流变仪对浆料的流变性能进行表征,研究分散剂和增塑剂加入量对浆料流变性能的影响。结果表明:油酸作为分散剂具有降低浆料黏度的效果,当油酸加入量为高岭土粉体的1%(质量分数)时浆料的黏度最小,在该条件下40%(体积分数)高岭土浆料的黏度为49.56 Pa·s。加入增塑剂PEG-300能够进一步降低浆料的黏度,浆料黏度随着增塑剂加入量的增加而减小,当增塑剂加入量为光敏树脂的20%(质量分数)时40%(体积分数)高岭土浆料的黏度下降为19.77 Pa·s,已经能较好地满足浆料涂布的要求。采用流变性能优化的浆料进行光固化成形,经过排胶、烧结后得到复杂形状的高岭土陶瓷件。 相似文献
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Stereolithography (SLA) is an additive manufacturing method with one of the highest accuracies (down to 100 nm) of all solid freeform techniques and has been used in various areas, such as medicine, automotive, aerospace, electronics, and others. However, most resins available nowadays are derived from petroleum. Its toxicity, low biocompatibility, and growing environmental concerns are limiting its application. This review discusses the development of biobased and biocompatible materials for different SLA processes as well as the usage of nanocomposites to increase their applicability. A comprehensive overview of the SLA technologies, photopolymerization chemistry, and resin properties are also provided. Finally, various examples using different types of materials are explored, to show the current and future capabilities of the SLA technique. 相似文献
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GAN Zhiwei MO Jianhua HUANG Shuhuai Hongquan 《武汉理工大学学报(材料科学英文版)》2006,21(1):99-101
1 IntroductionRapid Prototyping (RP) was developed as a newmanufacture technique and considered a significant break-through in the field of manufacturing in the past 20years[1-4].The principle of RPis based on layer additivefabrication. Firstly, a three-dimensional object modelfromcomputer-aided design (CAD) is divided into manythinlayers by delaminatingsoftware .Thetwo-dimensionaldata of eachthinlayer control alaser beam,whichirradi-ates many materials like resin point-by-point ,and solid… 相似文献
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Stabilization of tricalcium phosphate slurries against sedimentation for stereolithographic additive manufacturing and influence on the final mechanical properties
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Markus Pfaffinger Malte Hartmann Martin Schwentenwein Jürgen Stampfl 《International Journal of Applied Ceramic Technology》2017,14(4):499-506
Ceramic parts manufactured by lithography‐based ceramic manufacturing (LCM) excel in resolution and surface quality. The material for LCM is a photosensitive ceramic particle‐filled slurry which needs to have homogeneous properties over time and during each processing step. The goal of this study was to use “mechanical” stabilization for a tricalcium phosphate‐filled slurry done by increasing slurry viscosity, solids loading, or inducing thixotropic behavior. The modified slurries were compared with a nonstable reference slurry. While all methods lead to increased storage stability, only the stabilized slurry with 0.5 wt% fumed silica is stable during the printing process. 相似文献
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