精馏塔静态仿真：Ⅰ.静动态混合数学模型的应用

本文为了克服精馏塔静态仿真不易收敛和初值难以给定等难题，巧妙地利用隐含数值积分方法的特点，将稳态与动态数学模型耦合起来，用以求解高难度的非理想精馏塔静态仿真问题。所得静动态混俣模型大大提高了精馏塔静态仿真的鲁棒性，对于高度非理想精馏塔的仿真尤为有效。通过对某丙烯腈萃取精馏塔的静态仿真，充分证明了这种混合模型化方法的可行性。     

Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor

Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors decrease gradually with increasing Mg2 ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5 ℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8 ℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S:Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photoluminescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2 ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-xMgxO2S:0.06Ti phosphor.     

Direct atomic scale analysis of the distribution of Cu valence states in Cu/γ-Al2O3 catalysts

In this paper, the microstructure of a 1 wt.% Cu/γ-Al₂O₃ catalyst that was reduced in a 4% hydrogen/argon atmosphere at temperatures of 523, 773 and 1073 K, is studied by Z-contrast imaging and electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM). Results show that the copper species are well dispersed when the catalyst is reduced below 523 K. At 773 K, separated Cu(I) and Cu(0) species are found existing as ring-like and bulk-like particles. This appears to indicate that the copper has not been reduced to its metallic form due to the interaction between the copper oxide and the support. Large spherical particles having core-shell structures with Cu(I) in the shells and Cu(0) in the cores are generated when the catalyst is reduced at 1073 K. The formation of partially oxidized copper species upon reduction at 1073 K is attributed to the metallic copper interaction with the alumina support. This study also demonstrates that high-spatial resolution Z-contrast imaging and EELS performed simultaneously can provide unique information on the morphology and chemistry of metal species in supported metal catalysts.     

Kinetic investigation of the carbothermal reduction of an Iranian clay

The kinetics of the carbothermal reduction of clay under argon atmosphere has been investigated by the X-ray diffraction method. The clay-carbon (excess) mixture was formed into 2 cm diameter disks of different thicknesses. Experimental data evidences the significant effect of sample thickness on the reaction rate at 1400 °C. Decreasing thickness promotes mullite dissociation and formation of SiC and alumina powders. Mathematical modeling of the reaction system showed the gas diffusion in the Knudsen regime through the pellet to be the rate controlling step. Diffusivity of CO and reacted core tortuosity factor have been calculated.     

Does the Youth Corrections System Work? Tracking the Effectiveness of Intervention Efforts With Delinquent Boys in State Custody.

This study adopted a systemic approach to studying intervention efforts with delinquent youth, examining the association between several youth corrections programs and adult criminal outcomes. Two studies were designed to use juvenile and adult court records to evaluate the effectiveness of treatment programs provided to delinquent youth in state custody. The results of Study 1 suggested that court-recorded delinquent charges can be used to estimate delinquency severity. The results of Study 2 presented a discouraging but not entirely unexpected illustration of the effectiveness of intervention efforts among delinquent youth. It was found that time spent in juvenile detention facilities, work programs, and group homes was associated with negative adult criminal outcomes. No links between time spent in youth corrections programs and positive outcomes were identified. Implications for future program evaluation efforts are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

四倍频Nd：YAG激光在高压氢气中的喇曼频移研究

利用Nd:YAG固体激光器四倍频输出(266nm)在高压H₂中的受激喇曼散射获得多波长的激光输出。当泵浦能量一定时,通过改变H₂压力得到了最佳的能量输出,299nm波长的激光能量为3mJ,341nm波长的激光能量输出为6.1mJ,398nm波长的激光能量输出为2.8mJ,239nm波长的激光能量输出为0.8mJ,同时在477nm,595nm,218nm,200nm波段也有能量输出。     

用于泵浦固体激光器的激光二极管线阵的输出特性

从实验上测量了激光二极管线阵的输出特性,研究了温度、电流对输出功率、光谱特性,以及偏振特性的影响,为设计全固态激光器提供有益的参考。     

D1100-11型造气鼓风机技术改造

针对国内采用煤制气工艺的部分中氮肥生产厂发生的造气鼓风机出力不足的现象，根据不同的系统工作状况对原风机的叶轮进行重新设计施工，不改变机组其余部分，以起到增压扩容的效果，从而实现增产降耗的目的。     

Decomposition of Time Series Dynamic Linear Models

This paper derives the admissible decompositions for a time series dynamic linear model, assuming only that the model is observable. The decompositions depend on factorizations of the characteristic polynomial of the state evolution matrix G into relatively prime factors. This generalizes the method of West (1997 ) which considers one decomposition in the particular case where G is diagonalizable. Conditions are derived for a decomposition to be independent. These results show that no autoregressive process of order d has an independent decomposition for any integer d . Two illustrations of this procedure are discussed in detail.     

Time‐dependent heat transfer coefficient of a wall

A time‐dependent coefficient of heat transfer is proposed for the computation of thermal power required, so that a room temperature reaches a desired value within a given time. A mathematical formulation of the room heating transient phenomenon is constructed in a dimensionless form. Using an integral approximate solution an analytical expression for this coefficient is provided and it is verified by diagrams adopted by DIN 4701. Copyright © 2003 John Wiley & Sons, Ltd.