SOLUTION BEHAVIOUR OF VARIOUS ALLOYING ELEMENTS IN Ni_3Si

The solid solubilities of 15 common alloying elements added to the Ll_2-type intermetalliccompound Ni_3Si at 900°C have been estimated,and their substitution modes have been de-duced from the direction of solubility lobe of the compound.It is shown that the alloyingbehaviours in Ni_3Si are determined by both size and electronic factors,i.e.,the substitutionmode is governed by electronic configuration and solubility by the both.An interactionparameter is presented to describe quantitatively the influence of electronic configuration onsubstitution mode and the solubility limit can be successfully explained together with atom radius.     

球墨铸铁凝固过程微观组织模拟

根据热力学和凝固原理等，建立了凝固过程中热传递、溶质传递和石墨球、奥氏体形核、生长的数学物理模型，以能量最小原理为基础，考虑体积自由能和界面能的定量影响，对奥氏体晶粒的形核和生长进行了摸拟。根据所建立的模型。采用了Microsoft Visualc 6．0开发平台开发了相应的三维模似计算程序和二维动态显示程序。     

A STUDY OF RATE-DEPENDENCE AT ELEVATED TEMPERATURE FOR AN Al-Cu-Mg ALLOY

The hot deformation of an Al-Cu-Mg alloy was studied in the two temperature ranges (room temperature-300℃ and 400℃-480℃). The rate-independent flow curves are typical of elasto-plastic response with significant work hardening followed by strain softening below 300℃. Similar dislocation structures with high density tangled into grain interiors were observed by TEM, which suggests that the process of obstacles arresting mobile dislocations results in this macroscopically rate-independence. At 400-480℃, all rate dependent flow behaviors characterized by a continuous softening after an initial work hardening at a small plastic strain show large tensile elongations. Long dislocation segments around the second phases infer their good mobility to climb across obstacles. Grain boundary morphology observed by TEM suggests that the capacity of the grain boundaries to absorb the dislocations sensitively accounts for the rate-dependent mechanical properties.     

Monte-carlo modeling of grain growth in Zr equal channel angular pressed and recrystallized

Grain boundary character distribution in equal-channel-angular pressed Zr was studied. Using a die design of 90°/20° and an operation temperature of 350°C. The initial grain size of 20 μm was reduced to about 270 nm with 4 passes via route B_c. The grain growth kinetics of the recrystallized state was obtained by experiment and Monte-Carlo computer simulation, respectively, which showed good agreement. Based on kinetics and morphological characteristics, it was concluded that the grain coarsening mechanism was governed by normal grain growth. No sign of abnormal grain growth was detected either in the experiment or in simulation despite taking into consideration anisotropy in grain boundary energy as well as its mobility. This indicates that grain boundaries produced by severely deformed Zr are stable against explosive coarsening. The evolution characteristics of the microstructure in the present ECA pressed and recrystallized Zr differed from those of cold rolled Ti in that the grain boundary misorientation distribution and texture were rather stable during grain growth. Jointly Appointed by the Center for Advanced Aerospace Materials This article is based on a presentation made in the 2002 Korea-US symposium on the “Phase Transformations of Nano-Materials,” organized as a special program of the 2002 Annual Meeting of the Korean Institute of Metals and Materials, held at Yonsei University, Seoul, Korea on October 25–26, 2002.     

Nanocrystalline Nd2Fe14B／α—Fe permanent magnet

Nd8.5Fe75Co5Cu1Zr3Nb1B6.5bonded magnet was prepared by melt-spinning(vs=18m/s)and subsequent heat treatment(670℃，4min).Excellent magnetic properties of the bonded magnet were achieved:Br=0.68T,iHc=620.3kA/m,(BH)max=74kJ/m^3.The addition of Cu and Zr elements shows to be advantageous in improving an intrinsic coercivity and squareness of hysteresis loop,as well as energy product.In has a remarkable remanence enhancement and the isotropic saturation remanence ratio Mr/Ms is 0.83.     

MECHANISM OF NON-EQUILIBRIUM SEGREGATION OF SOLUTE TO GRAIN BOUNDARIES

本文以空位-溶质原子拖曳机制为基础,并考虑了空位、溶质原子和复合体三者的反应平衡及晶界平衡偏聚的作用,得到了溶质原子的非平衡晶界偏聚动力学方程。对硼在奥氏体中等温及连续冷却时所产生的非平衡晶界偏聚现象进行了理论计算,得到了与实验较为一致的结果。     

搅拌摩擦加工(FSP)AZ91D镁合金的组织分析

研究了AZ91D镁合金经搅拌摩擦加工后的组织。发现组织中搅拌摩擦区、热机械影响区和热影响区分区不明显。在搅拌摩擦区主要为再结晶形成的细小均匀的等轴晶结构,共晶组织α-Mg β相(Mg17Al12)完全均匀化,仅在晶界处有少量存在。     

用原料添加法提高钼粉粒度的探讨

叙述了在钼粉的工业化生产条件下采用原料添加法来提高最终粉末粒度，改善原料工艺性能的试验。研究表明：在钼酸铵原料中添加一定组份的钥粉，能有效地改善钼酸铵在动态焙解还原时的分散性和流动性，选择不同的添加量和添加粉粒度，可有效地把钼粉的ＦＳＳＳ粒度从２．５μｍ提高到４．２μｍ，从而可根据用粉要求，选择合适的添加工艺，来制取理想的钼粉。     

Ti40阻燃钛合金的高温蠕变行为

计算了Ti40合金在不同应力、不同温度下的稳态蠕变速率、应力指数及在460℃－540℃范围内蠕变激活能Q＝94.0kJ/mol，并以此基础上研究了其蠕变强化机制。实验结果表明：该合金在此温度范围内的蠕变受位错和扩散双重机制控制，晶界移动对蠕变也有一定的贡献。在目前实验条件下，Ti40合金在620℃蠕变性能较差。     

含Li的Al-Zn-Mg-Cu合金沉淀析出过程的定量分析

应用小角度X射线散射技术结合TEM分析定量的描述Al-Zn-Mg-Cu-Li合金时效过程中析出相尺寸分布和形貌等信息。通过分析确定合金在几种时效状态下析出相为轴比在0．2～0．4之间的扁回转椭球形。确定了析出相特征尺寸的对数正态分布和质量依回转半径的Maxwell分布。并分析分布曲线随动力强度Ks的变化特征，可以看出，析出相尺寸和质量分布曲线基本满足随动力强度增加，几何平均值增加，分布范围变宽。