HPMBP与伯胺N_(1923)对希土元素(Ⅲ)的协同萃取

本文研究了HPMBP与伯胺N_(1923)的二甲苯溶液,从盐酸介质中协同萃取希土(Ⅲ)的机理。用斜率法、恒摩尔法确定了协萃配合物的组成为:RNH_3Ln(PMBP)_4。求得关于Pr(Ⅲ)协萃反应的平衡常数及协萃配合物的生成常数分别为:logK_(12)=-1.95;logβ_(12)=3.94。实验发现,协萃系数(R)随希土元素的原子序数(Z)递变而呈现“双峰效应”。还研究了协萃配合物的IR,NMR谱。     

Morphology and properties of poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene]/silica nanoparticle hybrid films

Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry     

兰州重离子加速器大型真空室

已建成的兰州重离子加速器的真空室是一个大型整体结构的超高真空容器,直径约10m,高4.5m,重65000kg,内表面积211m~2,容积100m~3,工作真空度为5×10~(-5)Pa。采用有限单元法在计算机上用SAP-5C程序对真空室受力分析进行了计算。真空室结构材料选用瑞典Uddeholm钢厂生产的316 L 超低碳不锈钢。承制此大型容器的是航天工业部风华机器厂。由于结构庞大,首先将真空室分成八大块和几小块在工厂制造,然后运至现场焊制成一整体容器并进行机械加工。所有密封焊缝均用着色渗透液,X-射线探伤和氦质谱探漏仪进行检查和探漏。     

基于DELPHI的镍氢电池管理系统软件设计

通过对镍氢电池性能的研究，给出了一个应用ISA总线技术构建的、基于DELPHI编程平台的镍氢电池管理系统的设计方案，重点介绍了该系统的软件技术和实现方法。     

防水墙技术初探

防水墙技术是一种防止内部信息向外扩散的技术。论文给出了防水墙的定义及功能特性,并通过对防水墙系统WaterBox的介绍分析,探讨了利用防水墙技术构筑内网信息安全的可行性及发展趋势。     

β″－Al_2O_3陶瓷的强化和韧化

研究了稳定ＺｒＯ＿２和部份稳定ＺｒＯ＿２对β″－Ａｌ＿２Ｏ＿３陶瓷的强化和韧化作用，观察了不同种类、不同含量的ＺｒＯ＿２对β″－Ａｌ＿２Ｏ＿３陶瓷的显微结构、力学性能和电导率的影响，探讨了β″－Ａｌ＿２Ｏ＿３的韧化机理。     

The maximum bit rates of soliton communication systems with lumpedamplifiers and filters in different distances

The maximum bit rate of a soliton communication system with lumped amplifiers and optical filters is considered. When the dispersion of the fiber varies from one amplifier spacing to another amplifier spacing, the maximum bit rate is significantly reduced. To overcome the effect, the amplitude of the soliton is amplified so that it is still the average soliton corresponding to the fiber dispersion for an amplifier spacing. Thus, the maximum bit rate is only slightly less than that without the dispersion variations. For a given distance, the maximum bit rate limited by the stability and soliton interaction is obtained. The result is compared with that limited by the Gordon-Haus effect. For shorter transmission distance, the maximum bit rate is limited by the stability and soliton interaction. For longer transmission distance, the maximum bit rate is limited by the Gordon-Haus effect     

MSTP在3G的应用

讨论了MSTP的技术特点,指出MSTP能高效可靠传输各种业务,并结合3G网络的业务发展以及3G传输关注的接口,提出采用引入ATM功能的MSTP技术解决3G传输网络的方案.     

论王光祈的“少年中国”理想

王光祈的“少年中国”理想，是以“少年意大利”为基础，汲取五四时期社会主义思潮的积极成分而形成的。创造“少年中国”在“人”的方面，是从改造中国少年入手，同时注重青年学生与平民的改造，注重劳动阶级、智识阶级与资产阶级的改造与联合；在“事”的方面，积极开展社会事业和社会活动，且必须经过社会分工与国际分工。可见，他的这种理想是典型的社会改革主张，在早期带有无政府主义色彩，自始至终具有强烈的民族主义情感。