Influence of Se and Te substitutions at Tl-site of Tl(Ba,Sr)CaCu2O7 superconductor on the AC susceptibility and electrical properties

The Sr and Ba bearing Tl-1212 phase, Tl(Ba,Sr)CaCu₂O₇ is an interesting superconductor. The Sr only bearing TlSr₂CaCu₂O₇ is not easily prepared in the superconducting form. The Ba only bearing TlBa₂CaCu₂O₇ on the other hand does not show improvement in the transition temperature with elemental substitution. In this work the influence of multivalent Se (non-metal) and Te (metalloid) substitutions at the Tl-site of Tl_1-xM_x(Ba,Sr)CaCu₂O₇ (M = Se or Te) superconductors for x = 0–0.6 was studied. The samples were prepared via the conventional solid-state reaction method. XRD patterns showed a single Tl-1212 phase for x = 0 and 0.1 Se substituted samples. The critical current density at the peak temperature, T_p of the imaginary (χ”) part of the AC susceptibility (χ = χ’ +χ”), J_c-inter(T_p) for all samples was between 15 and 21 A cm⁻². The highest superconducting transition temperature was shown by the x = 0.3 Se-substituted sample (T_c-onset = 104 K, T_c-zero = 89 K, T_cχ’ = 104 K and T_p = 80 K). Te suppressed the superconductivity of Tl-1212 phase. The order of highest transition temperatures are as follows: Tl_1-xTe_x(Ba,Sr)CaCu₂O₇<Tl(Ba,Sr)CaCu₂O₇<Tl_1-xSe_x(Ba,Sr)CaCu₂O₇. This work showed that Se was better than Te in improving the transition temperature and flux pinning of the Tl-1212 phase. The roles of ionic radius of Se and Te on the superconductivity of Tl(Ba,Sr)CaCu₂O₇ are discussed in this paper.     

超宽带大功率合成器设计北大核心CSCD

在80 MHz~1 GHz频段,单个功率管输出功率能达到100 W以上,为研制输出功率400 W的功率放大器,文中设计了四路功率合成器。该合成器需要实现功率容量大、工作频带宽、体积小的设计目标。在功率容量方面,文中采用悬置带状线结构,其功率容量远远大于微带线结构;在工作频带方面,采用切比雪夫九节阻抗变换器,将工作带宽拓宽为80 MHz~1 GHz;在体积方面,文中合成器的功率合成部分采用Y型节级联实现四路功率合成,阻抗变换部分采用切比雪夫阻抗变换器进行阻抗变换,该结构相较于磁环巴伦功率合成器,不但具有损耗小、平坦度高的优点,而且通过将阻抗变换器设计成曲折的形状,进一步缩小了合成器体积。仿真与实测结果显示该合成器在80 MHz~1 GHz范围内还具有较高的平坦度,合成效率可达90%以上。     

储层泥浆侵入深度预测方法研究

泥浆侵入半径的确定尚缺乏严格的验证标准.以油水两相渗流理论和离子扩散方程为基础,结合储集层特点,研究了不同储层参数下泥浆滤液对地层的侵入特性.数值模拟侵入时间选取10 d和20 d.数值模拟结果表明,侵入半径在渗透率不变的情况下随孔隙度的增大而减小,在孔隙度不变的情况下随渗透率的增大而增大;当渗透率和孔隙度都发生变化时,泥浆侵入半径一般随孔隙度的增加呈幂函数增加.依据这种关系对测井资料约束处理,得到的泥浆侵入半径较客观地反映了地层的真实情况.     

对象族可镇定半径的计算

本文采用优化方法把计算对象族的可镇定半径问题转化成优化问题。2范数定义下的可镇定半径采用了Lagrange乘子法求解；无穷范数意义下的可镇定半径采用了最小范数解方法求解。本文方法对可镇定半径的定义形式和不确定参数结构没有要求，因此更具有一般性。     

普通稠油油藏启动压力梯度求解方法与应用

利用微观尺度管流模型,结合普通稠油流变特征,提出了在考虑稠油流变性条件下微观启动压力梯度计算方法.对渤海渤中18块不同渗透率岩心进行室内驱替实验,通过对实验数据的回归分析,得到不同粘度普通稠油油藏启动压力梯度与地层平均渗透率关系,并绘制了启动压力梯度的图版.将研究结果应用于普通稠油油藏,给出了利用启动压力梯度确定极限泄油半径及合理井距的理论计算方法.     

吐丝圈径对大规格高碳盘条组织性能的影响

计算与分析了斯太尔摩冷线上盘条的吐丝圈径、搭接密度及"佳灵"装置横向布风曲线之间的关系,研究了吐丝圈径的大小对大规格82B盘条组织和性能的影响,确定了大规格82B盘条最小吐丝圈径应为980mm.     

A note on the satisfaction of the boundary conditions for Chebyshev collocation methods in rectangular domains

The way boundary conditions are imposed when applying Chebyshev collocation methods to Poisson and biharmonic-type problems in rectangular domains is investigated. It is shown that careful selection of the number of collocation points leads to a linear system ofn linearly independent equations inn unknowns.     

Boiling: Size Distribution of Bubbles as Demanded by the Principle of Maximum Information

The principle of maximum informational entropy is used to find the probability density function for the departure radius of a bubble in boiling on a solid surface. A general relation is derived, which leads to particular expressions.     

A digital secure image communication scheme based on the chaotic Chebyshev map

In this paper, a simple image secure communication scheme based on the chaotic Chebyshev map and chaos synchronization is proposed. The scheme relies on the excellent correlation property of chaotic sequences, which is very desirable for secure image communication. The results obtained by computer simulation indicate that the transmitted source image can be correctly and reliably recovered using the proposed scheme, even through a noisy channel. Notably, the scheme possesses relatively high security and can be easily implemented. Moreover, the quality of the recovered image is satisfactory, quantified by such common criteria as the bit‐error rate performance. Copyright © 2004 John Wiley & Sons, Ltd.     

An analysis of the electrical conductivity in BaSO4-added Ag2SO4 solid electrolyte system

The compositions (1 −x)Ag₂SO₄−(x)BaSO₄, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba²⁺ in Ag₂SO₄ was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained using a detailed impedance analysis. The partial substitution of Ba²⁺ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model based on lattice distortion (expansion) due to partial substitution of Ag⁺ by the bigger Ba²⁺ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO₄-dispersed Ag₂SO₄ conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO₄ dispersed Ag₂SO₄ is due to percolation threshold.