Chemical bond characteristics and infrared reflectivity spectrum of a novel microwave dielectric ceramic CaIn2O4 with near-zero τf

Orthorhombic-structured CaIn₂O₄ ceramics with a space group Pca2₁ were synthesized via a solid-state reaction method. A high relative density (95.6 %) and excellent microwave dielectric properties (ε_r ～11.28, Qf = 74,200 GHz, τ_f ～ ?4.6 ppm/°C) were obtained when the ceramics were sintered at 1375 °C for 6 h. The dielectric properties were investigated on the basis of the Phillips–Van Vechten–Levine chemical bond theory. Results indicated that the dielectric properties were mainly determined by the InO bonds in the CaIn₂O₄ ceramics. These bonds contributed more (74.65 %) to the dielectric constant than the CaO bonds (25.35 %). Furthermore, the intrinsic dielectric properties of the CaIn₂O₄ ceramics were investigated via infrared reflectivity spectroscopy. The extrapolated microwave dielectric properties were ε_r ～10.12 and Qf = 112,200 GHz. Results indicated that ion polarization is the main contributor to the dielectric constant in microwave frequency ranges.     

热稳定性测定仪法测定PVC树脂及其制品的热稳定性

介绍了热稳定性测定仪的测定原理、试验注意事项及测定方法,指出该仪器具有操作简便、重现性好、数据准确的优点,对评价PVC树脂及其制品的热稳定性具有指导意义.     

Effects of Sr2+ substitution on the crystal structure,Raman spectra,bond valence and microwave dielectric properties of Ba3-xSrx(VO4)2 solid solutions

The effects of Sr²⁺ substitution for Ba²⁺ on microwave dielectric properties and crystal structure of Ba_3-xSr_x(VO₄)₂ (0 ≤ x ≤ 3, BSVO) solid solution were investigated. Such Sr²⁺ substitution contributes to significant reduction in sintering temperature from 1400 °C to 1150 °C. Both permittivity (∑_r) and quality factor (Q × f) values decreased with increasing x value, which was determined to be related with the descending values of average polarizability and packing fraction, whereas the increase in τ_f value was explained by the decreased average VO bond length, A-site bond valence. BSVO ceramics possessed encouraging dielectric performances with ∑_r = 12.2–15.6 ± 0.1, Q × f = 44,340 - 62,000 ± 800 GHz, and τ_f = 24.5–64.5 ± 0.2 ppm/°C. Low-temperature sintering was manipulated by adding B₂O₃ as sintering additive for the representative Sr₃V₂O₈ (SVO) ceramic and only 1 wt.% B₂O₃ addition successfully contributed to a 21.7% decrease in sintering temperature to 900 °C, showing good chemical compatibility with silver electrodes, which render BSVO series and SVO ceramics potential candidates in multilayer electronic devices fabrication.     

高准确度静态质量法液体流量标准装置及其不确定度评价

本文介绍了一种高准确度质量法液体流量标准装置的设计方法,为对市场中出现的高准确度科里奥利质量流量计的量值传递提供了可能。文中介绍了装置设计过程中,为提高装置准确度用到的电动换向、衡器自校准、蒸馏水代替自来水等方法。试验证明,上述方法的应用使装置达到了预期的不确定度水平。文章还着重介绍了高准确度静态质量法液体流量标准装置不确定度的评价要点,对装置的不确定度水平进行了评定。     

吸湿凉爽机织物的结构设计与性能

为研究织物组织结构与复合纱线线密度对织物凉爽性能的影响,将线密度为7.4和9.8 tex涤纶分别与线密度为7.8 tex锦纶反向加捻、并线后作为纬纱,以8.3 tex涤纶/竹浆纤维50/50混纺纱作经纱,设计平纹、二上一下斜纹和透孔组织织物.测试织物的瞬间接触凉感、热湿舒适性能及织物干、湿态升温曲线,并采用凉爽温度指数对织物的综合凉爽性能进行评价.研究结果表明:6种设计织物的瞬间接触凉感均高于标准,且平纹织物最好,纬纱粗细对瞬间接触凉感影响不显著;透孔织物透气性最好,且在人体出汗的状态下具有较好的导湿散热性能.平纹织物凉爽温度指数最高,最大凉爽温度为2.8℃,综合凉爽性能最好.     

102综采工作面瓦斯防治的实践

本文对曲江矿首次在102工作面上综采机生产时出现的瓦斯超限原因进行了认真分析，阐述了所采取的主要防治技术措施及其效果。     

气压变化与采空区瓦斯涌出规律探讨

研究分析了沿空掘巷掘进工作面老空区瓦斯受气温影响的涌出规律,提出了沿空掘巷掘进工作面防止老空区瓦斯涌出发生超限事故的综合治理措施。     

经济全球化与我国资源型城市产业结构转化研究——以辽宁省盘锦市为例

世界经济的全球化推动着地区产业结构的转化 ,由此 ,为我国资源型城市和地区如何发展经济 ,如何参与竞争并保持自身的可持续发展能力提出了一个严峻的课题。本文在理论阐述的基础上 ,以辽宁省盘锦市为例 ,从产业结构的基本特征、面临的问题以及如何进行产业结构调整与转化等方面进行了分析     

Study on preparation and application performance of blue sky rare earth light storage and emission material

Under reduction atmosphere, a blue sky rare earth silicate light storage and emission material was prepared by high temperature solid phase synthesis. The best constituent ratio of this material was determined through orthogonal experiment, and its excitation and emission spectra and X-ray diffraction patterns were measured. And a comparative study was conducted on its application properties.     

某新生代红土型金矿选矿试验研究

针对云南某新生代红土型露天金矿金的粒度分布呈粗细极不均匀的特点,采用高离心力场重选工艺进行研究,较好地解决了粗粒金以及微细粒金的回收难题,当原矿金品位1.1g/t,精矿金品位47.23g/t,金回收率达到86.09%,获得了满意的选别指标。