In-chain functionalization by alternating anionic copolymerization of styrene and 1-(4-dimethylaminophenyl)-1-phenylethylene

Anionic copolymerizations of styrene (M₁) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M₂) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;_n = 16.1 × 10³ g/mol (M?_w/M?_n = 1.04) and 38.2 × 10³g/mol (M?_w/M?_n = 1.05), and 24 and 38 moles of M₂ per macromolecule, respectively, were characterized by size exclusion chromatography, ¹H NMR spectroscopy and DSC. The monomer reactivity ratio, r₁ = 5.6, was obtained from the copolymer composition at complete consumption of M₁, assuming that the rate constant k₂₂ =0,i.e. r₂ =0. The polymers exhibited T_g values of 128 and 119°C, respectively, which correspond to an estimated T_g = 217°C for the hypothetical homopolymer of M₂.     

SYMMETRIC STABLE SEQUENCES WITH MISSING OBSERVATIONS

Abstract. A procedure for evaluating optimal linear estimates of missing values in the minimum dispersion sense is proposed for stationary symmetric stable processes. Analytical expressions for the estimates are obtained for the autoregressive moving-average process and it is shown that the finite variance setting results are special cases. Cases of one and more than one missing value are considered.     

Combinatorial optimization under uncertainty

In this paper, the general problem of Euclidean combinatorial optimization under uncertainty is formulated for the first time and the concepts of a stochastic multiset, a multiset of fuzzy numbers, a stochastic Euclidean combinatorial set, and general Euclidean combinatorial set of fuzzy stochastic numbers that combines the properties of both types of uncertainty are introduced. __________ Translated from Kibernetika i Sistemnyi Analiz, No. 5, pp. 35–44, September–October 2008.     

二维小波变换理论在地震信号去噪中的应用

针对地震信号随机干扰和规则干扰的特点，运用二维小波变换的理论，设计了相应的变换域去噪滤波器。理论记录和实际野外记录试算表明，二维小波变换具有较强的信噪分离作用。只要运用得当就能取得满意的效果。     

智能卡话者确认系统的研究

介绍了一个将参考模板存放在智能卡上的与相关的话者确认系统及其工作原理、相关算法和参数设置。     

水泥砂浆的率型损伤演化

实验结果表明,水泥砂浆在受力变形中的损伤演化是率相关的,因此,类似于位错运动的热激活机制;给出了水泥砂浆的率型损伤演化律．     

一个在线考试系统的设计与实现

网上考试作为网络教学和校园信息化建设的较为重要的部分,有其独特的需求和作用。本文论述了采用生成随机数方法的一个在线考试系统的功能和数据库的设计与实现过程。     

The synthesis of novel fluorine-containing random polymer and application in modification of solid surfaces

The novel fluorine-containing random polymers, poly (2, 3, 4, 5, 6-pentafluorostyrene)-r-poly (4-vinyl benzocyclobutene) random copolymer was synthesized, which can effectively decrease the surface energy and provide a good corrosion protection for some metals. Additionally, textured silicon was fabricated by an optically assisted electrochemical etching process to study the effect of the random copolymer modification on the binary geometric structures of the solid surface. After modification the superhydrophobic property can easily be obtained, which show long-term stability and good superhydrophobicity in corrosive solutions over a wide pH range, including acidic and basic solutions.