Electrochemical Aspects of Electroosmotic Dewatering of Clay Suspensions

An attempt is made to elucidate the electrochemical aspects of the electroosmotic dewatering (EOD) of clays as reported in some recent work, especially that on interrupted DC power electroosmotic dewatering published by Rabie, Mujumdar and Weber (2). These authors showed that the dewatering by EOD stops after the DC power has been on for several minutes or hours; on interruption of their power and on short-circuiting of the electrodes, conditions can be created again for some further dewatering by DC power EOD. This discovery, of Rabie et al. is interpreted as a fuel cell effect and it is shown that it affords clues to several other electrochemical strategies for the possible enhancement of the efficiency of the EOD by DC power.

Further, the open circuit potentials observed by Rabie et al. (2) on the interruption of DC power are given an electrochemical interpretation which leads to quantitative estimates in agreement with the experimental values.     

Evaluation of different coating systems by electrochemical methods

Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests.     

Influence of the composition of the binder and the carbonation on the zeta potential values of hardened cementitious materials

Electroosmotic experiments have been carried out on eight different mixes of hardened cementitious matrixes including concrete, mortar and pastes, different types of binders, carbonated and non-carbonated specimens and different test conditions. From these trials, the zeta potential values have been determined and the optimum experimental parameters and devices have been established. In addition, the influence of the composition of the binder on the zeta potential has been quantified indicating that higher amounts of Al₂O₃ in the binder lead to higher positive values of zeta potential, while the SiO₂ acts just on the opposite side. This has been explained in terms of the different i.e.p. (isoelectric point) for both oxides. Concerning the influence of carbonation, it increases the absolute value of the zeta potential toward more negative values; this behaviour has been attributed to the influence of the specifically adsorbed Ca²⁺ in the negative sites of the surface in the non-carbonated samples.     

砂土的剪胀方程及其塑性势(Ⅰ):发展现状

以能量守恒原理为主线,在各向同性前提下,对Taylor剪胀方程、Cam-clay剪胀方程、修正Cam-clay剪胀方程、Rowe剪胀方程和扩展的Rowe剪胀方程等进行了较全面的综述.论证了剪胀方程和塑性势函数之间的相互转化关系.指出了Lade-Kim塑性势函数和Nova塑性势函数的缺陷之处,即这两个塑性势函数均没有合理耦合临界状态这一概念.     

Molecular dynamics studies of atomic-scale tribological characteristics for different sliding systems

A slider-slab sliding model for hard-to-soft and soft-to-soft sliding systems with abrasive and non-abrasive wear conditions is used to investigate atomic-scale friction. The molecular dynamics simulation uses the Morse potential to calculate interatomic forces between atoms. Separation distance between the slider and the slab is changed to simulate repulsive and attractive interactive force fields exerted on interface between two sliding components. Effects of the interaction potential parameters on the sliding friction are investigated. The relationship of frictional force, normal force and temperature rise of the slider and the slab during sliding are established. Comparison of the hard-to-soft and the soft-to-soft sliding system are carried out and shows different tribological phenomena.     

The influence of temperature, pressure, salinity and capillary force on the formation of methane hydrate

We present here a thermodynamic model for predicting multi-phase equilibrium of methane hydrate liquid and vapor phases under conditions of different temperature, pressure, salinity and pore sizes. The model is based on the 1959 van der Waals-Platteeuw model, angle-dependent ab initio inter- molecular potentials, the DMW-92 equation of state and Pitzer theory. Comparison with all available experimental data shows that this model can accurately predict the effects of temperature, pressure, salinity and capillary radius on the formation and dissociation of methane hydrate. Online calculations of the p-T conditions for the formation of methane hydrate at given salinities and pore sizes of sediments are available on: www.geochem-model.org/models.htm.     

Effect of carrier screening on ZnO-based resistive switching memory devices

The carrier screening effect occurs commonly in dielectric materials. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory (RRAM) devices. An Au/ZnO film/Al-doped ZnO device fabricated in this work exhibited no resistive switching (RS), which was attributed to the carrier screening effect. Therefore, annealing was used for alleviating the screening effect, significantly enhancing the RS property. In addition, different on/off ratios were obtained for various bias values, and the screening effect was accounted for by investigating electron transport mechanisms. Furthermore, different annealing temperatures were employed to modulate the free carrier concentration in ZnO films to alleviate the screening effect. The maximal on/off ratio reached 10⁵ at an annealing temperature of 600 °C, yielding the lowest number of free carriers and the weakest screening effect in ZnO films. This work investigates the screening effect in RS devices. The screening effect not only modulates the characteristics of memory devices but also provides insight into the mechanism of RS in these devices.

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无限长圆柱体的热弹性耦合问题

应用经典传热学理论,研究无限长圆柱体的热弹耦合问题。建立了经典传热学理论的控制方程,借助拉普拉斯积分变换及其数值反变换技术对问题进行了求解,得到了瞬态热冲击作用下无限长圆柱体中的温度、应力、位移的分布规律。从其分布图上可以看出,介质中呈现出热弹耦合效应。并且比较了传统热弹性理论与广义热弹性理论。     

微系统技术（连载六）─性能与测试

简要介绍了利用新型干涉仪测量微机械零件表面粗糙度的原理和方法，加载结构动摩擦系数测量，微系统器件残余应力分析和半导体器件表面电位测量。     

镍钒钛三原子体系的平衡结构与性质

用密度泛函理论（B3LYP）方法和相对论有效原子实势（RECP）近似,研究了NiVTi、TiV2、NiV2、NiTi2和TiNi2的平衡结构与性质,讨论了最高占据轨道（HOMO）与最低空轨道（LUMO）之间的能级间隙,分析了聚合物体系的稳定性质。