Effect of preparation conditions on the properties of a coal-derived activated carbon honeycomb monolith

Activated carbon honeycomb (ACH) monoliths were prepared by extruding of a mixture of bituminous coal and organic additives and subsequent carbonization and steam activation. Preparation parameters that were varied were carbonization temperature and activation time. The carbonization conditions were 500, 650 and 800 °C for 1 h and the steam activation conditions were 850 °C for 2, 4 and 6 h. The monoliths at various states were characterized by SEM, XRD, nitrogen adsorption and compression test. It was found that carbonization temperature has significant effects on pore size distribution and mechanical strength of ACH monoliths. The ACH monoliths prepared from high carbonization temperatures exhibited lower values of the BET surface area and total pore volume and higher value of the mechanical strength than those of the ACH monoliths prepared from low carbonization temperatures. This was attributed to the effect of high temperature carbonization that results in the formation of relatively less defective structures.     

Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated.The results revealed that Zn+implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure.Meanwhile,C:Zn solid solution was synthesized after Zn+ implantation.The turn-on field and threshold field were 0.80 and 1.31 V/μm,respectively for original...     

Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

Damage and deterioration mechanism and curing technique of concrete structure in main coal cleaning plants

Concrete structures in main coal cleaning plants have been rebuilt and reinforced in the coal mines of the Shanghai Da-tun Energy Sources Co. Ltd., the first colliery of the Pingdingshan Coal Co. Ltd. and the Sanhejian mine of the Xuzhou Mining Group Co. Ltd. In these projects, the operating environment and reliability of concrete structures in the main plants of the three companies were investigated and the safety of the structures inspected. Qualitative and quantitative analyses were made on the spe-cial natural, technological and mechanical environments around the structures. On the basis of these analyses, we discuss the long-term, combined actions of the harsh natural (corrosive gases, liquids and solids) and mechanical environments on concrete structures and further investigated the damage and deteriorating mechanisms and curing techniques of concrete structures in the main coal cleaning plants. Our study can provide a theoretical basis for ensuring the reliability of concrete structures in main coal cleaning plants.     

光谱法研究Ni[S2P（OCH2CH2Ph）2]2与α,α＇-联吡啶加合反应

利用紫外光谱法研究了Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶的加合反应。研究发现Ni[S2P（OCH2CH2Ph）2]2与α,α-联吡啶形成1∶1型加合物,在25℃的苯溶剂中,加合物的离解度α=0.07,稳定常数K稳^θ=2.1×10^6。     

筏板基础在自贡地区高层建筑设计中的应用研究

文章结合工程设计经验对自贡地区的高层建筑在选用天然筏板基础的设计过程中,对高层建筑基础设计中涉及到的重要的地基沉降计算、结构设计和地下水等有关问题的处理进行了具体分析,对在一般高层建筑中采用天然筏板基础的实用性和可行性从设计和施工两个方面进行了相关的工程探讨。     

基于虚拟技术的单闭环直流调速系统的研究

本文建立了他励直流电动机虚拟模型,通过模型进行仿真算法分析,并利用虚拟技术,在仿真平台上实现仿真,在上位机上显示数据,对单闭环直流调速系统进行可行性研究与优化。仿真做的主要前期工作为模型建立,通过电枢回路方程和动力方程进而推导出电动机的数学模型方程,并对模型进行分析计算。后期工作对所建立的模型进行仿真,并调试出模型数据,进而得到仿真结果。设计的虚拟模型建立在虚拟仿真平台上,利用平台的模拟和数字输入输出端口进行信号的采集和传递,并利用仿真平台强大的内部资源进行运算分析,从而达到期望的研究效果。     

型钢混凝土框架桥受力特性的分析

目前框架桥结构主要是普通的钢筋混凝土框架结构,这种框架结构主要存在自重过大的问题,此问题导致顶进施工过程中土体的破坏和材料的浪费以及顶进施工难度的增加.本文提出用型钢混凝土结构代替框架桥中的普通钢筋混凝土结构,并用有限元软件Midas Civil对普通的钢筋混凝土框架桥和不同含钢率型钢混凝土框架桥进行了有限元的对比分析,对比两者在同等地质和荷载的条件下,所受内力和位移的情况.通过对比分析发现型钢混凝土框架桥结构是可行的,并得出了型钢混凝土框架桥含钢率的合理范围为5％～6％.     

消泡剂在发酵工业中的应用

泡沫问题是发酵工业中一个棘手的问题,几乎所用的液体深层发酵都会用到天然或者化学消泡剂。在过去的发酵过程中,泡沫控制一般是依靠经验,关于消泡剂的系统知识较少。本文综述了发酵工业中消泡剂的种类和作用机制,以及消泡剂的应用进展。     

含氮、磷有机配体对(CdSe)_2量子点结构和电子性质的影响

使用密度泛函理论方法研究了量子点(CdSe)2与配体L(L=PH3、PH2Me、PHMe2、PMe3、NH3、NH2Me、NHMe2、NMe3)之间的相互作用及其产物的结构和性质。配体中的P或N原子与Cd原子上分别形成较强的Cd—P和Cd—N配位键,从而影响(CdSe)2的结构和电子性质。配体作用下,(CdSe)2的几何结构、电荷分布、轨道能级、吸收光谱等均发生变化,但2类配体的影响,尤其是甲基数目的影响,存在较大差异。