温控阀用感温蜡的性能分析

感温包既是温控阀的驱动元件,也是流体的感温元件。感温包内的感温蜡性能的好坏直接影响温控阀的工作状况。作者通过差热分析实验,将温控阀用感温蜡和普通石蜡的相变性能进行分析,说明了感温蜡发生相变时能够吸收更多的热量,比普通石蜡更适合作感温介质。     

无限长圆柱体的热弹性耦合问题

应用经典传热学理论,研究无限长圆柱体的热弹耦合问题。建立了经典传热学理论的控制方程,借助拉普拉斯积分变换及其数值反变换技术对问题进行了求解,得到了瞬态热冲击作用下无限长圆柱体中的温度、应力、位移的分布规律。从其分布图上可以看出,介质中呈现出热弹耦合效应。并且比较了传统热弹性理论与广义热弹性理论。     

反应物量对纳米晶Fe_3Al组织和性能的影响

利用铝热反应熔化方法分别在反应物量为50、100、200g的条件下制备了块体纳米晶Fe3Al材料,通过TEM和XRD研究了材料的晶粒尺寸,并研究了材料室温压缩性能和硬度。结果表明,所制备的材料主要由非晶和纳米晶组织组成,当反应物量增大,部分区域甚至出现微米晶组织。反应物量为50g时Fe3Al材料中非晶较多,不存在微米晶;反应物量为100g时主要以纳米晶为主,非晶数量减少,伴随有少量的微米晶出现;反应物量为200g时,材料以纳米晶为主,微米晶数量较100g时有所增加。随着反应物量的增加,纳米晶相的平均晶粒尺寸增加,屈服强度和硬度呈先增大后减小的趋势。     

Knowledge Mining of Low Specific Speed Centrifugal Pump Impeller Based on Proper Orthogonal Decomposition Method

To clarify the complex relation between the pump blade shape and its corresponding hydraulic performance, the knowledge mining method of centrifugal pump impeller based on proper orthogonal decomposition(POD) was proposed. The pump blade shape was parameterized by cubic Bezier curve. The Latin hypercube design method was employed to supply the necessary samples for producing the perturbations of blade wrap angle, and blade angle at inlet and outlet. The hydraulic efficiency and head were optimized by NSGA-II and RBF hybrid algorithm. The Pareto-optimal solutions were obtained. In order to further illustrate the relationship between the centrifugal pump blade shape and its hydraulic performance, the POD method was used to discover the effects of optimized blade shape to the flow solutions. For the optimization of centrifugal pump MH48-12.5, blade shape and relative velocity field in impeller from Pareto-optimal solutions were analyzed. The results demonstrate that larger blade angle and smaller wrap angle increase the average kinetic energy in impeller, resulting in higher pump head design. Smaller blade angle and larger wrap angle decrease the velocity gradient from the pressure side to suction side, resulting in smaller hydraulic loss and higher efficiency design.     

Structural,optical and electrical properties of Cu2FeSnSe4 and Cu(In,Al)Se2 thin films

Cu-based semiconductors Cu₂FeSnSe₄ (CFTSe) and Cu(In, Al)Se₂ (CIAS) have been fabricated using radio-frequency magnetron sputtering combined with rapid thermal selenization processing. For CFTSe, the heating rate ranging from 60 to 150 °C/min results in a difference in structure, morphology and optical properties. Thin film exhibits a pure phase structure, smooth surface and a band gap of 1.19 eV as the heating rate elevated to 90 °C/min. Furthermore, the CFTSe thin film selenized at 90 °C/min own the smallest value of cell volume compared with the others samples, which represents a more stable structure. In terms of the other Cu-based material CIAS, three different selenization pressures, i.e., 1, 5 and 10 Torr, have been employed for CIAS preparation. Thin film transforms into single phase with dense morphology along with the pressure of 1 Torr. The diverse band gap of CIAS thin films from 1.34 to 2.18 eV attribute to two reasons: (i) the various Al content will affect the hybridization degree of Al–Se, and finally tunes the band structure, (ii) amounts of CuSe has a certain degree of effect on the band gap of the CIAS. In addition, the electrical properties of CFTSe and CIAS are also researched with the open circuit voltage (V_oc) of 94 and 365 mV, respectively, signifying potential applications of CFTSe and CIAS for the thin film solar cells.     

First-principles investigation of the optical properties of CuIn(SxSe1–x)2

We optimized the lattice structure of sulfur-doped CuInSe₂ using first principles. The lattice constants for CuIn(S_xSe_1–x)₂ vary linearly with x according to a(x)=–0.02828x+0.58786 nm and c(x)=–0.05692x+1.1834 nm, which agree well with experimental data. The optical properties of CuIn(S_xSe_1–x)₂ were then systematically investigated using first-principles calculations with the HSE06 functional. We present data for the complex dielectric function, refractive index, extinction coefficient, reflectivity index, absorption coefficient, and optical bandgap for CuIn(S_xSe_1–x)₂. The optical bandgap E_g obtained from the absorption coefficient is 1.07 eV for CuInSe₂ and 1.384 eV for CuInS₂. These values are very close to experimental results, indicating that first-principles calculations can yield accurate bandgap values. The optical bandgap of CuIn(S_xSe_1–x)₂ increases linearly with the sulfur concentration according to E_g=0.3139x+1.0825 eV.     

A 9,9′-bianthracene-cored molecule enjoying twisted intramolecular charge transfer to enhance radiative-excitons generation for highly efficient deep-blue OLEDs

The efficiency of fluorescent organic light emitting diodes (FOLEDs) is strongly affected by the fraction of singlet excitons formed. However, the standard statistical value of the single to triplet ratio is 1:3, which implies most of the excitons are invalid in fluorescent emitting devices. Here, we demonstrate the ability of twisted intramolecular charge transfer state (TICT-state) to enhance the occurrence of singlet excitons in a fluorescent emitter that is based on the 9,9′-bianthracene (BA) moiety. The anthracene–anthracene (A–A) linked by a single bond and having perpendicular electronic structure is a charge transfer intersystem crossing π system in excited state. The BA-cored fluorescence emitter (CzBACz) with particular TICT characteristics realizes the electron–hole (e–h) recombination via intramolecular conversion from charge-transfer excitons (immediate precursor) to radiative singlet exciton (final state). For CzBACz-based electroluminescent (EL) device, the singlet generation fraction is more than 25%.     

液氮温度下分子筛的真空吸附特性试验研究

为探究低温容器夹层所用分子筛吸附剂的吸附特性,采用静态膨胀法进行试验,获得了平衡压力为10-3Pa～103Pa范围内4A、5A和13X分子筛对N2、O2单一组分以及空气的吸附等温线,比较了不同分子筛对气体的吸附能力差异,探究了分子筛的吸附机理.研究结果表明:液氮温度下,5A和13X分子筛在真空条件下对N2及O2的吸附性...