六种药剂防治向日葵白锈病试验研究

六种药剂防治向日葵白锈病田间药效试验结果表明,25%甲霜灵WP1000倍、50%安克WG2500倍的防效分别为87.6%和86.8%,显著优于64%杀毒矾WP800倍(防效75.7%),而52.5%抑快净WG1000倍、72%霜疫必克WP600倍和80%乙磷铝WP600倍的防效相当,不理想,均未达到50%。经方差分析证明处理间差异达到显著水平。     

利用钛白废酸制高纯度磷酸一铵试验简介

试验表明,用钛白粉生产中副产的w(H2SO4)≈20%的钛白废酸,经浓缩、净化及再稀释后与磷矿粉反应,在加入净化添加剂的条件下制得纯净的湿法磷酸与氨或碳酸氢铵反应,可代替热法磷酸为原料生产相同质量的高纯度磷酸一铵。分析了该工艺的技术可行性和经济可行性,认为所得的纯净磷酸也可加工成其他高纯度磷化工产品。     

新型细胞固定化载体强化白腐菌降解活性染料

为提高白腐真菌的产酶能力和后续对染料的降解效果,采用摇瓶试验研究新型细胞固定化载体——聚氨酯泡沫固定化白腐真菌后的锰过氧化物酶(MnP)产生情况以及后续对活性染料——活性艳红K-2BP的降解效果.结果显示,新型载体固定化培养白腐真菌的5d脱色率为95%,比悬浮培养7d的脱色率高15%.固定化培养产生的MnP酶活为936.61U/L,而悬浮培养的MnP仅为269.52U/L,并且酶活高峰期提前4d.另外,固定化培养体系中碳、氮源的消耗比悬浮培养快很多,而且固定化培养使得白腐真菌具有较高的H2O2产量.因此,新型细胞固定化载体强化白腐真菌降解活性染料的原因应归于这种培养体系碳、氮源的快速消耗而带来的MnP酶活的提高和高H2O2产量.     

超高压改性对鸡蛋蛋白液起泡及物理性质的影响

采用超高压改性鸡蛋蛋白液,研究了压力、保压时间对蛋白液起泡性质和物理性质的影响结果表明,新鲜蛋白液在350MPa的静水压下处理15min后的起泡性质最好．此外,超高压改性还导致蛋白液的黏度和表面张力呈现升高后又急剧降低的趋势,并能够降低蛋白液的明度.     

一种白光测速仪在热锯区域中的应用

阐述白光测速仪的工作原理及优缺点,介绍其在莱钢大H型钢生产线热锯区域的应用.     

不同初始损伤白砂岩高温处理后的力学性能研究

通过进行不同初始损伤程度白砂岩在不同等级高温处理后的力学试验,分析了温度和初始损伤对白砂岩的杨氏模量、峰值应力和显微结构等方面的影响。试验结果表明:随着温度的升高,受到初始损伤的白砂岩试件的杨氏模量和抗压强度都呈下降的趋势,初始损伤越大,高温对白砂岩造成的影响越大。通过显微镜观察到随着温度的升高,试块的晶体变小,颗粒的破坏更为破碎,岩屑更多。此外,通过对试验数据的整理,建立了不同初始损伤等级和不同温度等级下白砂岩的本构关系曲线。     

Full color white light,temperature self-monitor,and thermochromatic effect of Cu+ and Tm3+ codoped germanate glasses

Lighting sources with full-color visible output are widely preferred in practical applications. In addition, modern lighting sources also tend to be intelligentized, and the intelligentization asks for smart luminescence materials. In this work, we attempt to develop novel full-color emitting material with temperature sensing and thermochromatic ability. To this end, the Cu²⁺ is successfully reduced to Cu⁺ which is incorporated into the germanate glasses. The glasses are prepared via a melt-quenching technique using graphite powders as reducing reagent. The supper-broadening of the excitation and the emission spectra of Cu⁺ in the germanate glasses are observed. Full-color emission is realized by introducing Tm³⁺ as co-dopant to provide the blue component in the spectra. The energy transfer behavior between Cu⁺ and Tm³⁺ is investigated, and it is found that these two luminescence centers are independently existent without energy transfer between them. The chromatic properties of the Cu⁺/Tm³⁺ co-doped glasses are tuned by Tm³⁺ concentration and excitation wavelength. The temperature sensing based on the fluorescence intensity ratio technique is demonstrated, and a constant sensitivity for the temperature detection is obtained. Moreover the thermochromatic property is also investigated, and it is found that the studied Cu⁺/Tm³⁺-doped glasses exhibit excellent thermochromatic performance.     

Broadband excited Na3Tb(PO4)2:Ce3+/Eu2+ green/yellow-emitting phosphors with high color purity for LED-based application

To enhance the display quality of light-emitting diodes (LEDs), it is of great significance to exploit green/yellow-emitting phosphors with narrow emission band, high quantum yield, and excellent color purity to satisfy the application. Herein, orthophosphate-based green/yellow-emitting Na₃Tb(PO₄)₂:Ce³⁺/Eu²⁺ (NTPO:Ce³⁺/Eu²⁺) phosphors have been successfully synthesized by a facile solid-state reaction method. The absorption band of NTPO samples was extended to the near-ultraviolet region and the absorption efficiency was significantly improved owing to a highly efficient energy transfer from Ce³⁺/Eu²⁺ ion to Tb³⁺ ion in NTPO host certified by time-resolved PL spectra. Upon 300 nm excitation, the NTPO:Ce³⁺ is characterized by ultra-narrow-band green emission of Tb³⁺ with an absolute quantum yield of 94.5%. Unexpectedly, NTPO:Eu²⁺ emits bright yellow light with a color purity of 73% as a result of the blending of green light emission from Tb³⁺ and red light emission from Eu³⁺. The thermal stability has been improved by controlling the stoichiometric ratio of Na⁺. The prototype white LED used yellow-emitting NTPO:Eu²⁺ phosphor has higher color-rendering index (Ra = 83.5), lower correlated color temperature (CCT = 5206 K), and closer CIE color coordinates (0.338, 0.3187) to the standard white point at (0.333, 0.333) than that used green-emitting NTPO:Ce³⁺ phosphor, indicating the addition of the yellow light component improved the Ra of the trichromatic (RGB) materials.     

60Mn环件断裂分析

60Mn环件在装配150h后发生崩裂.利用断口分析、化学成分分析、显微组织检验以及有限元计算对断裂件进行了分析.结果表明,环件中存在白点,白点在装配应力和内部氢压的作用下发生滞后扩展,当白点裂纹扩展到临界尺寸时,裂纹尖端的应力强度因子超过零件材料的断裂韧度,从而发生崩裂.     

高耐蚀性热镀锌板的钝化处理工艺探讨

介绍了热镀锌板钝化膜的形成机理 ;针对攀钢热镀锌板出现白锈、黑斑等问题 ,分析了钝化液pH值、添加剂及操作条件对钝化膜质量的影响 ,同时提出了改进热镀锌板耐蚀性能的措施