南水北调中线总干渠藻类的生态调度

南水北调中线总干渠无在线调蓄水库,对藻类生态调度过程中出现的问题开展生态调度实现策略和实施方式研究。主要实现策略包括:划定自身的调蓄区,隔离生态调度对下游的影响;采用高效的渠池运行方式,减少生态调度时蓄量的反复调整;综合考虑安全、快速、平稳等需求,设定生态调度实施进程和方式。具体实施方式包括:将总干渠划分为流速调控区、调蓄区和正常运行区,分别实施等体积、控制蓄量和闸前常水位方式运行;将生态调度过程划分为充水阶段和泄水阶段,基于流速调控目标值、持续时长和水位降幅约束条件,确定各阶段时长和各分区的闸门群调控方案等。基于2018年3月输水工况,采用明渠一维非恒定流模型,仿真总干渠上游15个渠池的藻类生态调度过程。结果表明,生态调度可在3.5 d内完成,各渠池的平均流速由0.48 m/s增至0.93 m/s,持续时间超过2 h。在整个生态调度过程中,水位变化平稳,水位变幅符合安全阈值要求,下游渠道的正常运行未受生态调度明显影响。     

Mg0.5NixZn0.5-xFe2O4 spinel as a sustainable magnetic nano-photocatalyst with dopant driven band shifting and reduced recombination for visible and solar degradation of Reactive Blue-19

Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg_0.5Ni_xZn_0.5-xFe₂O₄ (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg_0.5Ni_0.4Zn_0.1Fe₂O₄ (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O₂⁻ radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification.     

Creating an Holistic Emergency Alert Management Platform

ABSTRACT

Extreme natural events require effective emergency procedures to minimize adverse effects on a region’s population and economy. Such procedures typically involve the effort of several different teams of first responders (e.g., fire fighters, public administrations, police departments, utility companies), hence coordination is fundamental to the effectiveness of the response to the emergency that must be supported with adequate infrastructures. Nonetheless, first responders often rely on manual processes, in the life cycle of extreme events, which do not change consistently with the type of shock or affected population. The aim of this paper is to present a technology transfer process to improve both the emergency alert process and the knowledge of disaster-type safety procedures through the implementation of a proposed platform. We also highlight a pilot application on a post-disaster case study—the province of L’Aquila (Abruzzi) in Italy.     

基于热力学的自然风压分析方法

从热力学的角度出发，考虑巷道热力因素对风流的影响，导出自然风压的计算方法。     

Study on preparation and application performance of blue sky rare earth light storage and emission material

Under reduction atmosphere, a blue sky rare earth silicate light storage and emission material was prepared by high temperature solid phase synthesis. The best constituent ratio of this material was determined through orthogonal experiment, and its excitation and emission spectra and X-ray diffraction patterns were measured. And a comparative study was conducted on its application properties.     

纳米粉体粒度特性表征方法讨论

实验中采用不同的方法对四种ZrO2纳米粉体的颗粒特性进行了表征。对颗粒呈现球形、不发生硬团聚的微小粒子，例如YSZ—KD试样，一次颗粒粒度为10～15nm，比表面为64．2m^2／g，采用XRD获得的微晶粒子尺寸与TEM和BET方法获得的颗粒尺寸相一致。由于比表面高，颗粒之间容易发生静电力、范德华力和液桥力的作用而软团聚在一起，其团聚系数较大为62．5，粒度分布宽度为14．58。TEM和BET与XRD方法获得的颗粒尺寸出现偏差，说明YSZ—HW1、YSZ—TH试样中出现了基元为2～3的多晶颗粒，多晶颗粒存在使得颗粒体偏离球形。团聚系数为25．71，粒度分布宽度为18．94的YSZ—HW1试样中仍存在较多的软团聚体，团聚系数为6．89，粒度分布宽度为8．91的YSZ—TH试样中软团聚状况明显较少。YSZ—HW2试样中TEM和BET与XRD方法获得的颗粒尺寸出现很大偏差，说明其中存在较多的硬团聚体，硬团聚体使得颗粒呈现不规则外形，其比表面小，活性低，表现为团聚系数小，粒度分布窄。     

软开关技术的发展及其现状

详细地介绍了软开关技术发展的历史及最新研究现状,其中包括准谐振电路、零开关PWM电路和零转换PWM电路,指出了软开关技术的新进展,并给出了部分典型电路。     

谢一矿深部软岩巷道底臌机理及其防治措施研究

通过现场实测研究，查明谢一矿深部巷道失稳破坏的主导因素是底臌，因而对巷道底臌的机理进行了分析，提出了防治底臌的综合技术措施，取得了较好的效果。     

天然沸石的选矿提纯新工艺研究

本文通过一系列的选矿试验研究，得出了破碎—搅拌—分级提纯天然沸石原矿的新工艺，且工艺过程不含磨矿，流程简单，加工成本低。经上述工艺提纯的天然沸石，基本不含杂质，可直接作为许多工业部门的原材料使用。