Validation of a Method of Determination of Apparent Diffusivity Versus Composition in Solids

A method is presented for computing the values of apparent diffusivity in solids with respect to the concentration of the diffusing substance (water or sodium chloride). This method does not require any assumption upon the mathematical relationship between diffusivity and concentration. It can be applied to experimental measurements of local concentration versus position within the solid (profiles) with relatively few measurements (circa 10) and a mathematical smoothing of the experimental data by using an artificial neural network model. The method was first validated on simulated data obtained by using a constant diffusivity value and on experimental profiles when the relation between diffusivity and concentration was given. It was then applied to original experimental moisture profiles obtained by putting gelatin gels with different initial moisture contents into contact for up to 14 days. The method was also successfully applied to five sets of experimental moisture and sodium chloride profiles taken from the literature and obtained from different food products. Apparent diffusivities calculated by our method were found in agreement with those obtained by authors using different numerical methods to compute the diffusivity values.     

TCAD and SPICE modeling help solve ESD protection issues in analog CMOS technology

The number of circuit design iterations due to electrostatic discharge (ESD) failures increases with the complexity of VLSI technologies and their shrinking. In this paper, we show how TCAD and ESD SPICE modeling can be used to solve ESD protection issues in an analog CMOS technology.     

Structural and electronic properties of zirconia phases: A FP-LAPW investigations

The structural and electronic properties of ZrO₂ polymorphs were investigated using density functional theory (DFT). The Kohn–Sham equations were solved by applying the full-potential linearized augmented plane wave (FP-LAPW) method. We used the generalized gradient approximation (GGA) in the Perdew–Wang formalism to the exchange and correlation energy functional. The ground state properties such as lattice parameter, transition pressures, bulk modulus and its pressure derivative as well as the structural phase stability were calculated. The results were compared with previous calculations and experimental data when available. The FP-LAPW method correctly orders the zero temperature energies of all zirconia polymorphs. We have also studied the effect of distortion from the cubic to the tetragonal structure on the basis of charge density calculations. On the other hand, band structure and density of states (DOS), which allow us to discuss the features of orbital mixing, are also given. Our results suggest that the cotunnite structure should be better than the other zirconia phases as gate dielectric material.     

A Brief Survey of our Contribution to Stable Carbene Chemistry

This personal account summarizes our work, beginning with the discovery of the first stable carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have moved our focus from acyclic to cyclic carbenes, and shows that these stable species are not limited to the role of ligand for transition metals, but that they are also powerful agents for the activation of small molecules, and for the stabilization of highly reactive diamagnetic and paramagnetic species.     

A comparison framework for breathing motion estimation methods from 4-D imaging

Motion estimation is an important issue in radiation therapy of moving organs. In particular, motion estimates from 4-D imaging can be used to compute the distribution of an absorbed dose during the therapeutic irradiation. We propose a strategy and criteria incorporating spatiotemporal information to evaluate the accuracy of model-based methods capturing breathing motion from 4-D CT images. This evaluation relies on the identification and tracking of landmarks on the 4-D CT images by medical experts. Three different experts selected more than 500 landmarks within 4-D CT images of lungs for three patients. Landmark tracking was performed at four instants of the expiration phase. Two metrics are proposed to evaluate the tracking performance of motion-estimation models. The first metric cumulates over the four instants the errors on landmark location. The second metric integrates the error over a time interval according to an a priori breathing model for the landmark spatiotemporal trajectory. This latter metric better takes into account the dynamics of the motion. A second aim of this paper is to estimate the impact of considering several phases of the respiratory cycle as compared to using only the extreme phases (end-inspiration and end-expiration). The accuracy of three motion estimation models (two image registration-based methods and a biomechanical method) is compared through the proposed metrics and statistical tools. This paper points out the interest of taking into account more frames for reliably tracking the respiratory motion.     

Interaction of tallow and hay particle size on ruminal parameters.

