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1.
Mamata Mukhopadhyay Sameer V Dalvi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(4):445-454
A supercritical antisolvent (SAS) process is employed for production of solid nanoparticles from atomized droplets of dilute solution in a flowing supercritical carbon dioxide (SC CO2) stream by attaining extremely high, very rapid, and uniform supersaturation. This is facilitated by a two‐way mass transfer of CO2 and solvent, to and from the droplet respectively, rendering rapid reduction in equilibrium solubility of the solid solute in the ternary solution. The present work analyses the degree of supersaturation and nucleation kinetics in a single droplet of cholesterol solution in acetone during its flight in a flowing SC CO2 stream. Both temperature and composition are assumed to be uniform within the droplet, and their variations with time are calculated by balancing the heat and mass transfer fluxes to and from the droplet. The equilibrium solubility of cholesterol with CO2 dissolution has been predicted as being directly proportional to the Partial Molar Volume Fraction (PMVF) of acetone in the binary (CO2–acetone) system. The degree of supersaturation has been simulated up to the time required to attain almost zero cholesterol solubility in the droplet for evaluating the rate of nucleation and the size of the stable critical nuclei formed. The effects of process parameters have been analysed in the pressure range of 7.1–35.0 MPa, temperature range of 313–333 K, SC CO2 flow rate of 0.1136–1.136 mol s?1, the ratio of the volumetric flow rates of CO2‐to‐solution in the range of 100–1000, and the initial mole fraction of cholesterol in acetone solution in the range of 0.0025–0.010. The results confirm an extremely high and rapid increase in degree of supersaturation, very high nucleation rates and stable critical nucleus diameter of the order of a nanometre. Copyright © 2005 Society of Chemical Industry 相似文献
2.
During the 1997 winter season, shipborne polarimetric backscatter measurements of Great Lakes (freshwater) ice types using the Jet Propulsion Laboratory C-band scatterometer, together with surface-based ice physical characterization measurements and environmental parameters, were acquired concurrently with Earth Resource Satellite 2 (ERS-2) and RADARSAT Synthetic Aperture Radar (SAR) data. This polarimetric data set, composed of over 20 variations of different ice types measured at incident angles from 0° to 60° for all polarizations, was processed to radar cross-section to establish a library of signatures (look-up table) for different ice types. The library is used in the computer classification of calibrated satellite SAR data. Computer analysis of ERS-2 and RADARSAT ScanSAR images of Great Lakes ice cover using a supervised classification technique indicates that different ice types in the ice cover can be identified and mapped, and that wind speed and direction can have an influence on the classification of water as ice based on single frequency, single polarization data. Once satellite SAR data are classified into ice types, the ice map provides important and necessary input for environmental protection and management, ice control and ice breaking operations, and ice forecasting and modeling efforts. 相似文献
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基于多幅同目标图像和HMM的SAR图像目标识别 总被引:2,自引:0,他引:2
该文提出了一种基于多幅同目标图像和隐马尔可夫模型的合成孔径雷达图像目标识别方法。该方法通过小波域主成分分析提取目标图像特征向量,结合多幅不同方位角下的同目标图像的特征向量生成单幅图像的特征序列,用隐马尔可夫模型对特征序列进行识别。实验结果表明,该方法可明显提高目标的正确识别率,是一种有效的合成孔径雷达图像目标识别方法。 相似文献
5.
LiuHao ZhuMinhui 《电子科学学刊(英文版)》2003,20(4):313-320
Moving ships produce a set of waves of “V“ pattern on the ocean. These wavescan often be seen by Synthetic Aperture Radar (SAR). The detection of these wakes can provide important information for surveillance of shipping, such as ship traveling direction and speed.A novel approach to the detection of ship wakes in SAR images based on frequency domain is provided in this letter. Compared with traditional Radon-based approaches, computation is reduced by 20%-40% without losing nearly any of detection performance. The testing results using real data and simulation of synthetic SAR images test the algorithm‘s feasibility and robustness. 相似文献
6.
SAR图像舰船目标检测算法的对比研究 总被引:8,自引:0,他引:8
SAR图像舰船目标检测有二种经典算法:双参数CFAR算法和K-分布CFAR算法。本文分析了二种算法的特点,使用RADARSAT卫星不同模式SAR图像分别进行实验,给出二种算法的适应性。 相似文献
7.
文章研究了机载合成孔径雷达(SAR)在大斜视角下的成像算法,并分析了算法的成像性能。根据大斜视角SAR成像的空间几何模型和回波信号特点,提出了RD算法的改进方案。对改进的RD算法和ECS算法的仿真表明,其成像性能满足了大斜视角下机载SAR成像处理的要求。 相似文献
8.
针对聚束式合成孔径雷达(SAR)动目标检测的问题,把回波信号进行连续重叠地时域分组,每组信号可以看成是来自一个时域子孔径, 然后在每个子孔径内分别成像。地面固定目标在每幅图像上的成像情况是相同的, 通过彼此相减就可以消去,达到了抑制杂波的目的,而运动目标由于每个时刻的位置都在变化,在每幅图像上的位置是不同的, 从而在相减后剩余下运动目标的图像,把这些图像拼接起来就再现了运动目标的运动轨迹,根据运动轨迹就可以对其运动参数进行估计。该文给出了这个方法的原理推导和具体的检测过程。仿真结果证明了该方法的有效性。 相似文献
9.
利用合成孔径雷达(Synthetic Aperture Radar, SAR)获取的目标像进行识别时,基于子空间的自动目标识别(Automatic Target Recognition, ATR)方法通常是对样本数据的值空间进行操作。当识别相似目标时,由于彼此的值空间存在较大的交集,生成的识别模板的可分性较差。该文提出一种SAR目标ATR方法,该方法将SAR样本数据的正交子空间作为投影空间。因此,不同类目标样本在投影空间的差异性加大,能够明显提高识别效果。实验结果表明,本文方法的识别性能优于其它同类方法。 相似文献
10.