Lower down both ohmic and cathode polarization resistances of solid oxide fuel cell via hydrothermal modified gadolinia doped ceria barrier layer

Hydrothermal reaction in Cerium and Gadolinium solution as an optimization method is developed and first reported for the densification of gadolinia doped ceria, the barrier layer between Zirconia electrolyte and (La,Sr)(Co,Fe)O_3-δ cathode. This method is based on the hydrothermal reaction for nano particles in-situly grown on porous surface, to improve barrier layer density, alongside the sintering of cathode at 1075 °C. As a result, the ohmic resistance is prominently decreased by ～16.4 % at 750 °C for electrolyte supported symmetrical cell. Whereas, the cathode polarization resistance is decreased by as much as a factor of ～3 from 0.3702 Ω·cm² to 0.1325 Ω·cm² at 750 °C and $p_{O_2}=0.21atm$. Furthermore, the anode supported cell exhibits higher open circuit voltage, smaller area specific resistance, elevated performance output and less degradation. And this modified barrier layer shows reduced Sr migration in 300 h operation at 750 °C. The hydrothermal reaction is demonstrated to prepare denser and sintering-active barrier layer with faster oxygen ion transfer and better interface connection, with large-scale application prospects and cost-competitiveness.     

Novel high-energy ionic molecules deriving from new monovalent and divalent 4-oxyl-3,5-dinitropyrazolate moieties

ABSTRACT

In recent years, the exploration of a practical strategy for novel energetic molecules with high energy and low sensitivity is very desirable but highly challenging. Novel ionic energetic molecules have attracted much attention in this area due to their prominent advantages including low sensitivities, high thermal stability, and excellent energy performances. Herein, five different ionic energetic molecules based on new monovalent and divalent 4-oxyl-3,5-dinitropyrazolate moieties with enhanced oxygen balance have been synthesized, characterized and evaluated as potential high-energy materials. Thermal stability, sensitivities and energy output test were measured and studied in detail. The heats of formation and energetic parameters were calculated by using Gaussian 09 suite of programs and EXPLO 5 code. The results suggest that all as-prepared new molecules exhibit good thermal stability with high decomposition temperature (3, 231°C; 5, 160°C; 6, 185°C; 7, 180°C; 8, 213°C), and relative low sensitivity (IS > 20 J, FS = 324 N). Inheriting the significant oxygen content of monovalent and divalent 4-oxyl-3,5-dinitropyrazolate moieties, they also possess good energy properties (v _D = 8238 ~ 9208 m s^?1, P = 26.8 ~ 36.7 GPa, V _o = 481.8 ~ 959.4 L kg^?1), which make them competitive high-energy materials.     

Prediction of High Methane-Recovery Regions and Gas Extraction Technology Based on Geodynamic Zoning of Bowels

An analysis is performed for the existing hypotheses and theories used for calculating the technological parameters of operations on methane extraction from coal seams. The priority of geodynamic processes in methane collector formation, as well as the methods applied for the morphometry and processing of the remote probing data are substantiated. The urgency is shown for the investigation into the autooxidation and other exothermic reactions proceeding in coal seams and leading to methane transition to the free state.     

Indoor air quality in the 21st century: search for excellence

Field studies demonstrate that there are substantial numbers of dissatisfied people in many buildings, among them those suffering from sick building syndrome (SBS) symptoms, even though existing standards and guidelines are met. The reason is that the requirements specified in these standards are rather low, allowing a substantial group of people to become dissatisfied and to be adversely affected. A paradigm shift from rather mediocre to excellent indoor environments is foreseen in the 21st century. Based on existing information and on new research results, five principles are suggested as elements behind a new philosophy of excellence: 1) better indoor air quality increases productivity and decreases SBS symptoms; 2) unnecessary indoor pollution sources should be avoided; 3) the air should be served cool and dry to the occupants; 4) "personalized air", i.e. a small amount of clean air, should be served gently, close to the breathing zone of each individual; and 5) individual control of the thermal environment should be provided. These principles of excellence are compatible with energy efficiency and sustainability.     

在城市燃气工程中推广使用聚乙烯（“PE”）管材

阐述了“ＰＥ”管的优点、性质、使用条件及推广的意义。     

数据机房热环境影响因素研究

对某数据机房进行测量,以实测数据作为模拟的边界条件,采用开箱模型对机房热环境进行数值模拟,将模拟值与实测值进行对比,验证了模型的可靠性。在此基础上,分别对不同架空地板高度,送风孔板孔隙率,冷通道宽度以及不同挡板间距和高度等工况进行模拟,分析了各种因素对数据机房热环境的影响,得到了各个参数的最佳值,为数据机房的安全运行与节能优化提供指导。     

改善温暖地区室内热环境的新途径——除湿

长江流域广大地区有夏闷热而冬阴冷的气候特征,过去以夏日通风隔热而冬日保温防寒的传统措施有一定效果,但不很显著,原因是尚未抓着主要矛盾,以此来改善环境未能收到理想功效。本文论证,以降低湿度以改善室内热环境这一新途径。这可能是湿热地区最为有效和最经济和节能的方法。     

某办公楼地源热泵与冰蓄冷复合系统能效评价

地源热泵技术是当今世界较先进的空调技术,作为被政府和社会认可的可再生能源,在我国已得到大规模推广应用。空调蓄冷技术由于能够转移电力高峰用电量,平衡电网峰谷差,缓解供电压力,具有较大的经济和社会效益,在我国也得到了广泛应用。单一使用这两种技术的项目较多,二者复合运行的系统较少,通过对某办公楼地源热泵+冰蓄冷复合系统的现场测试,从技术和优化运行角度分析影响系统能效的关键因素,并对设备配置及管理人员对系统节能运行产生的影响进行论述,使项目具有更加良好的借鉴意义。