Four nonlactating ruminally cannulated Holstein cows were used in a 4 x 4 Latin square experiment with 4 21-d periods to determine if the effects of dietary fat would be affected by hay particle length. Treatments consisted of two levels of tallow (0 and 5%) and two hay particle lengths (short-cut and long-cut) in a 2 x 2 factorial. Diets contained alfalfa hay, corn silage, and concentrate [1:1:2, dry matter (DM) basis] fed as a total mixed ration (TMR) once per day. Samples of the 0 and 5% tallow TMR were ground and incubated in situ in polyester bags for 24 and 48 h. Ruminal samples were taken on day 21 at 0800 h and at 2-h intervals until 1600 h. The total tract digestibilities of acid detergent fiber (ADF) and neutral detergent fiber (NDF) were not affected by tallow or by hay by tallow interactions. There was a trend for tallow to improve total tract digestibility of crude protein (CP) (70.2 vs. 74.7%). After 48 h of ruminal incubation, tallow significantly decreased the digestibilities of DM, ADF, and NDF. No hay length by tallow interactions for DM, NDF, ADF or CP digestibilities occurred after 24 or 48 h. Tallow increased concentrations of propionate and decreased concentrations of acetate and valerate and the acetate-to-propionate ratio. Total volatile fatty acids increased when tallow was added to diets with short-cut hay, which suggests that when unprotected fat is added to diets with a high level of hay, a short-cut hay length may be advantageous. This result may be due to shorter rumen retention time of feed particles, which reduces the time for fatty acids to exert antimicrobial effects. Or, it may because the increased surface area of the hay particle provides more area for microbial attachment and increased fermentation.     

A Context-Aware Network Equipment for Dynamic Adaptation of Multimedia Services in Wireless Networks

B3G (Beyond 3rd Generation) networks is the next step in the wireless world. It will enable the delivery of services to end-users, on different underlying wireless access networks and customised to users’ context. Furthermore, seamless mobility between networks and switch of devices will be handled in a transparent way. In this paper, a Context-Aware Network Equipment (CANE) is introduced, that is able to dynamically adapt multimedia services according to the users’ context. The term context includes the users’ device, the users’ preferences, the network conditions as well as the service provider adaptation policies. As a proof of concept, an implementation of a CANE is given for a 802.11 network use-case. An evaluation of the prototype as well as simulations of the proposed solution, both for an audio streaming service and a video streaming service, are presented. The results show that adapting multimedia services in case of network overload can enable to maintain an acceptable quality of service delivered to end-users and even to allow more users to enjoy the services, which will not be possible without the CANE.     

Detection of Defects Using Fault Model Oriented Test Sequences

This paper analyzes the possibilities and limitations of defect detection using fault model oriented test sequences. The analysis is conducted through the example of a short defect considering the static voltage test technique. Firstly, the problem of defect excitation and effect propagation is studied. It is shown that the effect can be either a defective effect or a defect-free effect depending on the value of unpredictable parameters. The concept of Analog Detectability Interval (ADI) is used to represent the range of the unpredictable parameters creating a defective effect. It is demonstrated that the ADIs are pattern dependent. New concepts (Global ADI, Covered ADI) are then proposed to optimize the defect detection taking into account the unpredictable parameters. Finally, the ability of a fault oriented test sequence to detect defect is discussed. In particular, it is shown that the test sequence generated to target the stuck-at faults can reasonably guarantee short defect detection till a limit given by the Analog Detectability Intervals.     

High-Power CW Klystron for Fusion Experiments

A 3.7-GHz 700-kW klystron in continuous-wave (CW) operation has been developed to upgrade the lower hybrid RF plasma heating power in a tokamak up to 10 MW. The klystron is equipped with a diode gun, a five-cavity RF structure, two BeO-disk RF windows, and a large-size X-ray-shielded hypervapotron collector. The output power is recombined in a four-port junction which we also developed. The tube is designed to deliver 620-kW CW RF power with a mismatched load (VSWR = 1.4) and 700-kW CW with a matched load. Several prototypes have been built with successive design improvements. The major improvement was to change one single RF output into two RF outputs. The most recently built prototype meets all design specifications at 73.1 kV and 20.7 A, with an efficiency of 47% on a matched load and 40% with a 1.4 : 1 VSWR load, worst case phase. The power losses dissipated in the body have been measured as low as 17 kW, which corresponds to the RF heating and implies low beam interception. The measured temperatures of the output cavity noses and collector wall have been kept below 130degC and 200degC, respectively, which results in large thermal margin.