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1.
New mesogenic homologous series having an azo central linkage was synthesized by fixing a rigid 4-methyl phenyl azo group
to resorcinol moiety. The terminal and lateral phenolic -OH groups were esterified, one by one, with 4-n-alkoxybenzoyl and acetyl group, respectively. All the twelve homologues synthesized exhibit mesomorphism. The methoxy ton-decyloxy andn-hexadecyloxy derivatives exhibit monotropic nematic mesophase whereas,n-dodecyloxy andn-tetradecyloxy derivatives exhibit enantiotropic nematic mesophase. The mesogenic properties of the present series was compared
with those of other structurally related mesogenic series.
Paper presented at the 5th National Seminar on Liquid Crystals, University of Jammu, Jammu, December 1997. 相似文献
2.
The homopolyester of 4-(4′-hydroxyphenoxy)benzoic acid (poly(4-HPBA)), was prepared under two different reaction conditions and compared with a sample provided by another research group. Depending on the synthetic route, different melting points, d.s.c. traces and crystal lattices were found. However, after repeated heating and cooling, one thermodynamically stable modification with a melting point of 370–375°C can be obtained. Copolyesters of 4-hydroxybenzoic acid and 4-(4′-hydroxyphenoxy)benzoic acid were prepared with various molar ratios either in the melt (condensation in bulk) or in solution. These copolyesters were characterized by elemental analyses, 1H n.m.r. spectroscopy, d.s.c. measurements, wide-angle X-ray scattering measurements at various temperatures, and optical microscopy. Whereas copolyesters prepared in solution do not melt below 500°C, those prepared by polycondensation in bulk show melting points down to approximately 260°C and form a nematic melt. 相似文献
3.
M.H. Song B. Park S. Nishimura T. Toyooka I.J. Chung Y. Takanishi K. Ishikawa H. Takezoe 《Advanced functional materials》2006,16(14):1793-1798
A liquid crystal (LC) photonic device with an anisotropic optical heterojunction structure has been fabricated. The device has a phase‐retarding nematic LC (NLC) layer sandwiched between two polymer cholesteric LC films with right‐handed helices of different pitches. Electrotunable non‐reciprocal light transmittance and unidirectional circularly polarized (CP) lasing emission have been successfully demonstrated for this device structure. Two left CP (LCP) lasing emission peaks are observed at the edges of the overlapping region between the two photonic bands in the structure and are shifted upon the application of a voltage. In contrast, a non‐reciprocal right CP (RCP) lasing emission peak emerges at one of the band edges and diminishes upon the application of a voltage. These phenomena are interpreted based on the selective reflection of RCP light and the reorientation of the NLC molecules by the application of a voltage. 相似文献
4.
Drawing of square twisted wire 总被引:5,自引:0,他引:5
F. Knap 《Journal of Materials Processing Technology》1996,60(1-4):167-170
The shape of the deformation zone during drawing of square twisted wires is described in this paper. The condition of the stable deformation of the wire is formulated. This condition is satisfied by the constant value of the pitch of the helical surface of the die. The work focuses on the investigation of the influence of the die cone angle on the drawing parameters, in particular on the drawing stress. 相似文献
5.
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7.
轨道角动量(orbital angular momentum, OAM)的引入丰富了光通信领域内的调制维度,为寻找更高效快捷的通信方式提供了新思路,相较于传统携带涡旋相位的涡旋光束,部分相干扭曲光束携带的OAM性质更为复杂。本文针对椭圆多高斯关联扭曲光束在梯度折射率(gradient-index, GRIN)光纤中的OAM传输,基于GRIN光纤的ABCD光学传输矩阵,着重分析了多高斯关联扭曲光束在GRIN光纤传输的OAM的传输演化特性。研究结果表明,光束的光强、OAM通量密度以及归一化OAM通量密度在光纤传输过程中均呈现周期性变化,通过对关联结构以及扭曲因子的调控不仅可以改变光束OAM通量密度的分布,还可以调控单光子携带OAM的大小。本文的研究有助于丰富扭曲部分相干光束在GRIN光纤中传输的理论结果,在光纤通信中具有潜在的应用前景。 相似文献
8.
A composite liquid crystalline elastomer is designed, combining main-chain and side-chain mesogenic polymers in the network, and resulting in micro-phase separated regions of nematic and smectic ordering in the macroscopically homogeneous elastomer. A range of different fractions of the components is explored, from fully nematic main-chain system, across to fully smectic side-chain elastomer. Thermal phase transitions of both phases coexisting in the material are detected by calorimetry, and the nematic/smectic structure investigated by X-ray scattering. The tensile stress–strain data reveal the key effect of such a multi-phase composite, where the nematic fraction adds ductility while the smectic fraction increases the modulus and mechanical stiffness. Varying the composition, the authors are able to optimize the mechanical properties of this material type. 相似文献
9.
Experimental and numerical investigations on compressive properties of porous twisted wire materials
Wire diameter, sintering parameter, and porosity have great influences on porous structures and compressive properties of the stainless steel porous twisted wire materials with 30–92% porosities. Finer wires, higher sintering temperature, and longer sintering time will lead to narrower pore-size distributions, more compact porous structures, and stronger compressive yield strength. A random pore model and a twisted wire framework model are put forward to simulate the compressive process. The compressive deformation mechanism is a continuous densification process. The simulated and experimental stress-strain curves all exhibit elastic stage, plastic yield platform stage, and final densification stage. 相似文献
10.
A Significantly Twisted Spirocyclic Phosphine Oxide as a Universal Host for High‐Efficiency Full‐Color Thermally Activated Delayed Fluorescence Diodes 下载免费PDF全文