Morphology/behaviour relationship of nanocomposites based on natural rubber/epoxidized natural rubber blends

In order to analyze the effect of an epoxidized natural rubber (ENR) and filler treatment on the morphology and behavior of natural rubber (NR) nanocomposites, blends of these polymers have been prepared. The nature and extent of the clay dispersions in the filled samples were evaluated by X-ray diffraction. In the presence of ENR, an exfoliated structure was obtained which suggests that enough rubbery polymer was incorporated into the interlayer spacing. The effect of clay in rubber compounds was analyzed through rheological, mechanical and swelling characterization. A sensible improvement in the nanocomposite properties was observed by the addition of organoclay. It has been deduced that the properties of the compounds strongly depend on the extent of the silicate nanolayers dispersion into the rubber matrices as well as on the organoclay type and elastomer compatibility.     

Gentamicin treatment in peripheral vestibular disorders other than Ménière''s disease

Two cases of congenital trabecular hypoplasia of the right ventricle are reported. In the first, the neonatal diagnosis was missed and the child did well until the 13th month of life when a modified Blalock-Taussig shunt was done because of increasing cyanosis. Outcome was good until the 4th year of life when symptomatic atrioventricular block was detected in an emergency situation. A bidirectional Glenn anastomosis and pacemaker implantation were successfully carried out after clinical establization and the child is doing well up to now. The second case presents the disease with its worst features: severe cyanosis and acidosis in the first day of life. A modified Blalock-Taussig shunt was performed and death occurred soon after the operation.     

Evaluation of accuracy of measuring intraocular pressure by handheld non-contact applanation tonometer

PURPOSE: To evaluate the accuracy of measuring intraocular pressure by handheld non-contact applanation tonometer. METHOD: 58 patients' (113 eyes) intraocular pressure were measured by Keeler, non-contact tonometer and R 900 Goldmann applanation tonometer and the results of measurement of intraocular pressure by the two kinds of tonometers were compared. RESULT: The mean intraocular pressure measured by non-contact is 16.31 +/- 5.59 mmHg and 17.49 +/- 6.13 mmHg (1 mmHg = 0.1333 kPa) by Goldmann applanation tonometer, respectively. There was no statistical significance to be found (P > 0.05) between the two methods. By linear correlation and regression analysis, a positive correlation was found between the two methods (r = 0.8942, b = 0.8154). CONCLUSION: The handheld non-contact tonometer has the same accuracy and reliability of measurement of intraocular pressure comparing with Goldmann applanation tonometer, and it can be used in glaucoma clinic and screening.     

Effect of Magnetotactic bacteria on the susceptibility in Chinese loess–paleosol sequences

A simulated experiment of Magnetotactic bacteria (MB) effect on susceptibility in the samples from the 5th to 6th loess layers (L₅–S₅–L₆) in Xifeng and Duangjiapo sections was performed. It is demonstrated that MB can increase the susceptibility of the samples and promote newly produced magnetic minerals from paleosol layers under the suitable condition. The tiny magnetic particles and arranged as a chain in the minerals less than 30 μm were found in the paleosol sample of Duangjiapo section.     

Synthesis and two-photon absorption property of new π-conjugated dendritic fluorophores containing styrylpyridyl moieties

Four new multi-branched two-photon absorption chromophores, namely 1-(4-bromobenzal)-3,5-bis(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)benzene (4), tris(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)-benzene (5), 6-chloro-N²,N⁴-bis(4-((E)-2-(pyridin-4-yl)vinyl)phenyl)-1,3,5-triazine-2,4-diamine (6), tris-[4-(2-pyridin-4-yl-vinyl)-phenyl]-amine (7), have been synthesized and characterized. One-photon fluorescence, fluorescent quantum yields and two-photon fluorescence have been investigated. The experimental two-photon absorption cross-sections of 4–7 in DMF are 6, 11, 13 GM (pumped by 740 nm laser) and 19 GM (pumped by 800 nm laser), respectively. The calculated two-photon absorption cross-sections of 4–7 are 5.41, 7.67, 9.57 and 76.14 GM, respectively. The two-photon induced fluorescent peak wavelengths of 4–7 in DMF are 421, 425, 474 and 534 nm pumped by 680, 680, 740 and 800 nm laser, respectively. The results show that molecule 7 is a good two-photon absorption fluorophore possessing long two-photon fluorescent lifetime, good fluorescent quantum yield and large two-photon absorption cross-section. The two-photon absorption peak wavelength of molecule 7 is at 800 nm, which is favourable for initiating two-photon photopolymerization.     

