Excellent destabilization effect and ideal desorption temperature in the hydride Mg2FeH6 substituted with yttrium; a first principles study

We investigated some properties of the hydride Mg₂FeH₆ substituted with yttrium by a first principles calculation. Some experimental results showed that 4d transition metal, yttrium serves as a good catalyst for magnesium based hydrogen storage alloys, but there are a few theoretical studies about magnesium based hydrides substituted with it. Mg₂FeH₆ is regarded as a cheaper material than pure MgH₂, while it is crystalized into Fm3m structure (space group 225). Although it has high hydrogen storage capacity, many investigations have not been devoted to it due to its extremely high thermodynamic stability. The yttrium substituted Mg₂FeH₆ exhibits very low energy of formation, and its desorption temperature, 75 °C is very suitable for practical hydrogen storage applications. Our results showed that Mg₂FeH₆ is destabilized effectively by yttrium substitution and introducing vacancy defects has additive effect to the improvement of dehydrogenation performance.     

Genotoxic effect of triarylmethane dye--acid green 16 after chronic ethanol consumption in mice

Genotoxic effect and hepatic microsomal monooxygenase activities were assessed in mice treated with Acid Green 16 (single i.p. injection at dose 75 mg/kg) superimposed on prolonged ethanol consumption (10% solution in drinking water for 2-4 months). Treatment of mice with Acid Green 16 led to an increased frequency of micronucleated erythrocytes in bone marrow. In animals pretreated with ethanol the frequency of micronucleated erythrocytes, produced by Acid Green 16, was significantly higher. The changes in frequency of micronucleated erythrocytes were accompanied by the enhanced activity of microsomal monooxygenases manifested by higher activity of 7-ethoxycoumarin o-deethylase (the level of cytochrome P-450 was not altered). The obtained results showed that ethanol tended to increase the genotoxic effect of Acid Green 16. However, the slight inductive effect of ethanol on microsomal monooxygenases did not provide clear evidence that the genotoxic effect of Acid Green 16 was associated with ethanol stimulation of the metabolic activation of the dye in the liver.     

Adsorption and decomposition of NO on carbon and carbon-supported catalysts

The interactions of NO with carbon and carbon-supported catalysts have been investigated by means Fourier transform infrared spectroscopy. Nitric oxide direct decomposition over carbon-supported catalysts (Cu, Pt) was studied in a temperature ranging from 473 to 623 K. NO conversion increased with increasing reaction temperature in the whole temperature range. The carbon-supported Pt catalyst has a very high activity for the decomposition of NO in the absence of oxygen. As a result of NO chemisorption isocyanate (-NCO) species on the surface of carbon containing Cu were observed. When the reaction temperature was increased, the -NCO band at 2229 cm⁻¹ became more intense.     

Subatomic Natural Deduction for a Naturalistic First-Order Language with Non-Primitive Identity

A first-order language with a defined identity predicate is proposed whose apparatus for atomic predication is sensitive to grammatical categories of natural language (e.g., common nouns, verbs, adjectives, adverbs, modifiers). Subatomic natural deduction systems are defined for this naturalistic first-order language. These systems contain subatomic systems which govern the inferential relations which obtain between naturalistic atomic sentences and between their possibly composite components. As a main result it is shown that normal derivations in the defined systems enjoy the subexpression property which subsumes the subformula property with respect to atomic and identity formulae as a special case. The systems admit a proof-theoretic semantics which does not only apply to logically compound but also to atomic and identity formulae—as well as to their components. The potential of the defined systems for a meticulous first-order analysis of natural inferences whose validity crucially depends on expressions of some of the aforementioned categories is demonstrated.     

