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使用毛细管高剪切黏度仪研究了滑石颜料分散体系的高剪切黏度性能,以及pH值、固含量、不同分散剂和润湿剂、不同粒径分布对滑石分散体系高剪切黏度的影响。同时还研究了滑石与GCC及高岭土混合浆料的高剪切黏度性能。结果表明,滑石含量越高、粒度越细,其分散浆料的高剪切黏度值越大。同时发现,滑石高剪切黏度受分散剂和润湿剂的影响不大。提高pH值有利于降低滑石分散体系的高剪切黏度。滑石与GCC混合浆料的高剪切黏度随着GCC粒度的变细而降低。当滑石与GCC的体系中加入高岭土后,混合浆料的高剪切黏度大幅增大,且随着GCC粒度的变细而增大。 相似文献
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Weiyin Su Zhixin Wang Zeyu Chang Yawen Feng Xi Yao Meng Wang Kun Wang Jianxin Jiang 《造纸与生物质材料》2023,(1):1-11
Countries are duly focusing more on biomass resources because of the increasing oil crisis. Owing to their excellent properties, such as natural characteristics, good mechanical performance, and outstanding chemical properties, cellulose-based materials are highly valued as promising bioderived nanomaterials, especially bacterial cellulose(BC). The main advantage lies in eliminating the problem of removing lignin and hemicellulose from woody cellulose. Moreover, the use of BC reduces the consump... 相似文献
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研究了纤维特性、打浆度、化学纤维用量、原纸紧度、浆内添加增强剂及表面施胶等因素对吸尘袋纸透气度和耐破度的影响规律。结果表明,降低浆料打浆度,能有效提高吸尘袋纸原纸透气度,浆料的打浆度从10~11°SR降低至8~9°SR时,原纸的透气度提高53%以上;随着化学纤维用量的增加,原纸透气度呈上升趋势,当化学纤维用量达15%时,原纸透气度比不加化学纤维的透气度增加108%,但通过降低打浆度来减少化学纤维用量,是性价比较优的方案;将原纸紧度由0.3 g/cm~3提高到0.4 g/cm~3,吸尘袋纸原纸的耐破度提高45%~55%;表面施胶量约5 g/m~2时,吸尘袋纸的耐破度比原纸提高80%~110%。 相似文献
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采用亚氯酸钠脱木素、TEMPO氧化改性处理玉米芯原料,并在改性玉米芯表面原位负载锌系金属有机框架物(ZIF-8),制备出ZIF-8/玉米芯吸附功能材料。探讨了改性处理对不同粒径玉米芯结构与性能的影响,对比了块状和粒状改性玉米芯对ZIF-8负载及吸附功能材料性能的影响。结果表明,脱木素与氧化处理可提高玉米芯纤维素及羧基含量,促进纳米ZIF-8晶体在玉米芯上的配位结合与原位锚定。相比块状玉米芯,粒状玉米芯改性后的比表面积更大、Zeta电位更高和羧基含量更多,更有利于ZIF-8的负载与分布,因而具有更好的吸附能力(对甲基橙最大吸附能力:3.5 mg/g比1.0 mg/g)。上述两种吸附功能材料均具有较好的回用性能,循环使用6次后,两种吸附功能材料对甲基橙的去除率仍高于90%。 相似文献
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本研究建立了液相色谱串联多级质谱(LC-MS/MS)测定纸张中丙烯酰胺含量的方法,分析了样品提取条件对检测结果的影响,并对丙烯酰胺在纸和纸板之间的迁移规律进行了初步探究。本研究以水为提取液,将样品超声提取30 min后,采用LC-MS/MS的多反应离子监测(MRM)进行样品检测,内标法定量。结果表明,超声提取可以有效提高纸张中丙烯酰胺的溶出速率;同一样品重复测定的相对标准偏差均<5%,3个添加水平的平均回收率在93.13%~99.89%,表明该方法具有较好的重复性和准确度。此外,丙烯酰胺在特定条件下能够在接触的纸和纸板之间发生迁移,生活用纸企业应对此现象予以关注。 相似文献
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《Carbon》2014
Spherical carbons have been prepared through hydrothermal treatment of three carbohydrates (glucose, saccharose and cellulose). Preparation variables such as treatment time, treatment temperature and concentration of carbohydrate have been analyzed to obtain spherical carbons. These spherical carbons can be prepared with particle sizes larger than 10 μm, especially from saccharose, and have subsequently been activated using different activation processes (H3PO4, NaOH, KOH or physical activation with CO2) to develop their textural properties. All these spherical carbons maintained their spherical morphology after the activation process, except when KOH/carbon ratios higher than 4/1 were used, which caused partial destruction of the spheres. The spherical activated carbons develop interesting textural properties with the four activating agents employed, reaching surface areas up to 3100 m2/g. Comparison of spherical activated carbons obtained with the different activating agents, taking into account the yields obtained after the activation process, shows that phosphoric acid activation produces spherical activated carbons with higher developed surface areas. Also, the spherical activated carbons present different oxygen groups’ content depending on the activating agent employed (higher surface oxygen groups content for chemical activation than for physical activation). 相似文献