Machine-learning paradigms for selecting ecologically significant input variables

Harmful algal blooms, which are considered a serious environmental problem nowadays, occur in coastal waters in many parts of the world. They cause acute ecological damage and ensuing economic losses, due to fish kills and shellfish poisoning as well as public health threats posed by toxic blooms. Recently, data-driven models including machine-learning (ML) techniques have been employed to mimic dynamics of algal blooms. One of the most important steps in the application of a ML technique is the selection of significant model input variables. In the present paper, we use two extensively used ML techniques, artificial neural networks (ANN) and genetic programming (GP) for selecting the significant input variables. The efficacy of these techniques is first demonstrated on a test problem with known dependence and then they are applied to a real-world case study of water quality data from Tolo Harbour, Hong Kong. These ML techniques overcome some of the limitations of the currently used techniques for input variable selection, a review of which is also presented. The interpretation of the weights of the trained ANN and the GP evolved equations demonstrate their ability to identify the ecologically significant variables precisely. The significant variables suggested by the ML techniques also indicate chlorophyll-a (Chl-a) itself to be the most significant input in predicting the algal blooms, suggesting an auto-regressive nature or persistence in the algal bloom dynamics, which may be related to the long flushing time in the semi-enclosed coastal waters. The study also confirms the previous understanding that the algal blooms in coastal waters of Hong Kong often occur with a life cycle of the order of 1–2 weeks.     

Using spectral method as an approximation for solving hyperbolic PDEs

We demonstrate an application of the spectral method as a numerical approximation for solving hyperbolic PDEs. In this method a finite basis is used for approximating the solutions. In particular, we demonstrate a set of such solutions for cases which would be otherwise almost impossible to solve by the more routine methods such as the Finite Difference Method. Eigenvalue problems are included in the class of PDEs that are solvable by this method. Although any complete orthonormal basis can be used, we discuss two particularly interesting bases: the Fourier basis and the quantum oscillator eigenfunction basis. We compare and discuss the relative advantages of each of these two bases.     

On delay-independent stability of large-scale systems with timedelays

A new criterion for delay-independent stability of linear large scale time-delay systems is deduced by employing an improved Razumikhin-type theorem and the m-matrix properties. An illustrative example is given to demonstrate the superiority of the obtained results to those in the literature     

Interpretation of the morphology and crystallography of precipitate γ1-Ti4Nb3Al9 in L10-TiAl(Nb)-based intermetallics by invariant line theory

The coherent precipitate γ₁-Ti₄Nb₃Al₉ in the Nb-modified TiAl-based intermetallic compound with a nominal composition of Ti–48 at% Al–10 at% Nb was investigated by transmission electron microscopy. The crystallographic and morphologic characteristics of the precipitating phase have been calculated based on invariant line theory. It is revealed that in the γ-TiAl(Nb)/γ₁-Ti₄Nb₃Al₉ couples, both the morphological and crystallographical characteristics of the precipitate γ₁-Ti₄Nb₃Al₉ could be predicted by the three-dimensional phase transformation invariant line model. The needle direction of [001] at the early stage for coherent precipitate γ₁-Ti₄Nb₃Al₉ and [111] for equilibrium phase γ₁-Ti₄Nb₃Al₉ have both been explained well. The characterization of morphology and crystallography of the precipitate reaction in γ-TiAl/γ₁-Ti₄Nb₃Al₉ system sustain the postulate that precipitates are bounded by unrotated planes (eigenplanes) when three real eigenvalues exist.