C/C复合材料Mo - Si-N系抗氧化涂层成分优化

以Mo粉和Si粉为原始粉末,采用熔浆法在C/C复合材料表面原位合成了Si3N4-MoSi2/Si-SiC(MSN)系多层抗氧化涂层,借助扫描电镜和X射线衍射仪等分析手段对涂层的相组成和微观组织进行表征,并对涂层的抗氧化性能进行了初步研究.结果表明:Si浆料中添加适量Al可有效地阻止液态Si渗入C/C基材内部,3%Al-Si涂层具有最好的阻止Si渗入作用;Al含量超过3%时,Si的渗入程度随Al含量的增加而加剧;涂层中MoSi2的理论含量超过50%时,MSN-C/C复合材料1 400℃的抗氧化性能随MoSi2含量的增加而显著下降;MSN30-C/C和MSN40-C/C复合材料均在1 200～1 400℃表现出相近的抗氧化能力,但只有MSN30-C/C复合材料表现出抗1 450℃氧化的能力.     

Effects of La(NO_3)_3 Treatment on Photocattalytic Activity of TiO_2 Films Prepared by Micro-Arc Oxidation

Effects of La(NO_3)_3 Treatment on Photocattalytic Activity of TiO_2 Films Prepared by Micro-Arc Oxidation     

Effect of Ce^＋ Ion Implantation upon Oxidation Resistance of Superalloy K38G

The addition of small quantities of reactive ele ments (RE) or other elements with high oxygen affini ty, usually in the order of 0 1%~0 2% mass frac tion, will result in a beneficial effect on the oxidationresistance to superalloys[1~4].A number of mechanisms have been proposed toexplain the beneficial effect of RE additions on theCr2O3 forming alloys, including physical blocking byRE ions or second phase particles at grain boundaries,pegging effect between the oxide and the …     

Catalytic Activity of Ceria-Zirconia Nanostructured Materials Prepared via Reversed Microemulsion Method

CeO2-ZrO2mixed oxides have a number of i mpor-tant catalytic applications[1].They are extensively em-ployed in current automotive three-way catalysts(TWCs)as the oxygen storage promoters,i.e.materi-als that regulate the oxygen partial pressure throughtheC…     

Flow Resistance Law in Channels with Flexible Submerged Vegetation

In this paper, experimental data collected in a straight flume having a bed covered by grasslike vegetation have been used to analyze flow resistance for flexible submerged elements. At first, the measurements are used to test the applicability of Kouwen’s method. Then, a calibration of two coefficients appearing in the semilogarithmic flow resistance equation is carried out. Finally, applying the Π-theorem and the incomplete self-similarity condition, a flow resistance equation linking the friction factor with the shear Reynolds number, the depth-vegetation height ratio and the inflection degree is deduced.     

浅析影响SCR法铸坯质量的因素

分析了SCR连铸连轧工艺生产铜银合金导线时,铸坯凝固的热阻界、铸模的传热条件、铸坯组织的控制对产品质量的影响。     

Interface Characteristics and Laboratory Constructability Tests of Novel Fiber-Reinforced Polymer/Concrete Piles

Conventional pile materials such as steel, concrete, and timber are prone to deterioration for many reasons. Fiber-reinforced polymer (FRP) concrete composites represent an alternative construction material for deep foundations that can eliminate many of the performance disadvantages of traditional piling materials. However, FRP composites present several difficulties related to constructability, and the lack of design tools for their implementation as a foundation element. This paper describes the results of an experimental study on frictional FRP/dense sand interface characteristics and the constructability of FRP–concrete composite piles. An innovative toe driving technique is developed to install the empty FRP shells in the soil and self-consolidating concrete is subsequently cast in them. The experimental program involves interface shear tests on small FRP samples and uplift load tests on large-scale model piles. Two different FRP pile materials with different roughness and a reference steel pile are examined. Static uplift load tests are conducted on different piles installed in soil samples subjected to different confining pressures in the pressure chamber. The results showed that the interface friction for FRP materials compared favorably with conventional steel material. It was shown that toe driving is suitable for installation of FRP piles in dense soils.     

Analysis of nuclear proliferation resistance

All the civil nuclear energy systems could contribute to the proliferation risk that weapons-usable material might be diverted or misused for the weapons purpose by terrorists or states. Proliferation-resistant nuclear energy systems are of great importance for the peaceful use of nuclear energy by impeding the diversion or undeclared production of weapons-usable material by states. Since the National Alternative Systems Assessment Program (NASAP) carried out the assessment of proliferation resistance of the civil nuclear energy systems in late 1970s, several comprehensive studies have been performed, including the International Nuclear Fuel Cycle Evaluation (INFCE) by the International Atomic Energy Agency (IAEA), the Spent Fuel Standard by the United States National Academy of Science, the Technical Opportunities for Increasing the Proliferation Resistance of Global Civilian Nuclear Power Systems (TOPS) by the United States Department of Energy, the International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO) Methodology by the IAEA, and the Generation IV Nuclear Energy Systems (Gen IV) by the Gen IV International Forum. However, all these studies appear lack in the interpretation of country-specific proliferation risk that is arbitrary imposed to the specific countries by major nuclear weapons states, even though the countries are members of the Treaty on the Non-Proliferation of Nuclear Weapons (NPT). This paper outlines the assessments of proliferation resistance of the above studies, points out the country-specific proliferation risk, and suggests further studies to increase the proliferation resistance of the civil nuclear energy systems in the specific NPT member countries such as South Korea.     

NiCr合金在含氯氧化性气氛中的高温腐蚀

研究了纯Ni以及不同Cr含量的NiCr合金在5%O2-0.3%HCl-N2(体积分数)气氛中800℃的腐蚀行为,结果表明:在氧化膜/基体金属界面处有氯化物生成,合金的加速腐蚀机制为氯参与的"活化腐蚀"过程.NiCr合金在腐蚀初期表现为失重与生成Cr的氯化物和氯氧化物的挥发性有关,但Cr依然有益于合金的抗氯化-氧化腐蚀性.     

HK40钢的渗铝新工艺及抗碳化腐蚀性能研究

采用金相显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射仪(XRD)、X射线能谱分析仪(EDAX)等仪器设备研究了HK40钢的渗铝及其抗碳化腐蚀能力.试验结果表明,通过调整渗剂中特种添加剂与铝粉的比例和渗铝温度等工艺参数,可达到控制渗铝层相组成的目的.与传统一段法固体粉末渗铝工艺相比,两段法固体粉末渗铝工艺可提高渗速约60%.HK40钢的渗铝层由NiAl相和Ni3Al相组成时,其抗碳化腐蚀能力得到明显提高.