Early-warning performance monitoring system (EPMS) using the business information of a project

An early-warning performance monitoring system (EPMS) is proposed to objectively measure and monitor the performance of a project for early detection of inherent poor performance problems. The EPMS is built based on project progress data and consists of a database of business information, an optimized theoretical model used as a performance measurement baseline, and an index for monitoring and forecasting the performance. By monitoring the performance through an application of the EPMS to the Korean construction project, the quarterly variation of index was found to differ by project type. These results could explain the environmental changes in the project execution. Therefore, the EPMS is expected to be an alternative for objective performance monitoring and forecasting while applying the existing methods is difficult because of the limited available data on performance indicators. The development procedures may also be useful to researchers interested in approaches to quantitatively analyze trends in various industries.     

Effect of the structure of polymer inclusion membranes on zn(II) transport from chloride aqueous solutions

This article presents application of polymer inclusion membranes (PIM) containing polymer matrices: cellulose triacetate (CTA) or poly(vinyl) chloride (PVC), o‐nitrophenyloctyl ether (NPOE) as a plasticizer and phosphonium ionic liquids, i.e., trihexyltetradecylphosphonium chloride (Cyphos IL 101), bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL 104) and tributyltetradecylphosphonium chloride (Cyphos IL 167), as carriers for Zn(II) transport from chloride medium. Cyphos IL167 application as an ion carrier in PIMs is reported for the first time. The membrane composition is found to affect Zn(II) transport significantly. SEM and AFM images show the differences in the surface morphology of PVC and CTA based membranes. Better transport abilities of CTA membranes (Zn(II) recovery factors exceed 80%) compared with those of PVC, indicate that the structural differences between the two polymers play a crucial role for the membrane permeability. The best initial flux and permeability coefficient are obtained for the membranes with Cyphos IL 101 and Cyphos IL 104 as carriers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42319.     

Development of heat storage gypsum board with paraffin-based mixed SSPCM for application to buildings

Latent heat thermal energy storage using phase change materials (PCMs) is considered to be the method with the most potential to solve the energy shortage problem. In this study, paraffin-based mixed shape-stabilized PCM (SSPCM) (PBMS) was made by vacuum impregnation method. The prepared PBMS was added to gypsum powder as a fine aggregate. In the experiment, the n-hexadecane and n-octadecane was used as the PCM and the materials have latent heat capacities of 254.7 and 247.6 J/g, and melting points of 20.84 and 30.4 °C, respectively. The PBMS was prepared by an impregnation method in a vacuum, following the manufacturing process. The physical and thermal properties of the PBMS gypsum board were analyzed by Fourier transform infrared spectrometry (FTIS), differential scanning calorimetry, enthalpy analysis, and thermogravimetric analysis. From the Fourier transform infrared analysis, PBMS could be maintained in the structure of the gypsum board due to its physical rather than chemical bonding. From the specific heat and enthalpy analysis, the PBMS has high enthalpy and thermal inertia property. In addition, the gypsum board with PBMS has high latent heat capacity and high thermal efficiency.     

A team formation model based on knowledge and collaboration

Appointing a good leader to the position of team manager and having competent workers collaborate as team members is a key to success in business activities of an enterprising institution. The traditional methodologies of human resource management have defined the required abilities for team managers and team members, and evaluated those abilities of employees. However, it is difficult to consider those abilities systematically in practice. In addition, the current management paradigm undergoes rapid transitions into knowledge management. In step with these trends, this study presents a framework for analyzing the knowledge of the candidates for managers and team members for the new team, and proposes a genetic algorithm and social network measures for choosing a team manager and team members. A prototype was built for testing the feasibility of the model. The testing data are from an R&D institute’s human resource management department. The results show that our proposed approach is a quantitative and systematic method for selecting proper personnel for appropriate teams.     

Finishing works after welding of structures made of rust-resistant,high-alloy steels

In this paper, problems that occur when working with welds formed of high-alloy steels to restore their passive layers, damaged as a result of temperature impact, are discussed. Particular attention was paid to the procedures concerning aggressive etching agents during and after completion of the passivation processes (waste neutralization and utilization).